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公开(公告)号：US10696581B2
公开(公告)日：2020-06-30
申请号：US16269379
申请日：2019-02-06
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing
Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.
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公开(公告)号：US10590027B2
公开(公告)日：2020-03-17
申请号：US16081350
申请日：2016-03-21
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing , Guijiang Gu
Abstract: Provided are a high performance glass fiber composition, and a glass fiber and a composite material thereof. The content, given in weight percentage, of each component of the glass fiber composition is as follows: 52-67% of SiO2, 12-24% of Al2O3, 0.05-4.5% of Sm2O3+Gd2O3, less than 2% of Li2O+Na2O+K2O, 10-24% of CaO+MgO+SrO, less than 16% of CaO, less than 13% of MgO, less than 3% of TiO2, and less than 1.5% of Fe2O3. The composition significantly improves the mechanical properties and the thermal stability of glass, significantly reduces the liquidus temperature and forming temperature of glass, and under equal conditions, significantly reduces the crystallisation rate of glass. The composition is particularly suitable for the tank furnace production of a high performance glass fiber having excellent thermal stability.
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公开(公告)号：US12215049B2
公开(公告)日：2025-02-04
申请号：US17425542
申请日：2020-08-12
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Changying Fang , Xianliang Zhao , Yucang Yan , Xiaodong Weng
Abstract: A cover plate structure for a glass fiber tank furnace forehearth includes chest wall bricks at two sides of the forehearth, cover plate bricks each spanning between a top end of at least one of the chest wall bricks at one of the two sides of the forehearth and a top end of at least one of the chest wall bricks at another one of the two sides of the forehearth, a thermal insulation layer covering outer surfaces of the cover plate bricks and the chest wall bricks, and a gap-covering brick fixed between the cover plate bricks and the thermal insulation layer and covering a gap between adjacent ones of the cover plate bricks.
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公开(公告)号：US10329189B2
公开(公告)日：2019-06-25
申请号：US15739110
申请日：2016-06-16
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing , Guijiang Gu
Abstract: A high-modulus glass fiber composition, and a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components in weight percentage: SiO2 55.7 to 58.9%, Al2O3 15 to 19.9%, Y2O3 0.1 to 4.3%, La2O3 less than or equal to 1.5%, CeO2 less than or equal to 1.2%, CaO 6 to 10%, MgO 9.05 to 9.95%, SrO less than or equal to 2%, Li2O+Na2O+K2O less than or equal to 0.99%, Li2O less than or equal to 0.65%, Fe2O3 less than 1%, TiO2 0.1 to 1.5%; wherein, the range of the weight percentage ratio C1=Y2O3/(Y2O3+La2O3+CeO2) is greater than 0.6. The composition can greatly improve the elastic modulus of glass, significantly reduce liquidus temperature and forming temperature of the glass, greatly reduce the crystallization rate of molten glass and bubble amount under the same conditions, and therefore is more suitable for large-scale tank furnace production of high-modulus fiberglass with low bubble amount.
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公开(公告)号：US10239781B2
公开(公告)日：2019-03-26
申请号：US15738563
申请日：2016-03-07
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing
Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.
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Patent Agency Ranking
公开(公告)号：US20230183118A1
公开(公告)日：2023-06-15
申请号：US18167677
申请日：2023-02-10
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Changying Fang , Lifeng Yu , Peijun Shen , Xianliang Zhao , Yucang Yan , Xiaodong Weng
CPC classification number: C03B5/03 , C03B5/193 , C03B5/2353
Abstract: A glass tank furnace having a length to width ratio of no less than 2.3 and no greater than 2.8. The glass tank furnace includes one or more weirs and a plurality of bubbling tubes provided on a bottom of the glass tank furnace. The plurality of bubbling tubes are disposed before, behind, or on the weirs.
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7.发明授权公开(公告)号：US10669189B2
公开(公告)日：2020-06-02
申请号：US16084618
申请日：2016-03-21
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing , Xiucheng Hong
Abstract: Provided are a high-performance glass fiber composition, and a glass fiber and composite material thereof. The content, given in weight percentage, of each component of the glass fibre composition is as follows: 52-64% of SiO2, 12-24% of Al2O3, 0.05-8% of Y2O3+La2O3+Gd2O3, less than 2.5% of Li2O+Na2O+K2O, more than 1% of K2O, 10-24% of CaO+MgO+SrO, 2-14% of CaO, less than 13% of MgO, less than 2% of TiO2, and less than 1.5% of Fe2O3. The composition significantly increases the mechanical strength and the elastic modulus of glass, significantly reduces the liquidus temperature and the forming temperature of glass, and under equal conditions, significantly reduces the crystallization rate, the surface tension and the bubble rate of glass. The composition is particularly suitable for the tank furnace production of a high-strength high-modulus glass fiber having a low bubble rate.
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公开(公告)号：US10377662B2
公开(公告)日：2019-08-13
申请号：US15739081
申请日：2016-03-21
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing , Guijiang Gu
Abstract: The present invention provides a glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 53-64% SiO2, greater than 19% and lower than 25% Al2O3, 0.05-7% Y2O3+La2O3+Gd2O3, not greater than 1% Li2O+Na2O+K2O, 10-24% CaO+MgO+SrO, 1.5-12% CaO, lower than 2% TiO2, lower than 1.5% Fe2O3. Said composition can not only significantly improve the elastic modulus and chemical stability of the glass, but also overcome the technical problems in the manufacture of traditional high-performance glasses including high risk of crystallization, fining difficulty of molten glass and production efficiency difficulty with refractory-lined furnaces, significantly reduce the liquidus and forming temperatures and greatly reduce the crystallization rate under the same conditions, thus making it particularly suitable for production of high-performance glass fiber with excellent chemical stability in refractory-lined furnaces.
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公开(公告)号：US10294142B2
公开(公告)日：2019-05-21
申请号：US16066284
申请日：2016-03-07
Applicant: JUSHI GROUP CO., LTD.
Inventor： Yuqiang Zhang , Guorong Cao , Lin Zhang , Wenzhong Xing , Guijiang Gu
Abstract: A high modulus glass fiber composition, and a glass fiber and a composite material thereof. The glass fiber composition comprises the following components expressed as percentage by weight: 53-68% of SiO2, 13-24.5% of Al2O3, 0.1-8% of Y2O3+La2O3, less than 1.8% of La2O3, 10-23% of CaO+MgO+SrO, less than 2% of Li2O+Na2O+K2O, and less than 1.5% of Fe2O3, and the range of a weight percentage ratio C1 is more than 0.5, wherein C1=Y2O3/(Y2O3+La2O3). The composition significantly increases the elastic modulus of glass, significantly reduces the liquidus temperature and the forming temperature of glass, and under equal conditions, significantly reduces the crystallization rate and the bubble rate of glass. The composition effectively improves the material properties of glass, and is particularly suitable for the tank furnace production of a high modulus glass fiber having a low bubble rate.
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10.发明授权Composition for preparing high-performance glass fiber by tank furnace production 有权用于通过罐式炉生产制备高性能玻璃纤维的组成公开(公告)号：US09428414B2
公开(公告)日：2016-08-30
申请号：US14543388
申请日：2014-11-17
Applicant: Jushi Group Co., Ltd.
Inventor： Yuqiang Zhang , Guorong Cao , Bing Zhang , Lin Zhang , Wenzhong Xing , Guijiang Gu
Abstract: A composition for preparing high-performance glass fiber by tank furnace production comprising in preferred percentage by weight: 57.5˜62.5% of SiO2,14.5˜17.5% of Al2O3,13.5˜17.5% of CaO,6.5˜8.5% of MgO,0.05˜0.6% of Li2O,0.1˜2% of B2O3,0.1˜2% of TiO2,0.1˜2% of Na2O,0.1˜1% of K2O and 0.1˜1% of Fe2O3 and (CaO+MgO)/MgO>3, with the content of at least one of the three components, Li2O, B2O3 and TiO2higher than 0.5%, with the composition yielding glass fiber having improved mechanical property, causing the melting and clarification of glass and forming performance of fiber close to those of boron-free E glass, and facilitating industrial mass production by tank furnace processes with manufacturing costs close to those of conventional E glass.
Abstract translation: 一种用于通过槽式炉生产制备高性能玻璃纤维的组合物，其包含优选的重量百分比：57.5〜62.5％的SiO2,14.5〜17.5％的Al2O3,13.5〜17.5％的CaO，6.5〜8.5％的MgO，0.05〜 0.6％的Li2O，0.1〜2％的B2O3,0.1〜2％的TiO2,0.1〜2％的Na2O，0.1〜1％的K2O和0.1〜1％的Fe2O3和（CaO + MgO）/ MgO3， 三种成分中的至少一种，Li 2 O，B 2 O 3和TiO 2的含量高于0.5％，组合物产生具有改善的机械性能的玻璃纤维，导致玻璃的熔融澄清和接近硼 - 免费的E玻璃，并通过罐式炉工艺促进工业大规模生产，制造成本接近传统的E玻璃。
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