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公开(公告)号:US20200006781A1
公开(公告)日:2020-01-02
申请号:US16538703
申请日:2019-08-12
Applicant: Korea Institute of Energy Research
Inventor: Gu-Gon PARK , Sun-Mi HWANG , Sung-Dae YIM , Chang-Soo KIM , Won-Yong LEE , Tae-Hyun YANG , Seok-Hee PARK , Minjin KIM , Young-Jun SOHN , Byungchan BAE , Seung-Gon KIM , Dongwon SHIN
Abstract: The present disclosure relates to a method and an apparatus for manufacturing a core-shell catalyst, and more particularly, to a method and an apparatus for manufacturing a core-shell catalyst, in which a particle in the form of a core-shell in which the metal nanoparticle is coated with platinum is manufactured by substituting copper and platinum through a method of manufacturing a metal nanoparticle by emitting a laser beam to a metal ingot, and providing a particular electric potential value, and as a result, it is possible to continuously produce nanoscale uniform core-shell catalysts in large quantities.
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公开(公告)号:US20230420696A1
公开(公告)日:2023-12-28
申请号:US18465471
申请日:2023-09-12
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Gu-gon PARK , Eun Jik LEE , Kyunghee KIM , Sung-dae YIM , Seok-hee PARK , Min-ji KIM , Young-jun SOHN , Byungchan BAE , Seung-gon KIM , Dongwon SHIN , Hwanyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Won-yong LEE , Tae-hyun YANG
CPC classification number: H01M4/926 , H01M4/8657 , B01J23/38 , B01J37/00 , B01J35/008 , B01J23/34 , B01J23/28 , B01J23/30
Abstract: The present disclosure relates to a method for manufacturing core-shell particles using carbon monoxide, and more particularly, to a method for manufacturing core-shell particles, the method of which a simple and fast one-pot reaction enables particle manufacturing to reduce process costs, facilitate scale-up, change various types of core and shell metals, and form a multi-layered shell by including the steps of adsorbing carbon monoxide on a transition metal for a core, and reacting carbon monoxide adsorbed on the surface of the transition metal for the core, a metal precursor for a shell, and a solvent to form particles with a core-shell structure having a reduced metal shell layer formed on a transition metal core.
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公开(公告)号:US20230402619A1
公开(公告)日:2023-12-14
申请号:US18188740
申请日:2023-03-23
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Eun Jik LEE , Gu-gon PARK , DongJe LEE , Sung-dae YIM , Seok-hee PARK , Min-jin KIM , Young-jun SOHN , Byungchan BAE , Seung-gon KIM , Dongwon SHIN , Hwanyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Yun Sik KANG , Won-yong LEE , Tae-hyun YANG
CPC classification number: H01M4/921 , H01M4/9016 , H01M4/8652
Abstract: A method for preparing a platinum alloy catalyst using an oxide coating according to an embodiment of the present disclosure comprises: a first step of preparing a dispersion by mixing a commercial platinum catalyst and a transition metal precursor with a solvent; a second step of preparing a catalyst by putting an ultrasonic tip into the dispersion prepared through the first step and performing an ultrasonic process; a third step of performing a primary heat treatment process on the catalyst prepared through the second step; a fourth step of performing an acid treatment process on the catalyst that has undergone the primary heat treatment process through the third step; and a fifth step of preparing a platinum alloy catalyst by performing a secondary heat treatment process on the catalyst that has undergone the acid treatment process through the fourth step.
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公开(公告)号:US20180159138A1
公开(公告)日:2018-06-07
申请号:US15646995
申请日:2017-07-11
Applicant: Korea Institute of Energy Research
Inventor: Gu-Gon PARK , Sun-Mi HWANG , Sung-Dae YIM , Chang-Soo KIM , Won-Yong LEE , Tae-Hyun YANG , Seok-Hee PARK , Minjin KIM , Young-Jun SOHN , Byungchan BAE , Seung-Gon KIM , Dongwon SHIN
CPC classification number: H01M4/8657 , B01J19/02 , B01J19/087 , B01J19/121 , B01J2219/0209 , B01J2219/029 , B01J2219/0803 , B01J2219/0879 , B01J2219/089 , B01J2219/12 , H01M4/921 , H01M4/925
Abstract: The present disclosure relates to a method and an apparatus for manufacturing a core-shell catalyst, and more particularly, to a method and an apparatus for manufacturing a core-shell catalyst, in which a particle in the form of a core-shell in which the metal nanoparticle is coated with platinum is manufactured by substituting copper and platinum through a method of manufacturing a metal nanoparticle by emitting a laser beam to a metal ingot, and providing a particular electric potential value, and as a result, it is possible to continuously produce nanoscale uniform core-shell catalysts in large quantities.
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公开(公告)号:US20180154329A1
公开(公告)日:2018-06-07
申请号:US15646997
申请日:2017-07-11
Applicant: Korea Institute of Energy Research
Inventor: Gu-Gon PARK , Sun-Mi HWANG , Sung-Dae YIM , Chang-Soo KIM , Won-Yong LEE , Tae-Hyun YANG , Seok-Hee PARK , Min-Jin KIM , Young-Jun SOHN , Byungchan BAE , Seung-Gon KIM , Dongwon SHIN
Abstract: To provide a reactor to improve evenness in the thickness of shell metals coated on the surface of core particles by increasing area sizes in the reactor chamber to control electric potentials, the present invention is configured to comprise a top surface able to move up and down while serving as a working electrode, a wall serving as a working electrode, a bottom surface, a standard electrode, a power supplying part and a solution injecting part, wherein the top surface can move up and down automatically by an electric motor or manually. Also, the top surface is configured to be suitable for the interior diameter of the reactor chamber, for solutions inside the reactor chamber not to leak from the top surface or from the crevice between the top surface and the wall of the reactor chamber. The bottom surface of the reactor chamber may comprise an impeller or an ultrasonic wave diffuser to bring about even diffusion in the reactor chamber.
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公开(公告)号:US20240253026A1
公开(公告)日:2024-08-01
申请号:US18412426
申请日:2024-01-12
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Gu-Gon PARK , Eunjik LEE , Sung-Dae YIM , Seok-Hee PARK , Minjin KIM , Young-Jun SOHN , Byungchan BAE , Seung-Gon KIM , Dongwon SHIN , Seung Wook CHOI , Hwangyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Yun Sik KANG , Won-Yong LEE , Tae-Hyun YANG
CPC classification number: B01J37/0221 , B01J35/19 , B01J37/08 , B01J37/16 , B01J37/343
Abstract: Provided are a core-shell catalyst with improved durability and a manufacturing method thereof including irradiating ultrasonic waves to a solution containing a reducing solvent, a noble metal precursor, a transition metal precursor, and a carbon support to form a cavity due to the irradiation of the ultra-waves and forming transition metal precursor core and noble metal precursor shell particles due to a difference in vapor pressure; and nitriding the transition metal precursor core and noble metal precursor shell particles at a temperature of 450 to 550° C. and a pressure condition of 60 to 100 bar under a gaseous nitrogen source, in which the transition metal may be any one selected from the group consisting of Y, La, Ce, Zn, and Mn or combinations thereof.
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7.
公开(公告)号:US20230378480A1
公开(公告)日:2023-11-23
申请号:US18161941
申请日:2023-01-31
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Gu-gon PARK , Eunjik LEE , Ik Sung LIM , Sung-Dae YIM , Seok-Hee PARK , Minjin KIM , Young-Jun SOHN , Byungchan BAE , Seung-gon KIM , Dongwon SHIN , Hwanyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Yun Sik KANG , Won-yong LEE , Tae-hyun YANG
CPC classification number: H01M4/8882 , H01M4/8657 , H01M4/9058
Abstract: The manufacturing method of a palladium transition metal core-based core-shell electrode catalyst according to an exemplary embodiment of the present disclosure includes a first step of preparing a slurry by irradiating ultrasonic wave to a dispersion solution including a solvent, a platinum precursor, a palladium precursor, a carbon support, and a transition metal precursor, a second step of preparing a solid material by filtering, washing, and drying the slurry prepared in the first step, and a third step of preparing a core-shell electrode catalyst by thermally treating the solid prepared in the second step in a specific gas atmosphere.
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公开(公告)号:US20220077471A1
公开(公告)日:2022-03-10
申请号:US17466453
申请日:2021-09-03
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Gu-gon PARK , Eun Jik LEE , Kyunghee KIM , Sung-dae YIM , Seok-hee PARK , Min-ji KIM , Young-jun SOHN , Byungchan BAE , Seung-gon KIM , Dongwon SHIN , Hwanyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Won-yong LEE , Tae-hyun YANG
Abstract: The present disclosure relates to a method for manufacturing core-shell particles using carbon monoxide, and more particularly, to a method for manufacturing core-shell particles, the method of which a simple and fast one-pot reaction enables particle manufacturing to reduce process costs, facilitate scale-up, change various types of core and shell metals, and form a multi-layered shell by including the steps of adsorbing carbon monoxide on a transition metal for a core, and reacting carbon monoxide adsorbed on the surface of the transition metal for the core, a metal precursor for a shell, and a solvent to form particles with a core-shell structure having a reduced metal shell layer formed on a transition metal core.
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公开(公告)号:US20210170488A1
公开(公告)日:2021-06-10
申请号:US16916974
申请日:2020-06-30
Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
Inventor: Gu-gon PARK , Hyun-uk PARK , Won-yong LEE , Sung-dae YIM , Min-jin KIM , Young-jun SOHN , Byungchan BAE , Seung-gon KIM , Dongwon SHIN , Hwanyeong OH , Seung Hee WOO , So Jeong LEE , Hyejin LEE , Yoon Young CHOI , Seok-hee PARK , Tae-hyun YANG
Abstract: The present disclosure is related to a method to control sizes of core-shell nanoparticles comprising the steps of: manufacturing slurry by irradiating ultrasonic waves to a dispersion solution containing a reducing solvent, a carbon support, a transition metal precursor and a precious metal precursor; manufacturing a solid by filtering the manufactured slurry, followed by washing and drying; and manufacturing a nanoparticle of a transition metal core and a platinum shell by heat-treating the dried solid at a temperature of 450 to 900° C. and a pressure of 1 to 90 bar for 0.5 to 10 hours under N2 atmosphere.
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