-
1.发明授权Method for producing lactide directly from lactic acid and a catalyst used therein 有权直接由乳酸生产丙交酯的方法及其中使用的催化剂公开(公告)号：US09539561B2
公开(公告)日：2017-01-10
申请号：US14422526
申请日：2013-04-24
Inventor： Dong Won Hwang , Jong-San Chang , Pravin P. Upare , U-Hwang Lee , Young Kyu Hwang
IPC: C07D319/00 , B01J23/14 , C07D319/10 , C07D319/12 , B01J21/04 , B01J21/06 , B01J21/08 , B01J35/00 , C01G19/02 , B01J37/03 , B01J29/03 , B01J29/40 , B01J29/70
CPC classification number: B01J23/14 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J29/0308 , B01J29/405 , B01J29/7057 , B01J35/0006 , B01J35/002 , B01J37/031 , B01J37/035 , C01G19/02 , C07D319/10 , C07D319/12
Abstract: The present invention provides a method for directly producing lactide by subjecting lactic acid to a dehydration reaction in the presence of a catalyst comprising a tin compound, preferably, a tin (IV) compound, wherein lactide can be produced directly or by one step from lactic acid, without going through the step of producing or separating lactic acid oligomer. The method of the present invention has advantages of causing no loss of lactic acid, having a high conversion ratio to lactic acid and a high selectivity to optically pure lactide, and maintaining a long life time of the catalyst. Further, since lactic acid oligomer is not or hardly generated and the selectivity of meso-lactide is low, the method also has an advantage that the cost for removing or purifying this can be saved.
Abstract translation: 本发明提供一种在含有锡化合物，优选锡（IV）化合物的催化剂存在下使乳酸进行脱水反应直接生产丙交酯的方法，其中丙交酯可直接或通过一步从乳酸 酸，而不经过生产或分离乳酸低聚物的步骤。 本发明的方法具有不会损失乳酸，乳酸转化率高，对光学纯丙交酯具有高选择性，并保持催化剂寿命长的优点。 此外，由于乳酸低聚物不是或几乎不产生，内消旋 - 丙交酯的选择性低，所以该方法还具有可以节省除去或纯化成本的优点。
-
公开(公告)号：US09988362B2
公开(公告)日：2018-06-05
申请号：US15098905
申请日：2016-04-14
Inventor： Dong Won Hwang , Pravin P. Upare , Jong San Chang , Young Kyu Hwang , U Hwang Lee , Do Young Hong
IPC: C07D307/42 , C07D307/36 , C07D307/48 , C07D307/50
CPC classification number: C07D307/42 , C07D307/36 , C07D307/48 , C07D307/50
Abstract: The present invention relates to a method for preparing for a furan derivative from biomass, comprising step (1) of preparing 5-hydroxymethylfurfural by reacting biomass and a solid acid catalyst in butanol; and step (2) of preparing a furan derivative by reacting the butanol solution of 5-hydroxymethylfurfural, obtained in step (1), with a hydrogenation catalyst.
-
公开(公告)号：US09561492B2
公开(公告)日：2017-02-07
申请号：US14869138
申请日：2015-09-29
Inventor： Dong Won Hwang , Jong-San Chang , Pravin P. Upare , U-Hwang Lee , Young Kyu Hwang
IPC: C07D319/00 , B01J23/14 , C07D319/10 , C07D319/12 , B01J21/04 , B01J21/06 , B01J21/08 , B01J35/00 , C01G19/02 , B01J37/03 , B01J29/03 , B01J29/40 , B01J29/70
CPC classification number: B01J23/14 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J29/0308 , B01J29/405 , B01J29/7057 , B01J35/0006 , B01J35/002 , B01J37/031 , B01J37/035 , C01G19/02 , C07D319/10 , C07D319/12
Abstract: The present invention provides a method for directly producing lactide by subjecting lactic acid to a dehydration reaction in the presence of a catalyst comprising a tin compound, preferably, a tin (IV) compound, wherein lactide can be produced directly or by one step from lactic acid, without going through the step of producing or separating lactic acid oligomer. The method of the present invention has advantages of causing no loss of lactic acid, having a high conversion ratio to lactic acid and a high selectivity to optically pure lactide, and maintaining a long life time of the catalyst. Further, since lactic acid oligomer is not or hardly generated and the selectivity of meso-lactide is low, the method also has an advantage that the cost for removing or purifying this can be saved.
-
-
Search Results
3
records
(took 0.017 seconds)
