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公开(公告)号：US09376734B2
公开(公告)日：2016-06-28
申请号：US14423093
申请日：2013-04-26
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B58/00 , C22B3/00 , C07D233/64 , C07D237/06 , B01D11/04 , C07C237/06 , C22B3/26 , C22B3/32 , C22B3/38
CPC分类号： C22B58/00 , B01D11/0492 , C07C237/06 , C07D233/64 , C22B3/0024 , C22B3/0032 , C22B3/005 , Y02P10/234 , Y02P20/582
摘要： Provided are an extraction agent and extraction method that selectively extract and, at a low cost, recover indium from an acidic solution containing indium and zinc. The indium extraction agent comprises an amide derivative represented by general formula (I). In the formula, R1 and R2 each indicate the same or different alkyl group, R3 indicates a hydrogen atom or an alkyl group, and R4 indicates a hydrogen atom or any given group, other than an amino group, bound to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By extracting indium from an acidic solution containing indium and zinc by means of solvent extraction using the extraction agent, it is possible to selectively extract indium.
摘要翻译： 提供一种提取剂和提取方法，其选择性地提取并且以低成本从含有铟和锌的酸性溶液中回收铟。 铟提取剂包含由通式（I）表示的酰胺衍生物。 在该式中，R 1和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示氢原子或与α-碳结合的除氨基以外的任何给定基团 氨基酸。 通式优选具有甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 通过使用萃取剂通过溶剂萃取从含有铟和锌的酸性溶液中提取铟，可以选择性地提取铟。
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公开(公告)号：US20150376734A1
公开(公告)日：2015-12-31
申请号：US14765272
申请日：2014-03-12
发明人： Masahiro Goto , Fukiko kubota , Yuzo Baba
CPC分类号： C22B3/0004 , C22B3/0005 , C22B13/04 , C22B15/0063 , C22B15/0089 , Y02P10/234 , Y02P10/236 , Y02W30/84
摘要： In order to selectively extract copper and/or lead from an acidic solution containing high concentrations of manganese, etc., the valuable-metal extracting agent of the present invention is expressed by general formula (1). In the formula, R1 and R2 each represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a given group, other than an amino group, that bonds with an α carbon as an amino acid. In general formula (1), the inclusion of a glycine unit, a histidine unit, a lysine unit, an asparagine acid unit, or a normal methylglycine unit is preferred. When using the extracting agent to extract copper/and lead, it is preferable that the pH of the acidic solution be adjusted to 1.0-5.5 inclusive.
摘要翻译： 为了从含有高浓度锰等的酸性溶液中选择性地提取铜和/或铅，本发明的有价值金属提取剂由通式（1）表示。 在该式中，R 1和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示与α碳键合的氢原子或除了氨基以外的给定基团 氨基酸。 在通式（1）中，优选包含甘氨酸单元，组氨酸单元，赖氨酸单元，天冬酰胺酸单元或正常的甲基甘氨酸单元。 当使用提取剂萃取铜和铅时，优选将酸性溶液的pH调节至1.0-5.5（含）。
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公开(公告)号：US20150211093A1
公开(公告)日：2015-07-30
申请号：US14423061
申请日：2013-04-26
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B58/00 , C22B3/44 , C22B3/08 , C07C237/06 , C07D233/64
CPC分类号： C22B58/00 , B01D11/0492 , C07C237/06 , C07D233/64 , C22B3/0005 , C22B3/0032 , C22B3/08 , C22B3/44 , Y02P10/234 , Y02P20/582
摘要： Provided are an extraction agent and extraction method that selectively extract and, at a low cost, recover gallium from an acidic solution containing gallium and zinc. The gallium extraction agent comprises an amide derivative represented by general formula (1). In the formula, R and R2 each indicate the same or different alkyl group, R3 indicates a hydrogen atom or an alkyl group, and R4 indicates a hydrogen atom or any given group, other than an amino group, bonded to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By extracting gallium from an acidic solution containing gallium and zinc by means of solvent extraction using the extraction agent, it is possible to selectively extract gallium.
摘要翻译： 提供一种提取剂和提取方法，其选择性地提取并且以低成本从含有镓和锌的酸性溶液中回收镓。 镓提取剂包含由通式（1）表示的酰胺衍生物。 在该式中，R和R 2各自表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示氢原子或与α-碳结合的除氨基以外的任何给定基团， 氨基酸。 通式优选具有甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 通过使用提取剂通过溶剂萃取从含有镓和锌的酸性溶液中提取镓，可以选择性地提取镓。
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4.发明授权Valuable metal extraction agent and valuable metal extraction method using said extraction agent 有权有价值的金属提取剂和有价值的金属提取方法使用所述提取剂公开(公告)号：US08951486B2
公开(公告)日：2015-02-10
申请号：US14001832
申请日：2012-11-02
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C01F17/00 , C07C237/06 , C22B3/26 , C22B59/00 , C22B23/00 , C22B3/00 , C07D233/26 , H01M8/00
CPC分类号： C22B23/0461 , B01D11/00 , C01F17/0006 , C07C237/06 , C07D233/26 , C22B3/0005 , C22B3/0032 , C22B23/00 , C22B23/0453 , C22B59/00 , H01M8/008 , H01M10/54 , Y02P10/234 , Y02W30/84 , Y02W30/86
摘要： The objective of the present invention is to selectively extract light rare earth metals, and by extension, europium, from an acidic solution containing a plurality of types of rare earth metal. This valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each indicate the same or different alkyl group; R3 indicates a hydrogen atom or an alkyl group; and R4 indicates a hydrogen atom or any given group other than an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, when extracting europium using the extraction agent, the pH is adjusted into the range of 2.0-3.0 inclusive, and when selectively extracting light rare earth metals, the pH is adjusted to 1.7-2.7 inclusive.
摘要翻译： 本发明的目的是从含有多种类型的稀土金属的酸性溶液中选择性地提取轻稀土金属，并延伸铕。 这种有价值的金属提取剂由通式表示。 式中R1和R2各自表示相同或不同的烷基; R3表示氢原子或烷基; R 4表示氢原子或与作为氨基酸的α碳键合的氨基以外的任意给定基团。 优选地，通式为甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 优选地，当使用提取剂提取铕时，将pH调节到2.0-3.0的范围内，并且当选择性提取轻稀土金属时，将pH调节至1.7-2.7（含）。
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公开(公告)号：US10036082B2
公开(公告)日：2018-07-31
申请号：US15544079
申请日：2015-09-28
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B34/00 , C22B34/14 , C07C237/06 , B01D11/04
CPC分类号： C22B34/14 , B01D11/0492 , C07C237/06 , C22B3/0005 , C22B3/0024 , Y02P10/234
摘要： Provided are: an extractant which is capable of quickly and highly efficiently extracting zirconium from an acidic solution that is obtained by acid leaching a material containing zirconium and scandium such as an SOFC electrode material; and a method for extracting zirconium, which uses this extractant. A zirconium extractant according to the present invention is composed of an amide derivative represented by general formula (I). In the formula, R1 and R2 respectively represent the same or different alkyl groups, each of which may be linear or branched; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or an arbitrary group other than an amino group, said arbitrary group being bonded, as an amino acid, to the α carbon.
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公开(公告)号：US09725786B2
公开(公告)日：2017-08-08
申请号：US14650364
申请日：2013-09-06
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
CPC分类号： C22B23/0484 , B01D11/0492 , C22B3/0005 , C22B3/44 , C22B7/006 , C22B23/0453 , C22B23/0461 , H01M10/54 , Y02P10/234 , Y02W30/84
摘要： In the present invention, nickel is selectively extracted from an acidic solution that contains a high concentration of manganese. This valuable metal extraction agent is represented by the general formula. In the formula, R1 and R2 are alkyl groups that may be the same or different, R3 is a hydrogen atom or an alkyl group, and R4 is a hydrogen atom or any group, other than an amino group, bonded to an α carbon atom of an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit or a n-methylglycine unit. When extracting nickel by using this extraction agent, it is preferable to adjust the pH of the acidic solution to 2.3 to 5.5 inclusive.
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7.发明授权公开(公告)号：US09435006B2
公开(公告)日：2016-09-06
申请号：US14779908
申请日：2014-04-08
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
CPC分类号： C22B11/04 , C07C237/06 , C22B3/0024 , C22B3/20 , C22B61/00 , Y02P10/234
摘要： The present invention extracts precious metals from an acidic solution containing precious metals in an early and highly efficient manner. Provided is an extraction agent for precious metals that is represented by the general formula below. In the formula, R1 and R2 each represent the same alkyl group or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a discretionary group that is not an amino group and that bonds to α carbon as an amino acid. By subjecting an acidic solution containing precious metals to solvent extraction using the extraction agent for precious metals, a plurality of precious metals can be recovered all at once from a solution containing a large amount of various impurities.
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公开(公告)号：US09011804B2
公开(公告)日：2015-04-21
申请号：US14001848
申请日：2012-11-02
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： B01D11/00 , C22B3/00 , C01F17/00 , C22B3/26 , C22B59/00 , C22B23/00 , C07D233/26 , C07C237/06 , H01M8/00 , H01M10/54
CPC分类号： C22B23/0461 , B01D11/00 , C01F17/0006 , C07C237/06 , C07D233/26 , C22B3/0005 , C22B3/0032 , C22B23/00 , C22B23/0453 , C22B59/00 , H01M8/008 , H01M10/54 , Y02P10/234 , Y02W30/84 , Y02W30/86
摘要： The objective of the present invention is to selectively extract cobalt from an acidic solution containing a high concentration of manganese. This cobalt extraction method extracts cobalt from an acidic solution containing manganese and cobalt by subjecting the acidic solution to solvent extraction by means of a valuable metal extraction agent comprising an amide derivative represented by general formula (I). The valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each represent the same or different alkyl group; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or any given group aside from an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, the pH of the acidic solution is 3.5-5.5 inclusive.
摘要翻译： 本发明的目的是从含有高浓度锰的酸性溶液中选择性提取钴。 该钴提取方法通过使含有由通式（I）表示的酰胺衍生物的贵金属萃取剂进行溶剂萃取，从含有锰和钴的酸性溶液中提取钴。 有价值的金属萃取剂由通式表示。 式中R 1和R 2各自表示相同或不同的烷基; R3表示氢原子或烷基; 并且R 4表示氢原子或除了与作为氨基酸的α碳键合的氨基以外的任何给定基团。 优选地，通式为甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 优选地，酸性溶液的pH值为3.5-5.5（含）。
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公开(公告)号：US20140328737A1
公开(公告)日：2014-11-06
申请号：US14001848
申请日：2012-11-02
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B3/00
CPC分类号： C22B23/0461 , B01D11/00 , C01F17/0006 , C07C237/06 , C07D233/26 , C22B3/0005 , C22B3/0032 , C22B23/00 , C22B23/0453 , C22B59/00 , H01M8/008 , H01M10/54 , Y02P10/234 , Y02W30/84 , Y02W30/86
摘要： The objective of the present invention is to selectively extract cobalt from an acidic solution containing a high concentration of manganese. This cobalt extraction method extracts cobalt from an acidic solution containing manganese and cobalt by subjecting the acidic solution to solvent extraction by means of a valuable metal extraction agent comprising an amide derivative represented by general formula (I). The valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each represent the same or different alkyl group; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or any given group aside from an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, the pH of the acidic solution is 3.5-5.5 inclusive.
摘要翻译： 本发明的目的是从含有高浓度锰的酸性溶液中选择性提取钴。 该钴提取方法通过使含有由通式（I）表示的酰胺衍生物的贵金属萃取剂进行溶剂萃取，从含有锰和钴的酸性溶液中提取钴。 有价值的金属萃取剂由通式表示。 式中R 1和R 2各自表示相同或不同的烷基; R3表示氢原子或烷基; 并且R 4表示氢原子或除了与作为氨基酸的α碳键合的氨基以外的任何给定基团。 优选地，通式为甘氨酸单元，组氨酸单元，赖氨酸单元，天冬氨酸单元或N-甲基甘氨酸单元。 优选地，酸性溶液的pH值为3.5-5.5（含）。
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公开(公告)号：US20180010211A1
公开(公告)日：2018-01-11
申请号：US15544079
申请日：2015-09-28
发明人： Masahiro Goto , Fukiko Kubota , Yuzo Baba
IPC分类号： C22B34/14 , C07C237/06 , B01D11/04
CPC分类号： C22B34/14 , B01D11/0492 , C07C237/06 , C22B3/0005 , C22B3/0024 , Y02P10/234
摘要： Provided are: an extractant which is capable of quickly and highly efficiently extracting zirconium from an acidic solution that is obtained by acid leaching a material containing zirconium and scandium such as an SOFC electrode material; and a method for extracting zirconium, which uses this extractant. A zirconium extractant according to the present invention is composed of an amide derivative represented by general formula (I). In the formula, R1 and R2 respectively represent the same or different alkyl groups, each of which may be linear or branched; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or an arbitrary group other than an amino group, said arbitrary group being bonded, as an amino acid, to the α carbon.
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