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公开(公告)号：US5238977A
公开(公告)日：1993-08-24
申请号：US902466
申请日：1992-06-19
IPC分类号： C08F283/12 , C08L51/08
CPC分类号： C08L51/085 , C08F283/124 , Y10S525/902
摘要： Free-flowing, stable dispersions of crosslinked rubbers in the form of discrete particles having an average diameter of 0.1 to 3 .mu.m in organic liquids, containingI) up to 60% by weight (based on the dispersion as a whole) of a crosslinked, rubber-like, particulate graft polymer of a) a crosslinked silicone rubber as core and crosslinked acrylate rubber b) graft polymerized thereon as the rubber andII) a liquid, organic N,N-substituted amide as the continuous organic phase,and a process for their production.
摘要翻译： 交联橡胶在有机液体中具有平均直径为0.1至3μm的离散颗粒形式的自由流动稳定的分散体，其含有I）至多60重量％（基于分散体作为整体）交联的 ，a）交联硅橡胶为核心的交联丙烯酸酯橡胶和交联丙烯酸酯橡胶的橡胶状颗粒接枝聚合物，b）作为橡胶接枝在其上，II）作为连续有机相的液态有机N，N-取代酰胺，和 生产过程。
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公开(公告)号：US5147955A
公开(公告)日：1992-09-15
申请号：US729995
申请日：1991-07-15
申请人： Christian Lindner , Siegfried Korte
发明人： Christian Lindner , Siegfried Korte
IPC分类号： C08F22/36 , C08F30/02 , C08F222/06 , C08F230/02
CPC分类号： C08F230/02 , C08F222/06
摘要： Copolymers ofa) phosphonic acid derivatives corresponding to formula (I) ##STR1## wherein Y represents H or CH.sub.3,X represents a single bond or --CH.sub.2 --,R represents an aryl or alkyl,b) maleic anhydride andc) a polymerizable compound containing two or more allyl or methally groups in the molecule.
摘要翻译： 对应于式（I）的膦酸衍生物的共聚物其中Y表示H或CH 3，X表示单键或-CH 2 - ，R表示芳基或烷基，b）马来酸酐和c） 在分子中含有两个以上烯丙基或亚甲基的可聚合化合物。
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公开(公告)号：US4871850A
公开(公告)日：1989-10-03
申请号：US141875
申请日：1988-01-06
IPC分类号： C07D487/04 , C07D487/10 , C08F4/00
CPC分类号： C07D487/04 , C07D487/10 , C08F4/00
摘要： Triazolopyrimidines of the formula I ##STR1## in which R.sup.1 denotes CN, alkylsulphonyl, arylsulphonyl or arylR.sup.2 denotes H, alkyl or alkythio,R.sup.3 denotes alkyl, aralkyl, substituted aralkyl, alkenyl or alkynyl,R.sup.4 denotes alkyl, aralkyl or aryl, andR.sup.5 denotes alkyl, aralkyl or aryl, orR.sup.4 and R.sup.5, together with the carbon atom, denote a carbocyclic 5-, 6- or 7-membered ring which may be substituted or bridged,in which R.sup.4 cannot be methyl or aryl when R.sup.1 represents CN, R.sup.2 represents H, R.sup.3 represents methyl and R.sup.5 represents methyl or aryl, and in which alkyl preferably has 1-9 C atoms and aryl preferably has 6-12 C atoms, and also a process for their preparation, and their use as initiators.
摘要翻译： 式I的三唑并嘧啶其中R1表示CN，烷基磺酰基，芳基磺酰基或芳基R2表示H，烷基或链烯基，R3表示烷基，芳烷基，取代的芳烷基，烯基或炔基，R4表示烷基，芳烷基或芳基， R 5表示烷基，芳烷基或芳基，或者R 4和R 5与碳原子一起表示可以被取代或桥连的碳环5-，6-或7-元环，当R 1不为甲基或芳基时，R 1表示 CN，R 2表示H，R 3表示甲基，R 5表示甲基或芳基，并且其中烷基优选具有1-9个C原子，并且芳基优选具有6-12个C原子，并且其制备方法及其作为引发剂的用途 。
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公开(公告)号：US4426499A
公开(公告)日：1984-01-17
申请号：US344486
申请日：1982-02-01
IPC分类号： C08F291/00 , C08F2/04 , C08F2/06 , C08F2/14 , C08F2/18 , C08F4/34 , C08F4/40 , C08F265/00 , C08F265/04 , C08F279/00 , C08F279/02 , C08F291/02 , C08F279/04
CPC分类号： C08F265/04 , C08F279/02
摘要： This invention relates to a process for the graft polymerization of (A) from 95 to 40 parts, by weight, of at least one ethylenically unsaturated monomer in the presence of (B) from 5 to 60 parts, by weight, of a partially or completely cross-linked rubber, in which the one or more than one monomer (A) and rubber (B) in the form of a latex or of a dispersion in an organic solvent are polymerized in an aliphatic hydrocarbon as reaction medium at from 30.degree. to 100.degree. C., using a radical forming initiator, and the graft polymerization product obtained as a sedimenting suspension of particles having an average diameter of from 5 to 1,000 .mu.m is isolated.
摘要翻译： 本发明涉及一种在（B）5〜60重量份的（B）的部分或不饱和单体的存在下（A）95重量份至40重量份的至少一种烯属不饱和单体的接枝聚合方法 完全交联的橡胶，其中一种或多种胶乳形式的单体（A）和橡胶（B）或在有机溶剂中的分散体在脂肪族烃中作为反应介质在30℃下聚合 至100℃，使用自由基形成引发剂，分离得到作为平均直径为5〜1000μm的颗粒的沉降悬浮液得到的接枝聚合产物。
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5.发明授权Acrylonitrile polymer blended with a statistical copolymer of acrylic acid alkyl ester and styrene 失效丙烯腈聚合物与丙烯酸烷基酯和苯乙烯的统计共聚物共混
公开(公告)号：US4151228A
公开(公告)日：1979-04-24
申请号：US773392
申请日：1977-03-02
IPC分类号： C08L33/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/02 , C08L33/18 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L101/00
摘要： A thermoplastic moulding composition with improved flow properties being workable without difficulty by extrusion, injection moulding or blow moulding and resulting in colorless, transparent products with a smooth, glossy surface, comprising a mixture of(A)90 to 99.9% by weight of a polymer with a K-value of from 50 to 80, as measured at a temperature of 25.degree. C. in dimethyl formamide on a 0.5% by weight solution, which contains at least 50% by weight of acrylonitrile or methacrylonitrile or a mixture thereof in polymerized or grafted form, and(B)0.1 to 10% by weight of a statistical copolymer of copolymerized units of65 to 85% by weight of at least one acrylic acid alkyl ester with 1 to 8 carbon atoms in the alcohol component, and15 to 35% by weight of styrene,The copolymer B having an intrinsic viscosity [.eta.] of from 2.9 to 13.0 dl/g, as measured at 25.degree. C. in tetrahydrofuran.
摘要翻译： 具有改善的流动性能的热塑性模塑组合物通过挤出，注射成型或吹塑成型而无困难地工作，并产生具有光滑光泽表面的无色透明产品，其包含（A）90-99.9重量％的聚合物 其中K值为50至80，在25℃的温度下在二甲基甲酰胺中在0.5重量％的溶液中测量，其中含有至少50重量％的丙烯腈或甲基丙烯腈或其混合物在聚合 或接枝形式，和（B）0.1至10重量％的65至85重量％的共聚单元的统计共聚物，其中至少一个丙烯酸烷基酯与一至八个碳原子在醇醇组分中的重量比，和15至 35％的苯乙烯重量，共聚物B的特性粘度η为2.9至13.0dl / g，在25℃下在四氢呋喃中测得。
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6.发明授权Process for the production of low molecular weight acrylonitrile polymers and their use 失效制备低分子量丙烯腈聚合物的方法及其用途
公开(公告)号：US5393845A
公开(公告)日：1995-02-28
申请号：US168609
申请日：1993-12-16
申请人： Siegfried Korte , Heinrich Alberts , Branislav Bohmer , Werner Karstens , Wolfgang Koch , Hans-Gunter Poersch-Panke , Klaus Szablikowski
发明人： Siegfried Korte , Heinrich Alberts , Branislav Bohmer , Werner Karstens , Wolfgang Koch , Hans-Gunter Poersch-Panke , Klaus Szablikowski
CPC分类号： C08F8/12
摘要： The invention relates to a process for the continuous production of polyacrylonitrile hydrolyzates and to their use as dispersion and grinding aids for pigments and fillers, such as for example kaolin, CaCO.sub.3 or gypsum.
摘要翻译： 本发明涉及一种用于连续生产聚丙烯腈水解产物的方法及其作为颜料和填料如高岭土，CaCO 3或石膏的分散和研磨助剂的用途。
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公开(公告)号：US4501865A
公开(公告)日：1985-02-26
申请号：US505655
申请日：1983-06-20
申请人： Joachim Konig , Carlhans Suling , Siegfried Korte
发明人： Joachim Konig , Carlhans Suling , Siegfried Korte
摘要： It is possible to remove quantities of heat from exothermically running polymerization reactions of vinyl monomers in heterogeneous phase, in a sophisticated manner by adding liquids to the reaction medium for the removal of heat and to regulate the reaction temperature, which liquids do not dissolve the polymer under the reaction conditions and the boiling temperatures of which are lower than or are identical to the technically predetermined reaction temperatures under the polymerization conditions which are applied, and the heat which is released in the reaction system is removed by evaporating these liquids.
摘要翻译： 可以通过向反应介质中加入液体以除去热量并调节反应温度（这些液体不溶解聚合物），以复杂的方式从异构相中的乙烯基单体的放热运行的聚合反应中除去热量 在反应条件下，其沸点温度低于或等于在所施加的聚合条件下的技术上预定的反应温度，并且通过蒸发这些液体除去反应体系中释放的热量。
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公开(公告)号：US4384091A
公开(公告)日：1983-05-17
申请号：US310575
申请日：1981-10-09
申请人： Siegfried Korte , Theo Neukam , Carlhans Suling
发明人： Siegfried Korte , Theo Neukam , Carlhans Suling
IPC分类号： C08F220/00 , C08F2/06 , C08F2/18 , C08F20/44 , C08F220/42
CPC分类号： C08F20/44
摘要： Acrylonitrile polymers and copolymers with good affinity for basic dyes without sulfonic acid groups containing comonomers are obtained by polymerizing at a temperature of from 0.degree. to 60.degree. C. in an aliphatic hydrocarbon having a boiling point of from -10.degree. to 80.degree. C. or in a mixture of aliphatic hydrocarbons having boiling points in the range from -10.degree. to 80.degree. C. using an initiator system comprising from 0.1 to 8.0 mole percent of sulfur dioxide, from 0.1 to 2.0 mole percent of a hydroperoxide which is soluble in the reaction medium and from 0.01 to 1.0 mole percent of an acid which is soluble in the reaction system in that polymerization is carried out continuously and in that an average residence time of from 10 minutes to 2 hours is maintained.
摘要翻译： 通过在0〜60℃的温度下在沸点为-10〜80℃的脂肪族烃中进行聚合，得到丙烯腈聚合物和对具有不含磺酸基团的共聚单体的碱性染料具有良好亲和性的共聚物。 或者在沸点为-10℃至80℃的脂族烃的混合物中，使用引发剂体系，其包含0.1至8.0摩尔％的二氧化硫，0.1至2.0摩尔％的可溶于 在该聚合反应中可以连续进行反应介质和0.01〜1.0摩尔％的可溶于反应体系的酸，维持10分钟〜2小时的平均停留时间。
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公开(公告)号：US3936513A
公开(公告)日：1976-02-03
申请号：US371547
申请日：1973-06-19
申请人： Gunter Lorenz , Siegfried Korte , Carlhans Suling
发明人： Gunter Lorenz , Siegfried Korte , Carlhans Suling
IPC分类号： C08L33/00 , C08L1/00 , C08L27/00 , C08L27/02 , C08L33/02 , C08L33/18 , C08L33/20 , D01F6/18 , D01F6/38 , C08L33/24
摘要： Vacuole-free films, filaments and fibers consisting of a polymer mixture which comprises a copolymer of acrylonitrile and a polymer which is obtained by a polymer-analogue reaction of a polyacrylic acid ester with dimethylamine, said polymer containing from 40-99 mol % of N,N-dimethyl acrylamide units.
摘要翻译： 由聚丙烯腈共聚物和由聚丙烯酸酯与二甲胺的聚合物 - 类似物反应获得的聚合物的聚合物混合物组成的无真空膜，长丝和纤维，所述聚合物含有40-99mol％的N ，N-二甲基丙烯酰胺单元。
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公开(公告)号：US06637181B1
公开(公告)日：2003-10-28
申请号：US09701709
申请日：2000-12-01
申请人： Siegfried Korte , Rolf-Volker Meyer , Stefan Hütte
发明人： Siegfried Korte , Rolf-Volker Meyer , Stefan Hütte
IPC分类号： D02G302
CPC分类号： D01F6/70 , Y10T442/40
摘要： Described is a process for producing segmented polyurethanes having improved processing characteristics in the melt state and an efficient spinning process based thereon to form highly elastic, fine linear density elastane yarn and filament having improved mechanical and thermal properties by using hydroxyalkyl-terminated polysiloxanes in combination with specific crosslinking-capable polyisocyanates in the reaction of long-chain high molecular weight polyhydroxy compounds with organic diisocyanates and low molecular weight diols and also optionally further auxiliary and additive substances in the melt.
摘要翻译： 描述了一种在熔融状态下具有改进的加工特性的分段聚氨酯的制造方法和基于其的有效的纺丝工艺，以形成高弹性，细密度的线性密度的弹性纤维丝和具有改善的机械和热性能的长丝，通过使用羟烷基封端的聚硅氧烷与 在长链高分子量多羟基化合物与有机二异氰酸酯和低分子量二醇的反应中以及任选地在熔体中的另外的辅助和添加剂物质的反应中具有特异性交联的多异氰酸酯。
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