摘要:
The present invention relates to a process for the preparation of branched thermoplastic polycarbonates, characterized in that diphenols are completely reacted with about 0.05 to about 2.0 mol %, relative to mols of diphenols, of cyanuric chloride in a primary reaction, while controlling the pH and temperature and in the presence of a co-solvent, and thereafter the products are subjected to polycondensation, in accordance with known methods of the phase boundary process, to give high-molecular weight, branched polycarbonates. The invention further relates to the branched polycarbonates prepared by this process.
摘要:
The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
摘要:
This invention relates to optionally branched polyarylene sulphides and a process for the production thereof in a polar solvent, from 0.2 to 100 mole %, based on the aromatic dihalogen compounds, of an amino acid being added to the reaction mixture.
摘要:
This invention relates to a process for the production of high molecular weight, optionally branched polyarylene sulphides from alkali metal sulphides and halogenated aromatic compounds in the presence of from 0.5 to 100 mol %, based on the molar quantity of aromatic dihalogen compounds, of an ester or anhydride of a carboxylic acid.
摘要:
A process for preparing a polyarylene sulphide which comprises reacting(a) dihalogenobenzene consisting of 50 to 100 mol % of a compound of the formula ##STR1## or a compound of the formula ##STR2## or a mixture thereof and of 0 to 50 mol % of a compound of the formula ##STR3## wherein X is halogen and each R is selected from the group consisting of hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 20 carbon atoms, aryl having 6 to 24 carbon atoms, alkaryl having 7 to 24 carbon atoms and aralkyl having 7 to 24 carbon atoms with the proviso that at least one R is other than hydrogen and(b) 0 to 3.0 mol % based on the dihalogenobenzene content of a polyhalogeno aromatic of the formulaArX.sub.n (IV) wherein Ar is an aromatic or heterocyclic radical with 6 to 24 carbon atoms having at least 3 free valencies, X is halogen and n is .gtoreq. 3 with(c) an alkyl metal sulphide in(d) a polar solvent in the presence of(e) 0.05-2.0 mol of alkali metal fluoride per mol of alkali metal sulphide,for a polycondensation time of up to 30 hours and at a polycondensation temperature of between 160.degree. and 295.degree. C., the molar ratio of (a) to (c) being in the range from 0.85:1 to 1.15:1 and the molar ratio of (c) to (d) being in the range of from 1:2 to 1:15.
摘要:
The present invention relates to polycondensates of the formula 10, their use for absorbing metal ions of the transition elements of the periodic system and their use for the preparation of polymers containing metals of formula 11 which have e.g. improved resistance to heat and to chemicals compared to the corresponding polycondensates of formula 10.
摘要:
Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1 -C.sub.12 hydrocarbon radical, halogen andR.sup.5, R.sup.6 and R.sup.7 represent hydrogen, iso-C.sub.3 -C.sub.5 -alkyl,one of the substituents R.sup.5, R.sup.6 or R.sup.7 not being hydrogen, in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.
摘要:
Flame-resistant, thermoplastic polyamide moulding materials which contain 0.01-4% by weight of polyphenylene oxides as flameproofing agent and which are prepared by mixing the components in the melt.
摘要:
A process for removing onium salts from aqueous solutions comprising adding a phenolic compound to an onium salt containing aqueous solution, contacting the solution with a water-immiscible organic material whereby the onium salt migrates into the water-immiscible organic material and separating the aqueous hase from the onium salt in the water-immiscible organic material.