公开(公告)号：US09481145B2

公开(公告)日：2016-11-01

申请号：US14003916

申请日：2012-02-24

申请人： Kazuhiro Hatanaka ,  Hiroaki Sakata ,  Hiroshi Taiko

发明人： Kazuhiro Hatanaka ,  Hiroaki Sakata ,  Hiroshi Taiko

IPC分类号： B32B5/14 ,  B32B37/14 ,  C08J5/24 ,  B32B5/02 ,  C08K3/08

CPC分类号： B32B5/145 ,  B32B5/02 ,  B32B37/14 ,  B32B2260/046 ,  B32B2262/106 ,  C08J5/24 ,  C08J2300/24 ,  C08J2363/00 ,  C08J2400/22 ,  C08J2481/06 ,  C08K2003/0806 ,  Y10T156/10 ,  Y10T428/24893

摘要： The present invention relates to a sheet-form prepreg which comprises a plurality of carbon fibers and a matrix resin with which the plurality of carbon fibers are impregnated. This matrix resin contains a thermosetting resin, a curing agent, conductive particles of 1 μm or smaller in diameter, conductive particles of 5 μm or larger in diameter and thermoplastic resin particles, and the conductive particles of 1 μm or smaller in diameter, the conductive particles of 5 μm or larger in diameter and the thermoplastic resin particles are each disproportionately distributed in a specific part of the prepreg.By the present invention, a prepreg from which a carbon fiber-reinforced composite material having both excellent impact resistance and good conductivity in the lamination direction can be produced is provided.

摘要翻译： 通过本发明，提供了可以制造在层叠方向上具有优异的耐冲击性和良好的导电性的碳纤维增强复合材料的预浸料坯。

公开(公告)号：US20130344305A1

公开(公告)日：2013-12-26

申请号：US14003916

申请日：2012-02-24

申请人： Kazuhiro Hatanaka ,  Hiroaki Sakata ,  Hiroshi Taiko

发明人： Kazuhiro Hatanaka ,  Hiroaki Sakata ,  Hiroshi Taiko

IPC分类号： B32B5/14 ,  B32B37/14

CPC分类号： B32B5/145 ,  B32B5/02 ,  B32B37/14 ,  B32B2260/046 ,  B32B2262/106 ,  C08J5/24 ,  C08J2300/24 ,  C08J2363/00 ,  C08J2400/22 ,  C08J2481/06 ,  C08K2003/0806 ,  Y10T156/10 ,  Y10T428/24893

摘要： The present invention relates to a sheet-form prepreg which comprises a plurality of carbon fibers and a matrix resin with which the plurality of carbon fibers are impregnated. This matrix resin contains a thermosetting resin, a curing agent, conductive particles of 1 μm or smaller in diameter, conductive particles of 5 μm or larger in diameter and thermoplastic resin particles, and the conductive particles of 1 μm or smaller in diameter, the conductive particles of 5 μm or larger in diameter and the thermoplastic resin particles are each disproportionately distributed in a specific part of the prepreg.By the present invention, a prepreg from which a carbon fiber-reinforced composite material having both excellent impact resistance and good conductivity in the lamination direction can be produced is provided.

摘要翻译： 本发明涉及片状预浸料，其包含多个碳纤维和浸渍有多个碳纤维的基质树脂。 该基体树脂含有热固性树脂，固化剂，直径为1μm或更小的导电颗粒，直径为5μm或更大的导电颗粒和热塑性树脂颗粒，导电颗粒直径为1μm或更小，导电 直径5μm或更大的颗粒和热塑性树脂颗粒各自不成比例地分布在预浸料的特定部分中。 通过本发明，提供了可以制造在层叠方向上具有优异的耐冲击性和良好的导电性的碳纤维增强复合材料的预浸料坯。

公开(公告)号：US09834670B2

公开(公告)日：2017-12-05

申请号：US13823905

申请日：2011-09-22

申请人： Maki Mizuki ,  Yuko Goto ,  Nobuyuki Tomioka ,  Hiroaki Sakata ,  Hiroshi Taiko

发明人： Maki Mizuki ,  Yuko Goto ,  Nobuyuki Tomioka ,  Hiroaki Sakata ,  Hiroshi Taiko

IPC分类号： B32B27/38 ,  B32B27/04 ,  B32B27/18 ,  B32B27/26 ,  C08L63/00 ,  C08G59/28 ,  C08G59/38 ,  C08G59/50 ,  C08G59/42 ,  C08J5/24

CPC分类号： C08L63/00 ,  C08G59/28 ,  C08G59/38 ,  C08G59/4246 ,  C08G59/5033 ,  C08G59/504 ,  C08G2261/126 ,  C08J5/24 ,  C08J2363/00 ,  C08J2433/08 ,  Y10T428/249942 ,  Y10T428/249945 ,  C08L33/08

摘要： Provided are a fiber-reinforced composite material excellent in heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Further provided are a fiber-reinforced composite material having less volatile matters during the curing time, and having excellent heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Provided are: an epoxy resin composition for a fiber-reinforced composite material, comprising an amine type epoxy resin [A], an aromatic amine curing agent [B], and a block copolymer [C] having a reactive group capable of reacting with an epoxy resin; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg. Further provided are: an epoxy resin composition comprising an epoxy resin [A] having two or more of four- or more-membered ring structures, and having either one of a glycidyl amino group directly bonded to the ring structure or a glycidyl ether group directly bonded to the ring structure, epoxy resin [B] having three or more of functional groups, a curing agent [C], and an elastomer component [D]; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg.

公开(公告)号：US20120035299A1

公开(公告)日：2012-02-09

申请号：US13260082

申请日：2010-01-13

申请人： Atsuhito Arai ,  Hiroaki Sakata ,  Kenichi Yoshioka ,  Hiroshi Taiko ,  Jiro Nakatani ,  Kotaro Ono ,  Michiya Ishikawa

发明人： Atsuhito Arai ,  Hiroaki Sakata ,  Kenichi Yoshioka ,  Hiroshi Taiko ,  Jiro Nakatani ,  Kotaro Ono ,  Michiya Ishikawa

IPC分类号： C08K3/04 ,  C08L63/00

CPC分类号： C08G59/38 ,  C08G59/28 ,  C08G59/504 ,  C08J5/24 ,  C08J2363/00 ,  C08L63/00 ,  C08L2205/02 ,  Y10T428/24994 ,  Y10T428/31511 ,  C08L2666/22

摘要： Disclosed is a fiber-reinforced composite material that is high in heat resistance and strength while being low in the content of volatile matter that volatilizes during curing. Also disclosed are an epoxy resin composition for production thereof, and a prepreg produced from the epoxy resin composition. Specifically the invention provides an epoxy resin composition comprising: [A] an epoxy resin comprising two or more ring structures each consisting of four or more members, and at least one amine type or ether type glycidyl group directly connected to the ring structures, [B] a tri—or more—functional epoxy resin, and [C] a curing agent, and also provides a prepreg produced by impregnating reinforcing fiber with the epoxy resin composition and a fiber-reinforced composite material produced by curing the prepreg.

摘要翻译： 公开了一种耐热性和强度高的纤维增强复合材料，而固化期间挥发的挥发物的含量低。 还公开了用于生产环氧树脂组合物和由环氧树脂组合物制备的预浸料。 具体地说，本发明提供一种环氧树脂组合物，其包含：[A]包含两个或更多个环结构的环氧树脂，每个环结构各自由四个或更多个成员组成，以及至少一个直接与环结构连接的胺型或醚型缩水甘油基[B ]三官能或更多功能的环氧树脂和[C]固化剂，并且还提供通过用环氧树脂组合物浸渍增强纤维制成的预浸料和通过固化预浸料制备的纤维增强复合材料。

公开(公告)号：US20130281573A1

公开(公告)日：2013-10-24

申请号：US13978738

申请日：2012-01-20

申请人： Yuko Goto ,  Nobuyuki Tomioka ,  Yuji Echigo ,  Hiroaki Sakata ,  Shiro Honda ,  Hiroshi Taiko

发明人： Yuko Goto ,  Nobuyuki Tomioka ,  Yuji Echigo ,  Hiroaki Sakata ,  Shiro Honda ,  Hiroshi Taiko

IPC分类号： C08L63/00

CPC分类号： C08L63/00 ,  C08J5/24 ,  C08J2363/00 ,  C08L53/02 ,  C08L77/06

摘要： Provided are: a fiber-reinforced composite material which has mode I interlaminar fracture toughness, mode II interlaminar fracture toughness and compressive strength under heat and humidity conditions at the same time; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements (A), (B), (C) and (D). (A) An epoxy resin (B) Resin particles that satisfy the following conditions (b1)-(b3) and are insoluble in an epoxy resin (b1) The particle size distribution index is 1.0-1.8. (b2) The particle sphericity is 90 or more. (b3) The glass transition temperature of the particles is 80-180° C. (C) At least one elastomer component that is selected from among block copolymers containing a block having a glass transition temperature of 20° C. or less and rubber particles (D) An epoxy resin curing agent

摘要翻译： 提供：同时在热和湿度条件下具有模式I层间断裂韧性，模式II层间断裂韧性和抗压强度的纤维增强复合材料; 用于获得纤维增强复合材料的环氧树脂组合物; 和使用该环氧树脂组合物得到的预浸料坯。 至少含有以下组成元素（A），（B），（C）和（D）的纤维增强复合材料用环氧树脂组合物。 （A）环氧树脂（B）满足以下条件（b1） - （b3）并且不溶于环氧树脂（b1）的树脂颗粒粒径分布指数为1.0-1.8。 （b2）粒子球形度为90以上。 （b3）颗粒的玻璃化转变温度为80-180℃。（C）选自含有玻璃化转变温度为20℃以下的嵌段的嵌段共聚物和橡胶粒子中的至少一种弹性体成分 （D）环氧树脂固化剂

公开(公告)号：US20130202873A1

公开(公告)日：2013-08-08

申请号：US13823905

申请日：2011-09-22

申请人： Maki Mizuki ,  Yuko Goto ,  Nobuyuki Tomioka ,  Hiroaki Sakata ,  Hiroshi Taiko

发明人： Maki Mizuki ,  Yuko Goto ,  Nobuyuki Tomioka ,  Hiroaki Sakata ,  Hiroshi Taiko

IPC分类号： C08L63/00

CPC分类号： C08L63/00 ,  C08G59/28 ,  C08G59/38 ,  C08G59/4246 ,  C08G59/5033 ,  C08G59/504 ,  C08G2261/126 ,  C08J5/24 ,  C08J2363/00 ,  C08J2433/08 ,  Y10T428/249942 ,  Y10T428/249945 ,  C08L33/08

摘要： Provided are a fiber-reinforced composite material excellent in heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Further provided are a fiber-reinforced composite material having less volatile matters during the curing time, and having excellent heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Provided are: an epoxy resin composition for a fiber-reinforced composite material, comprising an amine type epoxy resin [A], an aromatic amine curing agent [B], and a block copolymer [C] having a reactive group capable of reacting with an epoxy resin; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg. Further provided are: an epoxy resin composition comprising an epoxy resin [A] having two or more of four- or more-membered ring structures, and having either one of a glycidyl amino group directly bonded to the ring structure or a glycidyl ether group directly bonded to the ring structure, epoxy resin [B] having three or more of functional groups, a curing agent [C], and an elastomer component [D]; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg.

摘要翻译： 提供耐热性和强度特性优异的纤维增强复合材料，获得纤维增强复合材料的环氧树脂组合物和使用该环氧树脂组合物得到的预浸料。 还提供了一种在固化时间内具有较少挥发性物质并具有优异的耐热性和强度特性的纤维增强复合材料，获得纤维增强复合材料的环氧树脂组合物和通过使用环氧树脂组合物获得的预浸料 。 提供：用于纤维增强复合材料的环氧树脂组合物，其包含胺型环氧树脂[A]，芳香族胺固化剂[B]和具有能与其反应的反应性基团的嵌段共聚物[C] 环氧树脂; 通过用环氧树脂组合物浸渍增强纤维而获得的预浸料坯; 以及通过固化预浸料获得的纤维增强复合材料。 进一步提供：环氧树脂组合物，其包含具有两个或更多个四元或多元环结构的环氧树脂[A]，并且直接与环结构直接键合的缩水甘油氨基或缩水甘油醚基团中的任一个 结合到环结构上，具有三个或更多个官能团的环氧树脂[B]，固化剂[C]和弹性体组分[D]; 通过用环氧树脂组合物浸渍增强纤维而获得的预浸料坯; 以及通过固化预浸料获得的纤维增强复合材料。

公开(公告)号：US20130005855A1

公开(公告)日：2013-01-03

申请号：US13634518

申请日：2010-12-24

申请人： Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko ,  Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani

发明人： Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko ,  Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani

IPC分类号： C08G59/32 ,  C08L63/00

CPC分类号： C08G59/3227 ,  C08J5/24 ,  C08J2363/00 ,  C08L63/00 ,  C08L2205/02

摘要： Disclosed is a carbon-fiber-reinforced composite material that is suitable for use as a construction material and exhibits high mechanical strength in harsh usage environments such as low-temperature environments and high-temperature moisture-absorbing environments. Also disclosed are an epoxy resin composition for producing the aforementioned carbon-fiber-rein-forced composite material and a prepreg obtained through the use of said epoxy resin composition. Said epoxy resin composition comprises at least the following constituents, by mass with respect to the total mass of the composition: (A) between 20% and 80% of an epoxy resin having the structure represented by formula (1); and (B) between 10% and 50% of an epoxy resin that has at least two ring structures with four or more members each and also has one amine glycidyl or ether glycidyl directly connected to a ring structure.

摘要翻译： 公开了一种适用于建筑材料的碳纤维增强复合材料，在恶劣的使用环境（如低温环境和高温吸湿环境）下表现出较高的机械强度。 还公开了用于制造上述碳纤维增强强化复合材料的环氧树脂组合物和通过使用所述环氧树脂组合物获得的预浸料。 所述环氧树脂组合物相对于组合物的总质量至少包含以下组分：（A）20％至80％的具有由式（1）表示的结构的环氧树脂; 和（B）10％至5​​0％的环氧树脂，其具有至少两个具有四个或更多个成员的环结构，并且还具有直接连接到环结构的一个胺缩水甘油基或醚缩水甘油基。

公开(公告)号：US08263216B2

公开(公告)日：2012-09-11

申请号：US13260082

申请日：2010-01-13

申请人： Atsuhito Arai ,  Hiroaki Sakata ,  Kenichi Yoshioka ,  Hiroshi Taiko ,  Jiro Nakatani ,  Kotaro Ono ,  Michiya Ishikawa

发明人： Atsuhito Arai ,  Hiroaki Sakata ,  Kenichi Yoshioka ,  Hiroshi Taiko ,  Jiro Nakatani ,  Kotaro Ono ,  Michiya Ishikawa

IPC分类号： B32B27/04 ,  B32B27/38 ,  C08L63/00 ,  C08G59/28 ,  C08G59/38 ,  C08G59/50

CPC分类号： C08G59/38 ,  C08G59/28 ,  C08G59/504 ,  C08J5/24 ,  C08J2363/00 ,  C08L63/00 ,  C08L2205/02 ,  Y10T428/24994 ,  Y10T428/31511 ,  C08L2666/22

摘要： Disclosed is a fiber-reinforced composite material that is high in heat resistance and strength while being low in the content of volatile matter that volatilizes during curing. Also disclosed are an epoxy resin composition for production thereof, and a prepreg produced from the epoxy resin composition. Specifically the invention provides an epoxy resin composition comprising: [A] an epoxy resin comprising two or more ring structures each consisting of four or more members, and at least one amine type or ether type glycidyl group directly connected to the ring structures, [B] a tri- or more-functional epoxy resin, and [C] a curing agent, and also provides a prepreg produced by impregnating reinforcing fiber with the epoxy resin composition and a fiber-reinforced composite material produced by curing the prepreg.

摘要翻译： 公开了一种耐热性和强度高的纤维增强复合材料，而固化期间挥发的挥发物的含量低。 还公开了用于生产环氧树脂组合物和由环氧树脂组合物制备的预浸料。 具体地说，本发明提供一种环氧树脂组合物，其包含：[A]包含两个或更多个环结构的环氧树脂，每个环结构各自由四个或更多个成员组成，以及至少一个直接与环结构连接的胺型或醚型缩水甘油基，[B ]三官能或更多功能的环氧树脂和[C]固化剂，并且还提供通过用环氧树脂组合物浸渍增强纤维制成的预浸料和通过固化预浸料制备的纤维增强复合材料。

公开(公告)号：US09434811B2

公开(公告)日：2016-09-06

申请号：US13634518

申请日：2010-12-24

申请人： Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko ,  Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani

发明人： Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko ,  Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani

IPC分类号： C08G59/22 ,  C08G59/28 ,  C08G59/32 ,  C08G59/38 ,  C08J5/24 ,  C08L63/00

CPC分类号： C08G59/3227 ,  C08J5/24 ,  C08J2363/00 ,  C08L63/00 ,  C08L2205/02

摘要： Disclosed is a carbon-fiber-reinforced composite material that is suitable for use as a construction material and exhibits high mechanical strength in harsh usage environments such as low-temperature environments and high-temperature moisture-absorbing environments. Also disclosed are an epoxy resin composition for producing the aforementioned carbon-fiber-rein-forced composite material and a prepreg obtained through the use of said epoxy resin composition. Said epoxy resin composition comprises at least the following constituents, by mass with respect to the total mass of the composition: (A) between 20% and 80% of an epoxy resin having the structure represented by formula (1); and (B) between 10% and 50% of an epoxy resin that has at least two ring structures with four or more members each and also has one amine glycidyl or ether glycidyl directly connected to a ring structure.

摘要翻译： 公开了一种适用于建筑材料的碳纤维增强复合材料，在恶劣的使用环境（如低温环境和高温吸湿环境）下表现出较高的机械强度。 还公开了用于制造上述碳纤维增强强化复合材料的环氧树脂组合物和通过使用所述环氧树脂组合物获得的预浸料。 所述环氧树脂组合物相对于组合物的总质量至少包含以下组分：（A）20％至80％的具有由式（1）表示的结构的环氧树脂; 和（B）10％至5​​0％的环氧树脂，其具有至少两个具有四个或更多个成员的环结构，并且还具有直接连接到环结构的一个胺缩水甘油基或醚缩水甘油基。

公开(公告)号：US08664413B2

公开(公告)日：2014-03-04

申请号：US13636153

申请日：2011-03-02

申请人： Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani ,  Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko

发明人： Michiya Ishikawa ,  Hidetoshi Kato ,  Jiro Nakatani ,  Atsuhito Arai ,  Hiroaki Sakata ,  Hiroshi Taiko

IPC分类号： C07D301/24 ,  C07D303/08

CPC分类号： C07D301/27 ,  B01J31/0239 ,  B01J31/0268 ,  B01J2231/40 ,  C07D303/36

摘要： An epoxy compound of high-purity N,N,N′,N′-tetraglycidyl-3,4′-diaminodiphenyl ether is produced by: an addition reaction step of reacting 3,4′-diaminodiphenyl ether with epichlorohydrin in a polar protic solvent at 65 to 100° C. for 12 hours or longer to form N,N,N′,N′-tetrakis(3-chloro-2-hydroxypropyl)-3,4′-diaminodiphenyl ether; and a cyclization reaction step of reacting the N,N,N′,N′-tetrakis(3-chloro-2-hydroxypropyl)-3,4′-diaminodiphenyl ether with an alkali compound for dehydrochlorination.

摘要翻译： 通过以下步骤制备高纯度N，N，N'，N'-四缩水甘油基-3,4'-二氨基二苯醚的环氧化合物：在极性质子溶剂中使3,4'-二氨基二苯醚与表氯醇反应的加成反应步骤 在65〜100℃下反应12小时以上以形成N，N，N'，N'-四（3-氯-2-羟丙基）-3,4'-二氨基二苯醚; 和使N，N，N'，N'-四（3-氯-2-羟丙基）-3,4'-二氨基二苯醚与碱性化合物反应脱氯化氢的环化反应步骤。