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    Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization
    1.
    发明授权
    Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization 有权
    用于烯烃聚合的固体钛催化剂组分，用于烯烃聚合的催化剂和烯烃聚合方法

    公开(公告)号：US07220696B2

    公开(公告)日：2007-05-22

    申请号：US10501888

    申请日：2003-04-03

    申请人： Kazuhisa Matsunaga ,  Masao Nagano ,  Masaaki Ohgizawa ,  Toshiyuki Tsutsui

    发明人： Kazuhisa Matsunaga ,  Masao Nagano ,  Masaaki Ohgizawa ,  Toshiyuki Tsutsui

    IPC分类号： B01J31/00

    CPC分类号： C08F110/06 ,  C08F10/00 ,  C08F4/6492 ,  C08F4/651 ,  C08F4/6545 ,  C08F2500/18 ,  C08F2500/15 ,  C08F2500/12

    摘要： Disclosed is a catalyst for olefin polymerization comprising [I] a solid titanium catalyst component [S] comprising titanium, magnesium, halogen and an electron donor (b), which is obtained by bringing a solid adduct consisting of a magnesium compound and an electron donor (a) into contact with an electron donor (b) and a liquid titanium compound by at least one method selected from (A) a method of contacting the materials in a suspended state in the coexistence of an inert hydrocarbon solvent and (B) a method of contacting the material plural times individed portions and [II] an organometallic compound catalyst component [M] containing a metal selected from the groups I to III in the periodic table.

    摘要翻译： 公开了一种用于烯烃聚合的催化剂，其包含[I]包含钛，镁，卤素和电子给体（b）的固体钛催化剂组分[S]，其通过使由镁化合物和电子给体 （a）通过选自以下的至少一种方法与电子给体（b）和液体钛化合物接触：（A）在惰性烃溶剂共存下使悬浮状态的材料接触的方法和（B） 将该材料多次接触的方法和[II]含有选自元素周期表中I〜III族的金属的有机金属化合物催化剂组分[M]。

    Catalyst for olefin polymerization and process for olefin polymerization
    3.
    发明申请
    Catalyst for olefin polymerization and process for olefin polymerization 有权
    用于烯烃聚合的催化剂和烯烃聚合方法

    公开(公告)号：US20080125555A1

    公开(公告)日：2008-05-29

    申请号：US11878739

    申请日：2007-07-26

    申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    IPC分类号： C08F4/72 ,  B01J31/12

    CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

    摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

    摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R 2和R 3各自独立地为COOR 1或R 2，R 2和R 2中的至少一个为R 3 是COOR 1; 单键（不包括C a a 键和C a 环状骨架中R 3为R的情况）可以用双键代替; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 和多个R各自独立地为氢原子或取代基，但R中的至少一个不为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。

    Catalyst for olefin polymerization and process for olefin polymerization
    5.
    发明授权
    Catalyst for olefin polymerization and process for olefin polymerization 有权
    用于烯烃聚合的催化剂和烯烃聚合方法

    公开(公告)号：US07888438B2

    公开(公告)日：2011-02-15

    申请号：US11878739

    申请日：2007-07-26

    申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    IPC分类号： C08F4/42

    CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

    摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

    摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。

    Process for Producing Olefin Polymer and Solid Titanium Catalyst Component
    6.
    发明申请
    Process for Producing Olefin Polymer and Solid Titanium Catalyst Component 有权
    生产烯烃聚合物和固体钛催化剂组分的方法

    公开(公告)号：US20080306228A1

    公开(公告)日：2008-12-11

    申请号：US11795505

    申请日：2006-01-19

    申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    IPC分类号： C08F4/16

    CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

    摘要： The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature. According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

    摘要翻译： 本发明的烯烃聚合物的制造方法的特征在于，在含有含有钛，镁的固体钛催化剂成分（I）的烯烃聚合催化剂存在下，聚合具有3个以上碳原子的烯烃 ，卤素和下述式（1）所示的环状酯化合物（a）：其中n为5〜10的整数，R2和R3各自独立地为COOR1或氢原子，R2和R3中的至少一个 是COOR1; 并且R 1各自独立地为具有1至20个碳原子的单价烃基，并且环状主链中的单键（不包括Ca-Ca键，在R3为氢原子的情况下为Ca-Cb键）可以被替换 （II），在聚合反应器的内压下，在聚合温度下为烯烃的饱和蒸气压的0.25倍以上。 根据该方法，可以制备具有宽分子量分布的烯烃聚合物。

    Process for producing olefin polymer and solid titanium catalyst component
    8.
    发明授权
    Process for producing olefin polymer and solid titanium catalyst component 有权
    制备烯烃聚合物和固体钛催化剂组分的方法

    公开(公告)号：US07888437B2

    公开(公告)日：2011-02-15

    申请号：US11795505

    申请日：2006-01-19

    申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    IPC分类号： C08F4/42

    CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

    摘要： The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature. According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

    摘要翻译： 本发明的烯烃聚合物的制造方法的特征在于，在含有含有钛，镁的固体钛催化剂成分（I）的烯烃聚合催化剂存在下，聚合具有3个以上碳原子的烯烃 ，卤素和下述式（1）所示的环状酯化合物（a）：其中n为5〜10的整数，R2和R3各自独立地为COOR1或氢原子，R2和R3中的至少一个 是COOR1; 并且R 1各自独立地为具有1至20个碳原子的单价烃基，并且环状主链中的单键（不包括Ca-Ca键，在R3为氢原子的情况下为Ca-Cb键）可以被替换 （II），在聚合反应器的内压下，在聚合温度下为烯烃的饱和蒸气压的0.25倍以上。 根据该方法，可以制备具有宽分子量分布的烯烃聚合物。

    Image capture apparatus and program
    9.
    发明授权
    Image capture apparatus and program 有权
    图像捕获设备和程序

    公开(公告)号：US08711230B2

    公开(公告)日：2014-04-29

    申请号：US12424769

    申请日：2009-04-16

    申请人： Kazuhisa Matsunaga

    发明人： Kazuhisa Matsunaga

    IPC分类号： H04N5/228 ,  G03B17/00

    CPC分类号： H04N5/365 ,  H04N5/23248 ,  H04N5/23258 ,  H04N5/23287

    摘要： An image capture apparatus shifts an image sensor at each shooting initiation time in the continuous-shoot mode in the event of a camera-shake in response to a control signal which reflects an offset signal indicating pixel shifting information in a compensating signal indicating shake compensating information. Thereby, a change in the shooting range of the image sensor due to the camera-shake is mostly compensated for and the shooting range is changed by one pixel at each shooting. Thus, even in the event of a camera-shake, the distance between a feature portion of a main subject and a fixed pattern noise can be made different for each of continuously shot images. As a result, even in the event of the camera-shake, a composite image having fixed pattern noises scattered can be obtained by combining continuously shot images with reference to the feature portion.

    摘要翻译： 响应于在指示抖动补偿信息的补偿信号中反映指示像素移位信息的偏移信号的控制信号，摄像机在每次拍摄开始时刻在连续拍摄模式中移动图像传感器， 。 因此，由于相机抖动，图像传感器的拍摄范围的变化大部分被补偿，并且在每次拍摄时拍摄范围被改变一个像素。 因此，即使在相机抖动的情况下，也可以使主要被摄体的特征部分和固定图案噪声之间的距离对于连续拍摄图像中的每一个都不同。 结果，即使在相机抖动的情况下，也可以通过参照特征部分连续拍摄的图像来组合具有固定图案噪声的合成图像。

    SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST, AND OLEFIN POLYMERIZATION PROCESS
    10.
    发明申请
    SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST, AND OLEFIN POLYMERIZATION PROCESS 有权
    固体钛催化剂组分，烯烃聚合催化剂和烯烃聚合方法

    公开(公告)号：US20100305285A1

    公开(公告)日：2010-12-02

    申请号：US12744760

    申请日：2008-11-14

    申请人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Tetsunori Shinozaki

    IPC分类号： C08F4/50 ,  B01J31/04

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/03 ,  C08F4/6465

    摘要： A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, a specific cyclic ester compound (a) and a specific cyclic ester compound (b), an olefin polymerization catalyst containing this catalyst component (I), and an olefin polymerization process using this olefin polymerization catalyst are disclosed. According to the solid titanium catalyst component, the olefin polymerization catalyst and the process for preparing an olefin polymer of the invention, an olefin polymer having high stereoregularity and a wide molecular weight distribution can be prepared with high activity, preparation of an olefin polymer excellent not only in molding properties such as high-speed streatchability and high-speed moldability but also in rigidity becomes possible, and besides, production cost can be reduced.

    摘要翻译： 包含钛，镁，卤素，特定环状酯化合物（a）和特定环状酯化合物（b）的固体钛催化剂组分（I），含有该催化剂组分（I）的烯烃聚合催化剂和烯烃聚合方法 公开了使用该烯烃聚合催化剂。 根据固体钛催化剂组分，本发明的烯烃聚合催化剂和制备烯烃聚合物的方法可以制备具有高立构规整性和宽分子量分布的烯烃聚合物，其活性高，不能制备优异的烯烃聚合物 只有在高速可塑性和高速成型性等成型性能的同时，也能够实现刚性化，而且可以降低生产成本。