公开(公告)号：US20090069515A1

公开(公告)日：2009-03-12

申请号：US11795504

申请日：2006-01-19

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/76 ,  B01J31/04

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的固体钛催化剂组分（I）的特征在于它含有钛，镁，卤素和由下式（1）表示的环酯化合物（a）：其中n是5至10的整数 ; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个不是氢原子。 当使用该固体钛催化剂组分（I）时，可以生产具有宽分子量分布的烯烃聚合物。

公开(公告)号：US06177593B1

公开(公告)日：2001-01-23

申请号：US09216864

申请日：1998-12-21

申请人： Tadahito Nobori ,  Takaomi Hayashi ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Isao Hara ,  Shinji Kiyono ,  Kazumi Mizutani ,  Usaji Takaki

发明人： Tadahito Nobori ,  Takaomi Hayashi ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Isao Hara ,  Shinji Kiyono ,  Kazumi Mizutani ,  Usaji Takaki

IPC分类号： C07F902

CPC分类号： C07F9/065

摘要： The compound [tris(dimethylamino)phosphonioamino]tris[tris(dimethylamino)phosphoranylideneamino]phosphonium dichloride can be prepared by contacting hydrogen chloride with tetrakis[tris(dimethylamino)phosphoranylideneamino]phosphonium chloride. The phosphonium dichloride compound can be used in a process wherein it is brought into contact with an OH−-form ion exchange resin to prepare tetrakis[tris(dimethylamino)phosphoranylideneamino]phosphonium hydroxide. Separate processes for separating or isolating the phosphonium chloride compound or isolating the phosphonium hydroxide compound from feed solutions wherein an extraction step is used are also set forth.

摘要翻译： 化合物[三（二甲基氨基）膦酰氨基]三[三（二甲基氨基）亚正膦基氨基]二氯化鏻可以通过使氯化氢与四[三（二甲基氨基）正膦亚基氨基]鏻氯化物接触来制备。 二氯化鏻化合物可以在与OH型离子交换树脂接触以制备四[三（二甲基氨基）正膦亚基氨基]鏻氢氧化物的方法中使用。 还提出了分离或分离氯化鏻化合物或从使用提取步骤的进料溶液中分离氢氧化鏻的分离方法。

公开(公告)号：US20100324239A1

公开(公告)日：2010-12-23

申请号：US12851901

申请日：2010-08-06

申请人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

发明人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

IPC分类号： C08F4/50 ,  B01J31/26

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

摘要翻译： 本发明提供了一种制备α-烯烃聚合物的方法，其包括在包含含有钛，镁，镁的固体钛催化剂组分（I）的烯烃聚合催化剂的存在下聚合或共聚（a）C3或更高级的α-烯烃， 卤素和具有两个或更多个醚键的特定结构的化合物和具有高催化活性的有机金属催化剂组分（II）。 在该方法中，特别是即使在（共）聚合（a）较高级烯烃中，也不需要脱矿质。 使用本发明的催化剂进行聚合得到的4-甲基-1-戊烯类聚合物的立构规整度，透明性，耐热性，脱模性优异，特别适用于脱模膜。

公开(公告)号：US07649062B2

公开(公告)日：2010-01-19

申请号：US11878740

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/42

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的固体钛催化剂组分（I）的特征在于它含有钛，镁，卤素和由下式（1）表示的环酯化合物（a）：其中n是5至10的整数 ; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个不是氢原子。 当使用该固体钛催化剂组分（I）时，可以生产具有宽分子量分布的烯烃聚合物。

公开(公告)号：US20080125555A1

公开(公告)日：2008-05-29

申请号：US11878739

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/72 ,  B01J31/12

CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R 2和R 3各自独立地为COOR 1或R 2，R 2和R 2中的至少一个为R ^{3 是COOR 1; 单键（不包括C a a 键和C a 环状骨架中R 3为R的情况）可以用双键代替; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 和多个R各自独立地为氢原子或取代基，但R中的至少一个不为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。}

公开(公告)号：US06762259B2

公开(公告)日：2004-07-13

申请号：US10149381

申请日：2002-06-12

申请人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

发明人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

IPC分类号： C08F446

CPC分类号： C09D129/12 ,  C08F2/38 ,  C08F4/00 ,  C09D125/00 ,  C09D133/04 ,  C09D135/06 ,  C09D139/00

摘要： The purpose of the present invention is to provide polymerization catalyst which can produce quite efficiently (co)polymer having number average molecular weight and number of molecules which are accurately controlled in producing method of (co)polymer by the polymerization of polar unsaturated compound, and provide living polymerized (co)polymer obtained according to the producing method. For the purpose, polymerization catalyst composition which comprises the composition comprising organic oxysalt compound and hydroxycarbonyl compound having at least both an alcoholic hydroxyl group and a carbonyl group in the same molecule is provided and the polar unsaturated compound is polymerized by using the polymerization catalyst composition. The composition containing the obtained (co)polymer were able to provide thermosetting powder coating composition having particularly excellent characteristics.

摘要翻译： 本发明的目的是提供聚合催化剂，其可以产生具有数均分子量和分子数的非常有效的（共）聚合物，其通过极性不饱和化合物的聚合制备（共）聚合物的方法被精确控制，以及 提供根据制造方法获得的活性聚合（共）聚合物。 为此，提供了包含含有有机氧化锡化合物和在同一分子中至少具有醇羟基和羰基两者的羟基羰基化合物的组合物的聚合催化剂组合物，并且通过使用聚合催化剂组合物聚合极性不饱和化合物。 含有所得（共）聚合物的组合物能够提供具有特别优异特性的热固性粉末涂料组合物。

公开(公告)号：US06469224B1

公开(公告)日：2002-10-22

申请号：US10018424

申请日：2001-12-20

申请人： Tadahito Nobori ,  Setsuko Fujiyoshi ,  Isao Hara ,  Takaomi Hayashi ,  Atsushi Shibahara ,  Katsuhiko Funaki ,  Kazumi Mizutani ,  Shinji Kiyono

发明人： Tadahito Nobori ,  Setsuko Fujiyoshi ,  Isao Hara ,  Takaomi Hayashi ,  Atsushi Shibahara ,  Katsuhiko Funaki ,  Kazumi Mizutani ,  Shinji Kiyono

IPC分类号： C07B3900

CPC分类号： B01J31/0265 ,  B01J2531/98 ,  C07B39/00 ,  C07B41/00 ,  C07C17/202 ,  C07C17/208 ,  C07C41/16 ,  C07C45/63 ,  C07C67/11 ,  C07C201/12 ,  C07C209/10 ,  C07C253/14 ,  C07C319/14 ,  C07D209/08 ,  C07D213/61 ,  C07C25/13 ,  C07C49/813 ,  C07C321/28 ,  C07C321/30 ,  C07C255/50 ,  C07C211/50 ,  C07C205/12 ,  C07C205/38 ,  C07C43/205 ,  C07C43/225 ,  C07C69/78

摘要： A substituted aromatic compound substituted with Q is obtained by reacting a phosphazenium compound represented by formula (1) (in the formula, Q− represents an anion in a form derived by elimination of a proton from an inorganic acid, or an active hydrogen compound having an active hydrogen on an oxygen atom, a nitrogen atom or a sulfur atom; a, b, c and d, each independently, is 0 or 1, but all of them are not 0 simultaneously; and R groups represent the same or different hydrocarbon groups having 1 to 10 carbon atoms, or two Rs on each common nitrogen atom may be bonded together to form a ring structure) with a halogenated aromatic compound having halogen atoms; whereby, at least one halogen atom in the halogenated aromatic compound is substituted with Q (where, Q represents an inorganic group or an organic group in a form derived by elimination of one electron from Q− in formula (1)).

摘要翻译： 被Q取代的取代芳香族化合物是通过使式（1）表示的磷氮烯基鏻化合物（式中的Q表示以无机酸除去质子衍生的阴离子，或具有式 氧原子，氮原子或硫原子上的活性氢; a，b，c和d各自独立地为0或1，但它们全部不同时为0; R基表示相同或不同的烃 具有1至10个碳原子的基团，或每个常见氮原子上的两个R可以结合在一起形成环结构）与具有卤素原子的卤代芳族化合物; 由此，卤代芳香族化合物中的至少一个卤素原子被Q取代（其中，Q表示通过在式（1）中从Q-中除去一个电子而得到的无机基团或有机基团）。

公开(公告)号：US20110082325A1

公开(公告)日：2011-04-07

申请号：US12452438

申请日：2008-06-27

申请人： Yasuhiko Suzuki ,  Shinsuke Kinoshita ,  Atsushi Shibahara ,  Naritoshi Yoshimura ,  Isao Hara ,  Tetsuya Hamada ,  Kazumori Kawamura ,  Kou Tsurugi ,  Yasunori Saito ,  Seiichi Ishii ,  Yasushi Nakayama ,  Naoto Matsukawa ,  Susumu Murata

发明人： Yasuhiko Suzuki ,  Shinsuke Kinoshita ,  Atsushi Shibahara ,  Naritoshi Yoshimura ,  Isao Hara ,  Tetsuya Hamada ,  Kazumori Kawamura ,  Kou Tsurugi ,  Yasunori Saito ,  Seiichi Ishii ,  Yasushi Nakayama ,  Naoto Matsukawa ,  Susumu Murata

IPC分类号： C07C2/26 ,  C07F7/28 ,  C07F11/00 ,  B01J31/14

CPC分类号： C08F10/00 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/2243 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/46 ,  B01J2531/62 ,  C07C2/32 ,  C07C251/24 ,  C07C2521/08 ,  C07C2521/16 ,  C07C2531/14 ,  C07C2531/22 ,  C07F7/003 ,  C08F110/02 ,  C07C11/107 ,  C08F4/64048 ,  C08F2500/02 ,  C08F4/64124 ,  C08F4/6931 ,  C08F4/64117 ,  C08F4/02

摘要： The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts.A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I′) below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.

摘要翻译： 本发明提供了过渡金属络合物，含有这些化合物的高活性烯烃低聚催化剂和使用该催化剂的烯烃低聚方法。 根据本发明的过渡金属络合物[A]由下式（I）或式（I'）表示。 烯烃低聚催化剂包括过渡金属络合物[A]。 在本发明的烯烃低聚方法中，烯烃在催化剂存在下被低聚。

公开(公告)号：US07888438B2

公开(公告)日：2011-02-15

申请号：US11878739

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/42

CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。

公开(公告)号：US20080306228A1

公开(公告)日：2008-12-11

申请号：US11795505

申请日：2006-01-19

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/16

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature. According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

摘要翻译： 本发明的烯烃聚合物的制造方法的特征在于，在含有含有钛，镁的固体钛催化剂成分（I）的烯烃聚合催化剂存在下，聚合具有3个以上碳原子的烯烃 ，卤素和下述式（1）所示的环状酯化合物（a）：其中n为5〜10的整数，R2和R3各自独立地为COOR1或氢原子，R2和R3中的至少一个 是COOR1; 并且R 1各自独立地为具有1至20个碳原子的单价烃基，并且环状主链中的单键（不包括Ca-Ca键，在R3为氢原子的情况下为Ca-Cb键）可以被替换 （II），在聚合反应器的内压下，在聚合温度下为烯烃的饱和蒸气压的0.25倍以上。 根据该方法，可以制备具有宽分子量分布的烯烃聚合物。