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1.发明授权公开(公告)号：US08791218B2
公开(公告)日：2014-07-29
申请号：US12607134
申请日：2009-10-28
IPC分类号： C08F16/24
CPC分类号： D06M15/277 , C08F220/24 , C08F220/36 , C08F238/00 , C08F2220/1891 , C08F2220/286 , C09D133/16 , D06M15/256 , D06M15/263 , D06M15/53 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can impart water/oil repellency to a surface of an article without having its texture deteriorated, and has excellent durability against washing and stability, a method for producing such a composition, and an article treated with such a water/oil repellent composition. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no Rf group and having a C12-18 alkyl group; and monomer (c) is monomer (c1) having no Rf group and having a blocked isocyanate group or monomer (c2) having no Rf group and having at least two polymerizable unsaturated groups.
摘要翻译： 提供一种斥水斥油剂组合物，其能够赋予制品表面无斥水性，而不会使织物变质，并且具有优异的耐洗涤耐久性和稳定性，制备这种组合物的方法和用这种方法处理的制品 斥水斥油剂组合物。 包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。 这里，单体（a）为下式所示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有Rf基且具有C12-18烷基的（甲基）丙烯酸酯; 单体（c）是不具有Rf基且具有封端异氰酸酯基的单体（c1）或不具有Rf基且具有至少两个可聚合不饱和基团的单体（c2）。
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公开(公告)号：US09834633B2
公开(公告)日：2017-12-05
申请号：US12212716
申请日：2008-09-18
IPC分类号： C08F220/24 , C09D133/16 , C09K3/18 , D06M15/277 , C08F220/18 , C08F220/32 , C08F220/36 , C08L33/16
CPC分类号： C08F220/24 , C08F220/18 , C08F2220/325 , C08F2220/365 , C08L33/16 , C08L2205/02 , C09D133/16 , C09K3/18 , D06M15/277 , D06M2200/11 , D06M2200/12 , C08L2666/06
摘要： To provide a liquid repellent composition which is excellent in liquid repellency and durability and an article having a liquid repelling film. A liquid repellent composition comprising a copolymer (I) and a copolymer (II), characterized in that the copolymer (I) containing from 65 to 95 mass % of a polymerized unit (a) (referred to as “[a1]”) and from 1 to 30 mass % of a polymerized unit (b); and the copolymer (II) containing from 25 to 80 mass % of a polymerized unit (a) (referred to as “[a2]”) and from 1 to 50 mass % of a polymerized unit (c) are contained in an amount of the copolymer (I)/the copolymer (II)=10/90 to 95/5 (mass ratio), and [a1]−[a2]≧10 (mass %).
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3.发明授权公开(公告)号：US09115234B2
公开(公告)日：2015-08-25
申请号：US12555377
申请日：2009-09-08
IPC分类号： C08F220/24 , C08F214/18 , D06M15/248 , D06M15/256 , D06M15/263 , D06M15/277 , C08F220/36 , C08F220/18
CPC分类号： C08F214/18 , C08F214/186 , C08F220/24 , C08F220/36 , C08F2220/1891 , D06M15/248 , D06M15/256 , D06M15/263 , D06M15/277 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can give water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability), a method for producing such a composition, and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group; and monomer (c) is vinylidene chloride.
摘要翻译： 本发明提供一种斥水斥油剂组合物，其能够对制品的表面赋予斥水斥油性，并且具有优异的耐久性（耐洗涤耐久性和耐雨性），制造这种组合物的方法以及具有水/ 拒油性，并且在洗涤或大雨时不易受到拒水/斥油性的损害。 包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。 这里，单体（a）为下式所示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有多氟烷基并具有C20-30烷基的（甲基）丙烯酸酯; 单体（c）是偏二氯乙烯。
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4.发明授权Water/oil repellent composition, method for its production and method for treating article 有权斥水斥油剂组合物，其制造方法和制品的处理方法公开(公告)号：US08193277B2
公开(公告)日：2012-06-05
申请号：US13278292
申请日：2011-10-21
IPC分类号： C08L27/12
CPC分类号： D06M15/277 , C08F220/20 , C08F220/22 , C08F220/24 , C08K5/34922 , C09K3/18 , D06M15/227 , D06M15/248 , C08K5/17 , C08L33/16 , C08F214/08 , C08F214/06
摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, a method for its production and a method for treating an article.A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a) and structural units based on the following monomer (b) and having a mass average molecular weight of at least 40,000, and a medium, is used. Monomer (a): a compound represented by (Z—Y)nX, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or the like, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): an olefin, a homopolymer of which has a glass transition temperature of from −50° C. to 50° C.
摘要翻译： 本发明提供一种斥水斥油剂组合物，其能够赋予制品表面足够的动态拒水性和空气后干燥性，并且对环境的影响较小，其制备方法及其制备方法 文章。 包含具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元并且具有至少40,000的质均分子量和介质的共聚物的斥水斥油剂组合物被使用 。 单体（a）：由（Z-Y）nX表示的化合物，其中Z为C1-6多氟烷基等，Y为二价有机基团等，n为1或2，X为可聚合的 不饱和基团。 单体（b）：烯烃，其均聚物的玻璃化转变温度为-50℃至50℃。
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公开(公告)号：US20100113665A1
公开(公告)日：2010-05-06
申请号：US12652785
申请日：2010-01-06
CPC分类号： C08F220/24 , C08F14/18 , C08F214/06 , C08F214/18 , C08F220/36 , C08F220/58 , C08F2220/1891 , D06M15/263 , D06M15/277 , D06M15/3566 , D06M2200/11 , D06M2200/12 , C08F2/04
摘要： To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound of Rf1—(CH2)b-Q-(CH2)a—SH, wherein Rf1 is a C1-30 polyfluoroalkyl group, Q is a bivalent organic group or a single bond, a is an integer of from 1 to 20, and b is an integer of from 0 to 20.
摘要翻译： 本发明提供一种斥水斥油剂组合物的制造方法，其能够对制品的表面赋予斥水斥油性，并具有优异的耐久性（耐洗涤耐久性和耐雨性），耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法，其特征在于，在表面活性剂和聚合引发剂：单体（a）的存在下，在介质中，将包含下述单体（a）的单体成分与下列化合物（x）共存， 是式（Z-Y）n X的化合物，其中Z是C 1-20多氟烷基等，Y是二价有机基团或单键，n是1或2，X是可聚合不饱和基团; 化合物（x）为Rf1-（CH2）bQ-（CH2）a-SH的化合物，其中Rf1为C1-30多氟烷基，Q为二价有机基团或单键，a为 1〜20，b为0〜20的整数。
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公开(公告)号：US08901264B2
公开(公告)日：2014-12-02
申请号：US12878045
申请日：2010-09-09
IPC分类号： C08F214/26 , C08F214/08 , C08F220/24 , C08F214/00 , C08F214/06 , C08F220/18 , C08F220/26
CPC分类号： C08F214/00 , C08F214/06 , C08F214/08 , C08F220/18 , C08F220/24 , C08F220/26 , Y10T428/3154
摘要： To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability. A copolymer which is characterized in that it has structural units based on the following monomer (a) and structural units based on the following monomer (b), wherein the content of structural units based on the monomer (a) is from 5 to 95 mass % in the total structural units (100 mass %), the content of structural units based on the monomer (b) is from 5 to 60 mass % in the total structural units (100 mass %) and the sum of the contents of structural units based on the monomer (a) and structural units based on the monomer (b) is at least 65 mass % in the total structural units (100 mass %), and a water repellent composition which comprises the copolymer: Monomer (a): a (meth)acrylate having no Rf group and having a C20-30 alkyl group; Monomer (b): a halogenated olefin.
摘要翻译： 为了提供赋予足够的动态防水性的共聚物，对制品表面的空气干燥防水性和摩擦耐久性，对环境的影响较小的共聚物，其制造方法，防水组合物和 具有优异的动态防水性，空气干燥防水性和摩擦耐久性。 一种共聚物，其特征在于其具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元，其中基于单体（a）的结构单元的含量为5至95质量份 （100质量％），基于单体（b）的结构单元的含量在总结构单位（100质量％）中为5〜60质量％，结构单元的含量之和 基于单体（a）和基于单体（b）的结构单元在总结构单元（100质量％）中为至少65质量％，以及包含共聚物的防水组合物：单体（a）：a （甲基）丙烯酸酯，不具有Rf基且具有C20-30烷基; 单体（b）：卤代烯烃。
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公开(公告)号：US20100105825A1
公开(公告)日：2010-04-29
申请号：US12652765
申请日：2010-01-06
IPC分类号： C09K3/18
CPC分类号： C08F220/24 , C08F14/18 , C08F2220/1891 , C08F2220/308 , C08F2/04
摘要： To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound having at least two groups of —(CH2)a—CHR1—(CH2)b—SH, wherein R1 is a methyl group or an ethyl group, a is an integer of from 0 to 2, and b is 0 or 1.
摘要翻译： 本发明提供一种斥水斥油剂组合物的制造方法，其能够对制品的表面赋予斥水斥油性，并具有优异的耐久性（耐洗涤耐久性和耐雨性），耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法，其特征在于，在表面活性剂和聚合引发剂：单体（a）的存在下，在介质中，将包含下述单体（a）的单体成分与下列化合物（x）共存， 是式（Z-Y）n X的化合物，其中Z是C 1-20多氟烷基等，Y是二价有机基团或单键，n是1或2，X是可聚合不饱和基团; 化合物（x）是具有至少两个 - （CH 2）a -CHR 1-（CH 2）b -SH的基团的化合物，其中R 1是甲基或乙基，a是0-2的整数 ，b为0或1。
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8.发明申请公开(公告)号：US20100069564A1
公开(公告)日：2010-03-18
申请号：US12555377
申请日：2009-09-08
IPC分类号： C09D5/00 , C08F214/18
CPC分类号： C08F214/18 , C08F214/186 , C08F220/24 , C08F220/36 , C08F2220/1891 , D06M15/248 , D06M15/256 , D06M15/263 , D06M15/277 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can give water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability), a method for producing such a composition, and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group; and monomer (c) is vinylidene chloride.
摘要翻译： 本发明提供一种斥水斥油剂组合物，其能够对制品的表面赋予斥水斥油性，并且具有优异的耐久性（耐洗涤耐久性和耐雨性），制造这种组合物的方法以及具有水/ 拒油性，并且在洗涤或大雨时不易受到拒水/斥油性的损害。 包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。 这里，单体（a）为下式所示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有多氟烷基并具有C20-30烷基的（甲基）丙烯酸酯; 单体（c）是偏二氯乙烯。
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9.发明授权公开(公告)号：US08703864B2
公开(公告)日：2014-04-22
申请号：US12570893
申请日：2009-09-30
IPC分类号： C08F2/32
CPC分类号： D06M15/277 , C08F214/18 , C08F220/24 , C08F220/34 , C08F2220/1891 , D06M15/248 , D06M15/256 , D06M15/263 , D06M2200/11 , D06M2200/12
摘要： A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a) and polymerized units derived from monomer (b), wherein the proportion of the polymerized units derived from the monomer (b) is 30 to 80 mol % in the total of the polymerized units derived from the monomer (a) and the polymerized units derived from the monomer (b). Monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or the like; n is 1 or 2; and X is a polymerizable unsaturated group; and monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group.
摘要翻译： 含有衍生自单体（a）的聚合单元和源自单体（b）的聚合单元的共聚物的斥水斥油剂组合物，其中衍生自单体（b）的聚合单元的比例为30〜80摩尔％ 衍生自单体（a）的聚合单元和衍生自单体（b）的聚合单元的总和。 单体（a）是由下式表示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团等; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有多氟烷基且具有C20-30烷基的（甲基）丙烯酸酯。
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公开(公告)号：US07989567B2
公开(公告)日：2011-08-02
申请号：US12652765
申请日：2010-01-06
IPC分类号： C08F2/38 , C08F218/00 , C09K3/18
CPC分类号： C08F220/24 , C08F14/18 , C08F2220/1891 , C08F2220/308 , C08F2/04
摘要： To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound having at least two groups of —(CH2)a—CHR1—(CH2)b—SH, wherein R1 is a methyl group or an ethyl group, a is an integer of from 0 to 2, and b is 0 or 1.
摘要翻译： 本发明提供一种斥水斥油剂组合物的制造方法，其能够对制品的表面赋予斥水斥油性，并具有优异的耐久性（耐洗涤耐久性和耐雨性），耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法，其特征在于，在表面活性剂和聚合引发剂：单体（a）的存在下，在介质中，将包含下述单体（a）的单体成分与下列化合物（x）共存， 是式（Z-Y）n X的化合物，其中Z是C 1-20多氟烷基等，Y是二价有机基团或单键，n是1或2，X是可聚合不饱和基团; 化合物（x）是具有至少两个 - （CH 2）a -CHR 1-（CH 2）b -SH的基团的化合物，其中R 1是甲基或乙基，a是0-2的整数 ，b为0或1。
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