公开(公告)号：US4579702A

公开(公告)日：1986-04-01

申请号：US761314

申请日：1985-07-30

申请人： Satoshi Maruyama ,  Koichi Tsuda ,  Kazuo Mukae ,  Ikuo Nagasawa

发明人： Satoshi Maruyama ,  Koichi Tsuda ,  Kazuo Mukae ,  Ikuo Nagasawa

IPC分类号： H01C7/10 ,  C04B35/453 ,  H01C7/112 ,  H01B1/06

CPC分类号： H01C7/112

摘要： A zinc oxide voltage-nonlinear resistor is described. The resistor is produced by sintering a zinc oxide mixture containing 0.08 to 5.0 atomic % of at least one rare earth element, 0.1 to 10.0 atomic % of cobalt, 0.01 to 1.0 atomic % of at least one member of potassium, cesium, and rubidium, 0.01 to 1.0 atomic % of chromium, and 5.times.10.sup.-4 to 1.times.10.sup.-1 atomic % of boron, the balance being zinc oxide. This resistor has superior voltage nonlinearity and is greatly improved in the short duration discharge current withstand capability and the life performance under application of electricity.

摘要翻译： 描述了氧化锌电压非线性电阻器。 电阻体是通过烧结含有0.08〜5.0原子％的至少一种稀土元素，0.1〜10.0原子％的钴，0.01〜1.0原子％的钾，铯和铷中的至少一种的氧化锌混合物来制造的， 0.01〜1.0原子％的铬和5×10-4〜1×10-1原子％的硼，余量为氧化锌。 该电阻器具有优异的电压非线性，并且在短时间内放电电流耐受能力和使用电力下的使用寿命方面大大提高。

公开(公告)号：US4477793A

公开(公告)日：1984-10-16

申请号：US509080

申请日：1983-06-29

申请人： Kazuo Mukae ,  Satoshi Maruyama ,  Koichi Tsuda ,  Ikuo Nagasawa

发明人： Kazuo Mukae ,  Satoshi Maruyama ,  Koichi Tsuda ,  Ikuo Nagasawa

IPC分类号： H01C7/112 ,  H01C7/10 ,  H01B1/08

CPC分类号： H01C7/112

摘要： A voltage non-linear resistor in the form of a sintered body is disclosed. The sintered body is comprised of 0.08 to 5.0 atomic % of a rare earth element, 0.1. to 10 atomic % of cobalt, 5.times.10.sup.-4 to 1.times.10.sup.-1 atomic % of boron and an additional component which may be 0.01 to 5.0 atomic % of magnesium or calcium and/or 1.times.10.sup.-4 to 5.times.10.sup.-2 atomic % of aluminum, gallium or indium. The remainder of the sintered body is comprised of zinc oxide. The sintered body provides a small voltage non-linear resistor with high discharge current withstand capability and good life performance.

摘要翻译： 公开了一种烧结体形式的电压非线性电阻器。 烧结体由0.08〜5.0原子％的稀土元素构成，为0.1。 至10原子％的钴，5×10-4至1×10-1原子％的硼和另外的组分，其可以为0.01至5.0原子％的镁或钙和/或1×10-4至5×10-2原子％的铝，镓 或铟。 烧结体的其余部分由氧化锌组成。 烧结体提供具有高放电电流耐受能力和良好寿命性能的小型电压非线性电阻器。

公开(公告)号：US4473812A

公开(公告)日：1984-09-25

申请号：US509508

申请日：1983-06-30

申请人： Satoshi Maruyama ,  Koichi Tsuda ,  Kazuo Mukae ,  Ikuo Nagasawa

发明人： Satoshi Maruyama ,  Koichi Tsuda ,  Kazuo Mukae ,  Ikuo Nagasawa

IPC分类号： H01C7/112 ,  H01B1/06

CPC分类号： H01C7/112

摘要： A voltage-dependent nonlinear resistor containing ZnO as a main component and six auxiliary components, i.e., (1) a rare earth element; (2) Co; (3) at least one of Mg and Ca; (4) at least one of K, Rb and Cs, (5) as well as Cr; and (6) B which may be combined with at least one of Al, Ga and In. Alternatively, the auxiliary components may be (1) a rare earth element; (2) Co; (3) at least one of K, Rb and Cs; (4) Cr; (5) B; and (6) at least one of Al, Ga and In. The voltage-dependent nonlinear resistor of the present invention has high resistance to both long and short wave-tail surge currents and has an extended service life without sacrificing good nonlinearity.

摘要翻译： 含有ZnO作为主要成分的电压相关非线性电阻和六个辅助成分，即（1）稀土元素; （2）公司 （3）Mg和Ca中的至少一种; （4）K，Rb和Cs中的至少一个，（5）以及Cr; 和（6）B，其可以与Al，Ga和In中的至少一种组合。 或者，辅助部件可以是（1）稀土元素; （2）公司 （3）K，Rb和Cs中的至少一个; （4）铬; （5）B; 和（6）Al，Ga和In中的至少一种。 本发明的电压依赖型非线性电阻器对长波长和短波浪浪涌电流具有高的抵抗能力，并且具有延长的使用寿命而不牺牲良好的非线性度。

公开(公告)号：US4386022A

公开(公告)日：1983-05-31

申请号：US191337

申请日：1980-02-12

申请人： Ikuo Nagasawa ,  Kazuo Mukae ,  Koichi Tsuda ,  Takashi Ishii ,  Toyoshige Sakaguchi

发明人： Ikuo Nagasawa ,  Kazuo Mukae ,  Koichi Tsuda ,  Takashi Ishii ,  Toyoshige Sakaguchi

IPC分类号： H01C7/10 ,  C04B35/453 ,  H01C7/112 ,  H01B1/06

CPC分类号： H01C7/112

摘要： A voltage non-linear resistance ceramics having a larger voltage non-linear coefficient and a superior protection ability against the overvoltage is prepared by firing an essential component of zinc oxide added with the accessary components of one or more elements in the form of elements or compounds. As the accessary components, at least one of magnesium and calcium in addition to praseodymium, cobalt, potassium and chromium in the predetermined amounts are added to obtain a voltage non-linear resistance ceramics with a sufficient reduction of the leakage current and an increased protection ability against the overvoltage.

摘要翻译： PCT No.PCT / JP79 / 00152 Sec。 371日期1980年2月12日 102（e）日期1980年2月12日PCT申请日1979年6月14日PCT公布。 公开号WO80 / 00114 日期：1980年1月24日。具有较大电压非线性系数和对过电压的优异保护能力的电压非线性电阻陶瓷通过焙烧添加有一种或多种元素的附着组分的氧化锌的必需组分 以元素或化合物的形式。 作为附属成分，添加规定量的除了镨，钴，钾，铬以外的镁，钙中的至少一种，得到电流非线性电阻陶瓷，能够充分降低漏电流，提高保护能力 针对过电压。

公开(公告)号：US4069061A

公开(公告)日：1978-01-17

申请号：US701279

申请日：1976-06-30

申请人： Ikuo Nagasawa ,  Kazuo Mukae ,  Takashi Ishii ,  Koichi Tsuda

发明人： Ikuo Nagasawa ,  Kazuo Mukae ,  Takashi Ishii ,  Koichi Tsuda

IPC分类号： C04B35/00 ,  H01C7/10 ,  C04B35/50 ,  H01C7/12

CPC分类号： C04B35/00 ,  H01C7/10

摘要： Ceramics having nonlinear voltage characteristics in which (1) zinc oxide is used as a main component and (2) praseodymium, (3) one or more of magnesium or calcium, and (4) cobalt are added thereto as subcomponents, in elemental form or as a compound thereof, in an amount of from about 0.08 to about 10.0 atomic % for praseodymium, from about 0.08 to about 10.0 atomic % for the one or more of magnesium or calcium, and from about 0.1 to about 8.0 atomic % for the cobalt, each calculated as praseodymium, magnesium or calcium and cobalt.

摘要翻译： 以（1）氧化锌为主要成分，（2）镨，（3）镁或钙中的一种或多种，​​和（4）钴）的非线性电压特性的陶瓷作为副成分以元素形式或 作为其化合物，对于镨为约0.08至约10.0原子％，对于一种或多种镁或钙为约0.08至约10.0原子％，对于钴为约0.1至约8.0原子％ ，各自计算为镨，镁或钙和钴。

公开(公告)号：US4767582A

公开(公告)日：1988-08-30

申请号：US943803

申请日：1986-12-19

申请人： Satoshi Maruyama ,  Kazuo Mukae ,  Ikuo Nagasawa

发明人： Satoshi Maruyama ,  Kazuo Mukae ,  Ikuo Nagasawa

IPC分类号： C04B35/453 ,  H01C7/112 ,  C04B35/50

CPC分类号： H01C7/112 ,  C04B35/453

摘要： A method of manufacturing a voltage nonlinear resistance element comprising the steps of providing a mixture of main component ZnO and auxiliary components of at least a rare earth element, Co and B in a mold, placing the mold in a sheath box having openings in the surfaces thereof, and baking the mold in the sheath box. The preferred ratio of the area of the openings in the sheath box to the total surface area of the sheath box is 10-90% to produce the voltage nonlinear resistance elements having favorable long wave tail surge withstanding data and an acceptable ratio of a voltage developed across the terminals of the element when a current of 1 mA flows in the element.

摘要翻译： 一种制造电压非线性电阻元件的方法，包括以下步骤：在模具中提供至少一种稀土元素Co和B的主要组分ZnO和辅助组分的混合物，将模具放置在具有表面开口的护套盒中 并且将模具在护套箱中烘烤。 护套箱中开口面积与护套箱总面积的优选比例为10-90％，以产生具有良好的长波尾浪涌耐受数据的电压非线性电阻元件，以及发生电压的可接受比例 当元件中流过1mA的电流时，跨过元件的端子。

公开(公告)号：US4038217A

公开(公告)日：1977-07-26

申请号：US598956

申请日：1975-07-24

申请人： Masaharu Namba ,  Ikuo Nagasawa ,  Kazuo Mukae

发明人： Masaharu Namba ,  Ikuo Nagasawa ,  Kazuo Mukae

IPC分类号： H01C7/10 ,  H01C1/06 ,  H01B1/08

CPC分类号： H01C7/10

摘要： A ceramic having non-linear voltage characteristics, comprising the product obtained on mixing (a) zinc oxide, as a principal component, and (b) (1) cobalt and (2) one of neodymium, samarium or dysprosium, either in an elemental form or as a compound thereof, each in an amount of 0.1 to 10 atomic % for the cobalt, neodymium, samarium and dysprosium, calculated as cobalt, neodymium, samarium and dysprosium as subcomponents, and calcining the mixture at a temperature of from about 1150.degree. to about 1400.degree. C.

公开(公告)号：US4033906A

公开(公告)日：1977-07-05

申请号：US583358

申请日：1975-06-03

申请人： Ikuo Nagasawa ,  Kazuo Mukae

发明人： Ikuo Nagasawa ,  Kazuo Mukae

IPC分类号： H01C7/10 ,  C04B35/00

CPC分类号： H01C7/10

摘要： Ceramics having nonlinear voltage characteristics comprising the product obtained on preparing a mixture of zinc oxide as a main component, and, as subcomponents, cobalt plus one of praseodymium or terbium, either in an elemental form or as a compound thereof, in an amount of from 0.1 to 8.0 atomic % for the cobalt, from 0.08 to 8.0 atomic % for the praseodymium and from 0.1 to 8.0 atomic % for the terbium, each calculated as cobalt, praseodymium and terbium, and calcining the mixture at a temperature in the range of from about 1150.degree. to about 1400.degree. C and a method for preparing the ceramics. An embodiment includes, as an additional subcomponent, lanthanum, either in an elemental form or as a compound in an amount of from 0.08 to 8.0 atomic %, calculated as lanthanum, with the zinc oxide, cobalt and praseodymium.

摘要翻译： 具有非线性电压特性的陶瓷包括在制备氧化锌作为主要成分的混合物中获得的产物，以及作为次要成分的钴，加上镨或铽中的一种，以元素形式或其化合物，其量为 对于钴为0.1至8.0原子％，对于镨为0.08至8.0原子％，对于铽为0.1至8.0原子％，各自以钴，镨和铽计算，并在该温度范围内煅烧该混合物 约1150℃至约1400℃，以及制备该陶瓷的方法。 作为附加的副成分，实施方案包括作为镧以0.08至8.0原子％的量的元素形式的镧或与氧化锌，钴和镨的化合物。

公开(公告)号：US5422336A

公开(公告)日：1995-06-06

申请号：US124788

申请日：1993-09-22

申请人： Koichi Tsuda ,  Toshiyuki Matsui ,  Takeshi Suzuki ,  Hiroshi Kimura ,  Takashi Ishii ,  Akihiko Ohi ,  Kazuo Mukae

发明人： Koichi Tsuda ,  Toshiyuki Matsui ,  Takeshi Suzuki ,  Hiroshi Kimura ,  Takashi Ishii ,  Akihiko Ohi ,  Kazuo Mukae

IPC分类号： H01L39/22 ,  H01L39/14 ,  B05D5/12 ,  H01B12/00

CPC分类号： H01L39/146 ,  Y10S505/779

摘要： A superconducting transistor with superior withstand voltage having source region and a drain region formed of oxide superconductors 3, a PrBa.sub.2 Cu.sub.3 O.sub.7-x layer 2 or an ScBa.sub.2 Cu.sub.3 O.sub.7-x layer 2 forming an intermediate region sandwiched by the source and drain regions. The regions are disposed on a substrate 1. An insulation layer 4 is disposed on the intermediate region. A transistor uses the intermediate region as an insulator when the gate is turned off, and as a superconductor when the gate is turned on.

摘要翻译： 具有优异的耐电压的超导晶体管具有源极区和由氧化物超导体3，PrBa2Cu3O7-x层2或ScBa2Cu3O7-x层2形成的漏极区，形成由源极和漏极区夹持的中间区。 这些区域设置在基板1上。绝缘层4设置在中间区域上。 当栅极截止时，晶体管使用中间区域作为绝缘体，并且当栅极导通时，作为超导体使用。

公开(公告)号：US4981624A

公开(公告)日：1991-01-01

申请号：US242940

申请日：1988-09-09

申请人： Koichi Tsuda ,  Kazuo Mukae ,  Toyoshige Sakaguchi ,  Takashi Ishii

发明人： Koichi Tsuda ,  Kazuo Mukae ,  Toyoshige Sakaguchi ,  Takashi Ishii

IPC分类号： H01C7/10 ,  H01C7/112 ,  H01C17/30

CPC分类号： H01C7/112 ,  H01C17/30

摘要： A method of producing a voltage nonlinear ZnO varistor in which seed grains of ZnO are produced by spray drying a slurry of ZnO particles and then sintering the dried slurry to form seed grains having a size of 10 to 100.mu.m. The seed grains are mixed with a ZnO powder of particles of much smaller size than the seed grains and a small amount of an auxiliary component. The mixture is then molded and sintered to form the varistor element to which electrodes are attached.

摘要翻译： 一种制造电压非线性ZnO压敏电阻的方法，其中通过喷雾干燥ZnO颗粒的浆料然后将干燥的浆料烧结以形成尺寸为10至100μm的晶种，制备ZnO晶种。 将种子晶粒与粒径小于粒子的ZnO粉末和少量的辅助成分混合。 然后将混合物模制和烧结以形成电极附接到的变阻器元件。