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公开(公告)号：US20120095218A1
公开(公告)日：2012-04-19
申请号：US13337658
申请日：2011-12-27
IPC分类号： C07D223/18
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
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2.发明申请OPTICALLY ACTIVE QUATERNARY AMMONIUM SALT HAVING AXIAL ASYMMETRY AND PROCESS FOR PRODUCING ALPHA-AMINO ACID AND DERIVATIVE THEREOF WITH THE SAME 有权具有轴向不对称性的光学活性季铵盐及其制备方法与其制备氨基酸及其衍生物公开(公告)号：US20090270614A1
公开(公告)日：2009-10-29
申请号：US11910364
申请日：2006-03-24
IPC分类号： C07D223/18 , C07C227/16 , C07C227/18
CPC分类号： C07B53/00 , B01J31/0239 , B01J2531/985 , C07C227/32 , C07C249/02 , C07D223/18 , C07D487/10 , C07C229/36 , C07C251/24
摘要： The present invention provides a chiral phase-transfer catalyst of the following formula (I): The compound (I) can be produced by reacting a 2,2′-dimethylene bromide-1,1′-biphenyl derivative, which can be produced through comparatively small number of steps, with an easily available secondary amine.
摘要翻译： 本发明提供下述式（I）的手性相转移催化剂：化合物（I）可以通过使2,2'-二亚甲基溴-1,1'-联苯衍生物 相对较少的步骤，具有容易获得的仲胺。
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3.发明申请OPTICALLY ACTIVE QUATERNARY AMMONIUM SALT HAVING AXIAL ASYMMETRY, AND METHOD FOR PRODUCING ALPHA-AMINO ACID AND DERIVATIVE THEREOF BY USING THE SAME 审中-公开具有轴向不对称性的光学活性季铵盐，以及通过使用它们生产α-氨基酸及其衍生物的方法公开(公告)号：US20120101310A1
公开(公告)日：2012-04-26
申请号：US13338313
申请日：2011-12-28
IPC分类号： C07C43/225
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
摘要翻译： 本发明公开了具有轴向不对称性的光学活性季铵盐和使用其制备α-氨基酸及其衍生物的方法。 具有本发明的轴向不对称性的光学活性季铵盐是手性相转移催化剂，其结构简单，可以以较少数量的工艺步骤生产。 本发明的化合物在α-烷基-α-氨基酸及其衍生物以及α，α-二烷基-α-氨基酸及其衍生物的合成中作为相转移催化剂是非常有用的 。 因此，本发明的化合物可用于开发新型食品和药物。
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4.发明申请OPTICALLY ACTIVE QUATERNARY AMMONIUM SALT HAVING AXIAL ASYMMETRY, AND METHOD FOR PRODUCING ALPHA-AMINO ACID AND DERIVATIVE THEREOF BY USING THE SAME 有权具有轴向不对称性的光学活性季铵盐，以及通过使用它们生产α-氨基酸及其衍生物的方法公开(公告)号：US20100029935A1
公开(公告)日：2010-02-04
申请号：US12443588
申请日：2007-09-13
IPC分类号： C07C229/06 , C07D223/18 , C07C25/02 , C07C15/12 , C07C229/04
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
摘要翻译： 本发明公开了具有轴向不对称性的光学活性季铵盐和使用其制备α-氨基酸及其衍生物的方法。 具有本发明的轴向不对称性的光学活性季铵盐是手性相转移催化剂，其结构简单，可以以较少数量的工艺步骤生产。 本发明的化合物在α-烷基-α-氨基酸及其衍生物以及α，α-二烷基-α-氨基酸及其衍生物的合成中作为相转移催化剂是非常有用的 。 因此，本发明的化合物可用于开发新型食品和药物。
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5.发明授权Optically active quaternary ammonium salt having axial asymmetry, and method for producing alpha-amino acid and derivative thereof by using the same 有权具有轴向不对称性的光学活性季铵盐，以及通过使用其产生α-氨基酸及其衍生物的方法公开(公告)号：US08252952B2
公开(公告)日：2012-08-28
申请号：US13338601
申请日：2011-12-28
IPC分类号： C07C229/06
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
摘要翻译： 本发明公开了具有轴向不对称性的光学活性季铵盐和使用其制备α-氨基酸及其衍生物的方法。 具有本发明的轴向不对称性的光学活性季铵盐是手性相转移催化剂，其结构简单，可以以较少数量的工艺步骤生产。 本发明的化合物在α-烷基-α-氨基酸及其衍生物以及α，α-二烷基-α-氨基酸及其衍生物的合成中作为相转移催化剂是非常有用的 。 因此，本发明的化合物可用于开发新型食品和药物。
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公开(公告)号：US08110680B2
公开(公告)日：2012-02-07
申请号：US12443588
申请日：2007-09-13
IPC分类号： C07D223/18
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
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7.发明授权Optically active quaternary ammonium salt having axial asymmetry and process for producing α-amino acid and derivative thereof with the same 有权具有轴向不对称性的光学活性季铵盐及其制备α-氨基酸及其衍生物的方法公开(公告)号：US08614316B2
公开(公告)日：2013-12-24
申请号：US11910364
申请日：2006-03-24
IPC分类号： C07D223/18
CPC分类号： C07B53/00 , B01J31/0239 , B01J2531/985 , C07C227/32 , C07C249/02 , C07D223/18 , C07D487/10 , C07C229/36 , C07C251/24
摘要： The present invention provides a chiral phase-transfer catalyst of the following formula (I): The compound (I) can be produced by reacting a 2,2′-dimethylene bromide-1,1′-biphenyl derivative, which can be produced through comparatively small number of steps, with an easily available secondary amine.
摘要翻译： 本发明提供下述式（I）的手性相转移催化剂：化合物（I）可以通过使2,2'-二亚甲基溴-1,1'-联苯衍生物 相对较少的步骤，具有容易获得的仲胺。
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公开(公告)号：US08263798B2
公开(公告)日：2012-09-11
申请号：US13338659
申请日：2011-12-28
IPC分类号： C07C229/08 , C07C229/32
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
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公开(公告)号：US20120095252A1
公开(公告)日：2012-04-19
申请号：US13338601
申请日：2011-12-28
IPC分类号： C07C249/02
CPC分类号： C07B53/00 , B01J31/0239 , B01J2231/46 , B01J2531/0266 , B01J2531/985 , C07B2200/07 , C07C43/225 , C07C249/02 , C07D223/18 , C07D487/04 , C07C251/24
摘要： The present invention discloses an optically active quarternary ammonium salt having axial asymmetry and a method for producing an α-amino acid and a derivative thereof using the same. The optically active quarternary ammonium salt having axial asymmetry of the present invention is a chiral phase-transfer catalyst that has a simple structure and that can be produced in a smaller number of process steps. The compound of the present invention is very useful as a phase-transfer catalyst in the synthesis of an α-alkyl-α-amino acid and a derivative thereof as well as an α,α-dialkyl-α-amino acid and a derivative thereof. Therefore, the compound of the present invention can be used in the development of novel foods and pharmaceuticals.
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10.发明申请BOTTLED DRINK CONTAINING INDIGESTIBLE DEXTRIN AND METHOD FOR PRODUCING THE SAME 审中-公开含有可溶性脱脂剂的含糖饮料及其生产方法公开(公告)号：US20150181919A1
公开(公告)日：2015-07-02
申请号：US14413614
申请日：2012-09-03
CPC分类号： A23L2/54 , A23L2/52 , A23L2/58 , A23L2/60 , A23L5/42 , A23L27/30 , A23L29/212 , A23L33/21 , A23V2002/00
摘要： To provide a bottled carbonated drink containing indigestible dextrin, capable of reducing exuding of a dissolved carbon dioxide. The bottled carbonated drink containing indigestible dextrin, including a caramel pigment and a high-intensity sweetener is provided.
摘要翻译： 提供含有消化不良糊精的瓶装碳酸饮料，能够减少溶解二氧化碳的渗出。 提供含有不可消化的糊精的瓶装碳酸饮料，包括焦糖色素和高强度甜味剂。
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