公开(公告)号：US5192778A

公开(公告)日：1993-03-09

申请号：US677030

申请日：1991-03-29

申请人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

发明人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

IPC分类号： C07D401/06 ,  C07D405/14 ,  C07D417/06 ,  C07D417/14

CPC分类号： C07D401/06 ,  C07D405/14 ,  C07D417/06 ,  C07D417/14

摘要： Novel dialkoxymethylimidazolidine derivatives of the formula (1) ##STR1## are described. Also, a preparation process of the derivatives and insecticidal compositions comprising the same are set forth. In addition, novel intermediate compounds of the formula (2) useful in preparing the derivatives of the formula(1) are also described along with their preparation process ##STR2##

公开(公告)号：US5264584A

公开(公告)日：1993-11-23

申请号：US944687

申请日：1992-09-14

申请人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

发明人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

IPC分类号： C07D401/06 ,  C07D405/14 ,  C07D417/06 ,  C07D417/14 ,  C07D233/52

CPC分类号： C07D401/06 ,  C07D405/14 ,  C07D417/06 ,  C07D417/14

摘要： Novel dialkoxymethylimidazolidine derivatives of the formula (1) ##STR1## are described. Also, a preparation process of the derivatives and insecticidal compositions comprising the same are set forth. In addition, novel intermediate compounds of the formula (2) useful in preparing the derivatives of the formula (1) are also described along with their preparation process ##STR2##

摘要翻译： 描述了式（1）的新型二烷氧基甲基咪唑烷衍生物（1）。 另外，提出了包含它们的衍生物和杀虫组合物的制备方法。 此外，还描述了可用于制备式（1）的衍生物的式（2）的新型中间体化合物及其制备方法。

公开(公告)号：US5219868A

公开(公告)日：1993-06-15

申请号：US802092

申请日：1991-12-04

申请人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

发明人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Michihiko Nakaya ,  Koichi Ebihara ,  Shirou Shiraishi ,  Eiichi Yamada ,  Satoshi Numata

IPC分类号： A01N43/50 ,  C07D233/52 ,  C07D233/88 ,  C07D401/06

CPC分类号： C07D401/06 ,  C07D233/88

摘要： Herein disclosed are novel imidazolidine derivatives of the formula (I) and intermediates of the formula (II) ##STR1## wherein each R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, a halogen atom, an alkoxy group having from 1 to 6 carbon atoms, a methylenedioxy group, an alkylthio group having from 1 to 4 carbon atoms, a haloalkyl group having from 1 to 2 carbon atoms, a haloalkoxy group having from 1 to 4 carbon atoms, an alkylcarbonyl group having from 1 to 6 carbon atoms, an alkoxycarbonyl.group having from 1 to 6 carbon atoms, a hydroxy group, a cyano group, a nitro group, an alkylamino group having from 1 to 8 carbon atoms, a phenyl group, a phenoxy group, a benzyl group or a halopyridylmethyloxy group, and n is an integer of from 1 to 3, ##STR2## wherein R and n have, respectively, the same meanings as defined above. Processes for preparing the compounds of the formulas (I) and (II) are also described. Moreover, insecticidal compositions comprising an effective amount of the derivative (I) are described.

公开(公告)号：US5614527A

公开(公告)日：1997-03-25

申请号：US447962

申请日：1995-05-23

申请人： Katsutoshi Kinoshita ,  Takeo Wakita ,  Kenji Kodaka ,  Hirozumi Matsuno ,  Kenichi Satoh ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Nobuyuki Kawahara ,  Koichi Ebihara ,  Michihiko Nakaya

发明人： Katsutoshi Kinoshita ,  Takeo Wakita ,  Kenji Kodaka ,  Hirozumi Matsuno ,  Kenichi Satoh ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Nobuyuki Kawahara ,  Koichi Ebihara ,  Michihiko Nakaya

IPC分类号： A01N43/50 ,  A01N43/54 ,  A01N51/00 ,  C07D405/06 ,  C07D251/08

CPC分类号： C07D405/06 ,  A01N51/00

摘要： A tetrahydrofuran-compound is disclosed herein which is represented by the formula (1) ##STR1## wherein each of X.sub.1 and X.sub.2 is a hydrogen atom or a methyl group, Y is a hydrogen atom or a carbonyl group substituted by a lower alkyl group (Y') having 1 to 4 carbon atoms, i.e., an acyl group (--COY'), andn is 2 or 3,and an insecticide containing the tetrahydrofuran-compound as an effective component.

摘要翻译： 本文公开的四氢呋喃化合物，其由式（1）表示：其中X1和X2各自为氢原子或甲基，Y为氢原子或被低级 具有1至4个碳原子的烷基（Y'），即酰基（-COY'），n为2或3，以及含有四氢呋喃化合物作为有效成分的杀虫剂。

公开(公告)号：US5434181A

公开(公告)日：1995-07-18

申请号：US326260

申请日：1994-10-20

申请人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Takeo Wakita ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Michihiko Nakaya ,  Hirozumi Matsuno ,  Nobuyuki Kawahara ,  Koichi Ebihara

发明人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Takeo Wakita ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Michihiko Nakaya ,  Hirozumi Matsuno ,  Nobuyuki Kawahara ,  Koichi Ebihara

IPC分类号： A01N43/08 ,  A01N43/36 ,  A01N47/12 ,  A01N47/40 ,  A01N51/00 ,  A01N53/00 ,  C07D307/14 ,  C07D405/06 ,  C07D307/16

CPC分类号： C07D405/06 ,  A01N43/08 ,  A01N43/36 ,  A01N47/40 ,  A01N51/00 ,  A01N53/00 ,  C07D307/14

摘要： The present invention relates to novel (tetrahydro-3-furanyl)methylamino derivatives of the following formula (1): ##STR1## wherein the variables are defined in the specification, which are useful as insecticides.

摘要翻译： 本发明涉及下式（1）的新的（四氢-3-呋喃基）甲基氨基衍生物：其中变量在本说明书中定义，其可用作杀虫剂。

公开(公告)号：US5532365A

公开(公告)日：1996-07-02

申请号：US417111

申请日：1995-04-05

申请人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Takeo Wakita ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Michihiko Nakaya ,  Hirozumi Matsuno ,  Nobuyuki Kawahara ,  Koichi Ebihara

发明人： Kenji Kodaka ,  Katsutoshi Kinoshita ,  Takeo Wakita ,  Shirou Shiraishi ,  Kazutomi Ohnuma ,  Eiichi Yamada ,  Naoko Yasui ,  Michihiko Nakaya ,  Hirozumi Matsuno ,  Nobuyuki Kawahara ,  Koichi Ebihara

IPC分类号： A01N43/08 ,  A01N43/36 ,  A01N47/12 ,  A01N47/40 ,  A01N51/00 ,  A01N53/00 ,  C07D307/14 ,  C07D405/06 ,  C07D251/08

CPC分类号： C07D405/06 ,  A01N43/08 ,  A01N43/36 ,  A01N47/40 ,  A01N51/00 ,  A01N53/00 ,  C07D307/14

摘要： The present invention relates to novel (tetrahydro-3-furanyl)methylamino derivatives of the following formula (1): ##STR1## wherein the variables are defined in the specification, which are useful as insecticides.

摘要翻译： 本发明涉及下式（1）的新的（四氢-3-呋喃基）甲基氨基衍生物：其中变量在本说明书中定义，其可用作杀虫剂。

公开(公告)号：US08906314B2

公开(公告)日：2014-12-09

申请号：US12998203

申请日：2009-09-25

申请人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada ,  Atsushi Murata ,  Osamu Wakamura

发明人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada ,  Atsushi Murata ,  Osamu Wakamura

IPC分类号： B01J8/22 ,  C07C1/04 ,  C10G2/00

CPC分类号： C10G2/342 ,  B01J8/22 ,  B01J2208/00141 ,  B01J2208/00203 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2219/00006 ,  C10G2/32

摘要： A bubble column reactor includes a reactor body which contains a slurry having solid catalyst particles suspended in a liquid, an inflow port which is provided at the bottom of the reactor body and allows a synthesis gas including a carbon monoxide gas and a hydrogen gas as the main components to flow into the slurry therethrough, and an outflow port which is provided at the top of the reactor body and allows gaseous hydrocarbons synthesized by a chemical reaction between the synthesis gas and the slurry, an unreacted synthesis gas, and the like to flow out therethrough. The distance in a vertical direction between the liquid surface of the slurry and the outflow port is 1.4 m or more and 10 m or less.

摘要翻译： 泡罩塔反应器包括反应器主体，其包含悬浮在液体中的固体催化剂颗粒的浆料，设置在反应器主体的底部并允许包含一氧化碳气体和氢气的合成气作为流入口的流入口 主要组分流入浆料，以及流出口，其设置在反应器主体的顶部，并允许通过合成气和浆料之间的化学反应合成的气态烃，未反应的合成气等流动 从中穿过。 浆液的液面与流出口之间的垂直方向的距离为1.4μm以上且10μm以下。

公开(公告)号：US08479572B2

公开(公告)日：2013-07-09

申请号：US12733892

申请日：2008-09-26

申请人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada

发明人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada

IPC分类号： G01F23/14

CPC分类号： G01F23/168 ,  B01J8/1809 ,  B01J8/1818 ,  B01J8/226 ,  B01J2208/00132 ,  B01J2208/00539 ,  B01J2208/00584 ,  B01J2208/0061 ,  B01J2219/002 ,  B01J2219/0022 ,  B01J2219/00234 ,  C10G2/342 ,  G01F23/18 ,  G01F23/185

摘要： There is provided a bubble column type hydrocarbon synthesis reactor which synthesizes a hydrocarbon compound by a chemical reaction of a synthesis gas including hydrogen and carbon monoxide as main components, and a slurry having solid catalyst particles suspended in liquid. The hydrocarbon synthesis reactor includes a reactor main body which accommodates the slurry, a synthesis gas supplying section which supplies the synthesis gas to the slurry; one pressure sensor which is arranged higher than the liquid level of the slurry to measure the pressure of the synthesis gas above the liquid level, another pressure sensor which is arranged lower than the liquid level of the slurry to measure the pressure of the slurry, and a liquid level detecting device which detects a liquid level position of the slurry on the basis of measurement results of the pressure sensors. A plurality of the other pressure sensors are provided at arbitrary intervals in an axial direction of the reactor main body.

摘要翻译： 提供了一种泡沫塔型烃合成反应器，其通过包含氢和一氧化碳作为主要成分的合成气的化学反应和悬浮在液体中的固体催化剂颗粒的浆料合成烃化合物。 烃合成反应器包括容纳浆料的反应器主体，向浆料供给合成气的合成气供给部; 一个压力传感器被布置成高于浆液的液面以测量液面以上的合成气的压力，另一压力传感器布置成低于浆液的液面以测量浆料的压力，以及 液位检测装置，其基于压力传感器的测量结果来检测浆料的液面位置。 多个其他压力传感器以反应器主体的轴向任意间隔设置。

公开(公告)号：US08398340B2

公开(公告)日：2013-03-19

申请号：US12736114

申请日：2009-03-12

申请人： Yasuhiro Onishi ,  Yuzuru Kato ,  Atsushi Murata ,  Eiichi Yamada

发明人： Yasuhiro Onishi ,  Yuzuru Kato ,  Atsushi Murata ,  Eiichi Yamada

IPC分类号： B65G53/12 ,  B01J10/00

CPC分类号： G01N1/10 ,  B01J8/0035 ,  B01J8/22 ,  B01J8/228 ,  B01J2208/00141 ,  B01J2208/00761 ,  B01J2208/00769 ,  B01J2208/00973 ,  C10G2/343 ,  G01N2001/1025 ,  G01N2001/105 ,  G01N2001/2238

摘要： A method of extracting the contents from the inside of a reactor kept at high temperature and high pressure includes the steps of introducing the contents of the reactor into a pipe having an internal space which communicates with the reactor, closing the pipe to enclose the contents in the internal space, removing unnecessary gas from the internal space, and supplying an inert gas to the internal space, thereby replacing the contents enclosed in the internal space with the inert gas. The contents are discharged from the internal space by replacing the contents enclosed in the internal space with the inert gas.

摘要翻译： 从保持在高温高压的反应器内部提取内容物的方法包括将反应器的内容物引入到具有与反应器连通的内部空间的管道中的步骤，封闭管道以将内容物包围 内部空间，从内部空间去除不需要的气体，并向内部空间供给惰性气体，由此用惰性气体代替内部空间中封入的内容物。 通过用惰性气体代替内部空间中包含的内容物，将内容物从内部空间排出。

公开(公告)号：US20110245356A1

公开(公告)日：2011-10-06

申请号：US12998203

申请日：2009-09-25

申请人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada ,  Atsushi Murata ,  Osamu Wakamura

发明人： Yasuhiro Onishi ,  Yuzuru Kato ,  Eiichi Yamada ,  Atsushi Murata ,  Osamu Wakamura

IPC分类号： C07C1/04 ,  B01J8/02 ,  B01J19/00

CPC分类号： C10G2/342 ,  B01J8/22 ,  B01J2208/00141 ,  B01J2208/00203 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2219/00006 ,  C10G2/32

摘要： A bubble column reactor includes a reactor body which contains a slurry having solid catalyst particles suspended in a liquid, an inflow port which is provided at the bottom of the reactor body and allows a synthesis gas including a carbon monoxide gas and a hydrogen gas as the main components to flow into the slurry therethrough, and an outflow port which is provided at the top of the reactor body and allows gaseous hydrocarbons synthesized by a chemical reaction between the synthesis gas and the slurry, an unreacted synthesis gas, and the like to flow out therethrough. The distance in a vertical direction between the liquid surface of the slurry and the outflow port is 1.4 m or more and 10 m or less.

摘要翻译： 泡罩塔反应器包括反应器主体，其包含悬浮在液体中的固体催化剂颗粒的浆料，设置在反应器主体的底部并允许包含一氧化碳气体和氢气的合成气作为流入口的流入口 主要组分流入浆料，以及流出口，其设置在反应器主体的顶部，并允许通过合成气和浆料之间的化学反应合成的气态烃，未反应的合成气等流动 从中穿过。 浆液的液面与流出口之间的垂直方向的距离为1.4μm以上且10μm以下。