公开(公告)号：US4866201A

公开(公告)日：1989-09-12

申请号：US70712

申请日：1987-07-07

申请人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

发明人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

IPC分类号： A01N37/08 ,  A01N37/42 ,  C07C51/00 ,  C07C62/24 ,  C07C62/38 ,  C07C67/00 ,  C07C69/757 ,  C07D333/22

CPC分类号： A01N37/42 ,  C07D333/22

摘要： A new compound is provided by a cyclohexane derivative of the formula ##STR1## wherein R represents a hydrogen atom or an alkyl group, an alkylthioalkyl group or an unsubstituted or substituted phenyl group; and R.sup.1 represents an alkyl group, an unsubstituted or substituted benzyl group, a phenethyl group, a phenoxymethyl group, a 2-thienylmethyl group, an alkoxymethyl group or an alkylthiomethyl group, or a salt of said cyclohexane compound.This cyclohexane compound exhibits useful plant-growth regulating effects on crop-plants and also non-crop plants such as lawn and may be prepared by cyclization of an acetonylsuccinic acid dialkyl ester, followed by reaction with an organic acid chloride and by intermolecular rearrangement.

公开(公告)号：US4678496A

公开(公告)日：1987-07-07

申请号：US761497

申请日：1985-08-01

申请人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

发明人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

IPC分类号： A01N37/08 ,  A01N37/42 ,  C07C51/00 ,  C07C62/24 ,  C07C62/38 ,  C07C67/00 ,  C07C69/757 ,  C07D333/22 ,  A01N43/10 ,  C07C62/26 ,  C07C87/68

CPC分类号： A01N37/42 ,  C07D333/22

摘要： As new compound is provided a cyclohexane derivative of the formula ##STR1## wherein R represents a hydrogen atom or an alkyl group, an alkylthioalkyl group or an unsubstituted or substituted phenyl group; and R.sup.1 represents an alkyl group, an unsubstituted or substituted benzyl group, a phenethyl group, a phenoxymethyl group, a 2-thienylmethyl group, an alkoxymethyl group or an alkylthiomethyl group, or a salt of said cyclohexane compound.This cyclohexane compound exhibits useful plant-growth regulating effects on crop-plants and also non-crop plants such as lawn and may be prepared by cyclization of an acetonylsuccinic acid dialkyl ester, followed by reaction with an organic acid chloride and by intermolecular rearrangement.

公开(公告)号：US4560403A

公开(公告)日：1985-12-24

申请号：US534827

申请日：1983-09-22

申请人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

发明人： Kenji Motojima ,  Takeshige Miyazawa ,  Yasufumi Toyokawa ,  Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano

IPC分类号： A01N37/08 ,  A01N37/42 ,  C07C51/00 ,  C07C62/24 ,  C07C62/38 ,  C07C67/00 ,  C07C69/757 ,  C07D333/22 ,  C07C87/30 ,  C07C91/26

CPC分类号： A01N37/42 ,  C07D333/22

摘要： As new compound is provided a cyclohexane derivative of the formula ##STR1## wherein R represents a hydrogen atom or an alkyl group, an alkylthioalkyl group or an unsubstituted or substituted phenyl group; and R.sup.1 represents an alkyl group, an unsubstituted or substituted benzyl group, a phenethyl group, a phenoxymethyl group, a 2-thienylmethyl group, an alkoxymethyl group or an alkylthiomethyl group, or a salt of said cyclohexane compound.This cyclohexane compound exhibits useful plant-growth regulating effects on crop-plants and also non-crop plants such as lawn and may be prepared by cyclization of an acetonylsuccinic acid dialkyl ester, followed by reaction with an organic acid chloride and by intermolecular rearrangement.

公开(公告)号：US4875930A

公开(公告)日：1989-10-24

申请号：US186663

申请日：1988-04-26

申请人： Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano ,  Takeshige Miyazawa ,  Yasufumi Toyokawa

发明人： Masafumi Matsuzawa ,  Hiroshi Hokari ,  Shoji Kusano ,  Takeshige Miyazawa ,  Yasufumi Toyokawa

IPC分类号： A01N37/44 ,  A01N37/50 ,  A01N39/02 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  C07D213/38 ,  C07D213/86 ,  C07D213/87 ,  C07D295/13 ,  C07D307/52 ,  C07D307/68 ,  C07D333/20 ,  C07D333/38

CPC分类号： C07D213/86 ,  A01N37/44 ,  A01N37/50 ,  A01N39/02 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  C07D213/38 ,  C07D213/87 ,  C07D295/13 ,  C07D307/52 ,  C07D307/68 ,  C07D333/20 ,  C07D333/38

摘要： As new compound is provided a cyclohexane derivative of the formula ##STR1## wherein R.sup.1 is a hydrogen or a lower alkyl; R.sup.2 is a lower alkyl; R.sup.3 is a hydrogen, an alkyl, an alkenyl, a hydroxyalkyl, a cycloalkyl, a morpholino, an aminoalkyl, an N-alkylaminoalkyl, an N,N-di-alkylaminoalkyl, an alkoxycarbonylalkyl, a group of the formula --(CH.sub.2).sub.l --R.sup.4 where R.sup.4 is a lower alkoxy, a lower alkylthio, a benzylthio, an anilino, a morpholino, a piperazino, a piperidino or a lower alkyl-substituted piperidino and l is 2 or 3, a group of the formula ##STR2## where X is a halogen, a lower alkyl, a lower alkoxy, a phenoxy or an alkoxycarbonylalkyloxy, m is zero or 1 and n is an integer of zero to 2, inclusive, a group of the formula --CH.sub.2 --R.sup.5 where R.sup.5 is a furyl, a thenyl or a pyridyl, or a group of the formula ##STR3## where R.sup.5 is as defined above; or a salt of said cyclohexane derivative.This cyclohexane derivative exhibits useful plant growth regulating effects on crop-plants and also non-crop-plant such as lawn.

摘要翻译： 当提供新化合物时，式（I）的环己烷衍生物其中R 1是氢或低级烷基; R2是低级烷基; R3是氢，烷基，烯基，羟基烷基，环烷基，吗啉代，氨基烷基，N-烷基氨基烷基，N，N-二 - 烷基氨基烷基，烷氧基羰基烷基，式 - （CH2） -R4，其中R4是低级烷氧基，低级烷硫基，苄硫基，苯胺基，吗啉代，哌嗪子基，哌啶子基或低级烷基取代的哌啶子基，l是2或3，式 X为卤素，低级烷基，低级烷氧基，苯氧基或烷氧基羰基烷氧基，m为0或1，n为0〜2的整数，包括式-CH 2 -R 5的基团，其中R 5为呋喃基 ，草酰基或吡啶基，或者式为“IMAGE”的基团，其中R5如上定义; 或所述环己烷衍生物的盐。 该环己烷衍生物对作物植物以及非作物植物如草坪表现出有用的植物生长调节作用。

公开(公告)号：US5019151A

公开(公告)日：1991-05-28

申请号：US511346

申请日：1990-04-19

申请人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Takayoshi Takehi

发明人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Takayoshi Takehi

IPC分类号： A01N43/54 ,  C07D239/52 ,  C07D239/60 ,  C07D401/12

CPC分类号： C07D401/12 ,  A01N43/54 ,  C07D239/52 ,  C07D239/60

摘要： A 2-phenoxypridimine derivative having the formula: ##STR1## wherein X is a halogen atom or ##STR2## wherein X.sup.1 is a halogen atom, a lower alkyl group or a lower alkoxy group and k is 0, 1, or 2; R.sup.1 is a hydrogen atom, a benzyl group, --(CH.sub.2).sub.m R.sup.3 is a cyano group, a formyl group, a dialkylamino group, a phenyl group, a pyridyl group, a trimethylsilyl group, a naphthyl group, an alkoxycarbonyl group, a benzoyl group, an alkylthio group, a phenylthio group, an alkylsulfonyl group or a benzyloxy group and m is 1, 2, or ##STR3## wherein R.sup.4 is a hydrogen atom or a lower alkyl group, R.sup.5 is a lower alkyl group or ##STR4## wherein X.sup.2 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a nitro group, n is 0 or 1, provided that when R.sup.5 is an alkyl group, n is 1; and R.sup.2 is a chlorine atom or a methoxy group, provided that when R.sup.1 is a hydrogen atom or a benzyl group, X is ##STR5## and R.sup.2 is a methoxy group, when R.sup.1 is ##STR6## X is a chlorine atom at the 6-position and R.sup.2 is a methoxy group, and when R.sup.1 is --(CH.sub.2).sub.m R.sup.3, X is a halogen atom at the 6-position.

公开(公告)号：US4969949A

公开(公告)日：1990-11-13

申请号：US326638

申请日：1989-03-21

申请人： Masahiro Shigematsu ,  Shoji Kusano ,  Takayoshi Takehi ,  Takeshige Miyazawa ,  Yasufumi Toyokawa

发明人： Masahiro Shigematsu ,  Shoji Kusano ,  Takayoshi Takehi ,  Takeshige Miyazawa ,  Yasufumi Toyokawa

IPC分类号： A01N43/54 ,  C07D213/78 ,  C07D401/12

CPC分类号： C07D401/12 ,  A01N43/54 ,  C07D213/78

摘要： A pyrimidine derivative of the formula: ##STR1## wherein each of R.sup.1 and R.sup.2 which may be the same or different is an alkyl group, or R.sup.1 and R.sup.2 together with the adjacent carbon atom form a ring.

公开(公告)号：US4946495A

公开(公告)日：1990-08-07

申请号：US181319

申请日：1988-04-13

申请人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Takayoshi Takehi

发明人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Takayoshi Takehi

IPC分类号： A01N43/54 ,  C07D239/52 ,  C07D239/60 ,  C07D401/12

CPC分类号： C07D401/12 ,  A01N43/54 ,  C07D239/52 ,  C07D239/60

摘要： A 2-phenoxypyrimidine derivative having the formula: ##STR1## wherein X is a halogen atom or ##STR2## wherein X.sup.1 is a halogen atom, a lower alkyl group or a lower alkoxy group and k is 0, 1 or 2; R.sup.1 is a hydrogen atom, a benzyl group, --(CH.sub.2).sub.m R.sup.3 wherein R.sup.3 is a cyano group, a formyl group, a dialkylamino group, a phenyl group, a pyridyl group, a trimethylsilyl group, a naphthyl group, an alkoxycarbonyl group, a benzoyl group, an alkylthio group, a phenylthio group, an alkylsulfonyl group or a benzyloxy group and m is 1, 2 or 3, or ##STR3## wherein R.sup.4 is a hydrogen atom or a lower alkyl group, R.sup.5 is a lower alkyl group or ##STR4## wherein X.sup.2 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a nitro group, n is 0 or 1, provided that when R.sup.5 is an alkyl group, n is 1; and R.sup.2 is a chlorine atom or a methoxy group, provided that when R.sup.1 is a hydrogen atom or a benzyl group, X is ##STR5## and R.sup.2 is a methoxy group, when R.sup.1 is ##STR6## X is a chlorine atom at the 6-position and R.sup.2 is a methoxy group, and when R.sup.1 is --(CH.sub.2).sub.m R.sup.3, X is a halogen atom at the 6-position.

公开(公告)号：US4889552A

公开(公告)日：1989-12-26

申请号：US181366

申请日：1988-04-13

申请人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi

发明人： Nobuhide Wada ,  Yoshihiro Saito ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Satoru Takahashi

IPC分类号： A01N43/54 ,  C07D239/60 ,  C07D405/12

CPC分类号： C07D405/12 ,  A01N43/54 ,  C07D239/60

摘要： A 2-phenoxypyrimidine derivative having the formula: ##STR1## wherein R is a formyl group or --COOR.sup.1 wherein R.sup.1 is a hydrogen atom, a lower alkyl group, a 2-methylsulfonylethyl group, a diethoxypropyl group, a lower alkenyl group, a lower alkynyl group, a haloalkyl group, a haloalkenyl group, an alkoxyalkyl group, a hydroxyalkyl group, a cycloalkyl group, a phenyl group or ##STR2## wherein Y is a halogen atom, a methyl group or a methoxy group and n is 0, 1 or 2; and X is a halogen atom, an alkynyloxy group, an alkenyloxy group, an alkylthio group, an alkoxyalkyloxy group, a haloalkoxy group, an acetyloxy group, a benzoyloxy group, a formyl group, a trifluoromethyl group, a carboxyl group, an alkoxycarbonyl group, a dialkylamino group, a dimethoxymethyl group, ##STR3## wherein R.sup.2 is a hydrogen atom or a methyl group, Z is a chlorine atom or an alkyl group and m is 0, 1 or 2, or ##STR4## wherein R.sup.3 is an alkyl group or a phenyl group, or X forms a methylenedioxy group attached to the adjacent carbon atoms, provided that when X is a halogen atom, it is located at the 6-position of the phenyl group and R is --COOR.sup.1 wherein R.sup.1 is a lower alkenyl group, a lower alkynyl group, a haloalkyl group, a haloalkenyl group, an alkoxyalkyl group, a hydroxyalkyl group, a cycloalkyl group, a phenyl group or ##STR5## wherein Y is a halogen atom, a methyl group or a methoxy group and n is 1 or 2.

公开(公告)号：US4770691A

公开(公告)日：1988-09-13

申请号：US918925

申请日：1986-10-15

申请人： Yukio Nezu ,  Kazuhiko Sugiyama ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Ikuo Kajiwara

发明人： Yukio Nezu ,  Kazuhiko Sugiyama ,  Shoji Kusano ,  Yasufumi Toyokawa ,  Takeshige Miyazawa ,  Ikuo Kajiwara

IPC分类号： A01N43/54 ,  C07D239/34 ,  C07D239/38 ,  C07D239/52 ,  C07D239/56 ,  C07D239/60 ,  C07D403/12 ,  C07D405/12 ,  C07D239/28

CPC分类号： C07D239/34 ,  A01N43/54 ,  C07D239/52 ,  C07D239/56 ,  C07D239/60 ,  C07D403/12 ,  C07D405/12

摘要： As new compounds are provided 2-(4',6'-di-substituted pyrimidine-2'-yl)oxy- or thio-benzoic acid derivatives of the formula ##STR1## wherein R is hydrogen, hydroxy, alkoxy, alkenyloxy, alkylthio or other substituents, R.sup.1 and R.sup.2 are each a halo, alkyl, alkoxy or other substituents; and X is oxygen or sulfur atom. These new compounds are useful as herbicidal agent effective to inhibit the growth of annual weeds and also perennial weeds predominant in irrigated fields of aquatic rice plants and in plowed fields.

摘要翻译： 当新化合物提供式（IMAGE）的2-（4'，6'-二取代嘧啶-2'-基）氧基或硫代苯甲酸衍生物时，其中R是氢，羟基，烷氧基，烯氧基，烷硫基 或其它取代基，R 1和R 2各自为卤素，烷基，烷氧基或其它取代基; X为氧或硫原子。 这些新化合物可用作抑制一年生杂草生长的除草剂，以及主要在水稻和灌溉田中灌溉的多年生杂草。

公开(公告)号：US4932999A

公开(公告)日：1990-06-12

申请号：US415871

申请日：1989-10-02

申请人： Yoshihiro Saito ,  Nobuhide Wada ,  Shoji Kusano ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Yasuhumi Toyokawa ,  Ikuo Kajiwara

发明人： Yoshihiro Saito ,  Nobuhide Wada ,  Shoji Kusano ,  Takeshige Miyazawa ,  Satoru Takahashi ,  Yasuhumi Toyokawa ,  Ikuo Kajiwara

IPC分类号： A01N43/54 ,  A01P13/00 ,  C07D239/46 ,  C07D239/60

CPC分类号： A01N43/54 ,  C07D239/60

摘要： A pyrimidine compound having the formula: ##STR1## wherein X is a halogen atom, or a salt thereof.