公开(公告)号：US09003833B2

公开(公告)日：2015-04-14

申请号：US13883039

申请日：2011-11-25

申请人： Yoshinori Kotani ,  Zuyi Zhang ,  Akira Sugiyama ,  Kenji Takashima ,  Naoyuki Koketsu

发明人： Yoshinori Kotani ,  Zuyi Zhang ,  Akira Sugiyama ,  Kenji Takashima ,  Naoyuki Koketsu

IPC分类号： C03C11/00 ,  C03C15/00 ,  C03C17/25

CPC分类号： C03C11/005 ,  C03C15/00 ,  C03C17/25 ,  C03C2217/228 ,  C03C2217/23 ,  Y10T428/315

摘要： This invention provides a porous glass with a varied porous structure that shows an excellent optical performance. A method of manufacturing a porous glass comprising: a first step of forming a surface layer containing a boron compound and an alkali metal compound as main ingredients on a matrix glass containing a silicon oxide, a boron oxide and an alkali metal oxide; a second step of heat treatment the matrix glass and the surface layer for phase separation to form a phase-separated glass; and a third step of acid treatment the phase-separated glass to form the porous glass having pores.

摘要翻译： 本发明提供了具有优异的光学性能的多孔玻璃。 一种制造多孔玻璃的方法，包括：在含有氧化硅，氧化硼和碱金属氧化物的基质玻璃上形成含有硼化合物和碱金属化合物作为主要成分的表面层的第一步骤; 对基体玻璃和表面层进行相分离的热处理以形成相分离玻璃的第二步骤; 以及对相分离玻璃进行酸处理以形成具有孔的多孔玻璃的第三步骤。

公开(公告)号：US20130068725A1

公开(公告)日：2013-03-21

申请号：US13700068

申请日：2011-05-20

申请人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

发明人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

IPC分类号： C03C15/00

CPC分类号： C03C15/00 ,  C03C11/005 ,  C03C23/00 ,  C03C23/008

摘要： Provided is a method of producing a porous glass, including selectively etching a phase-separated glass with an acid solution, in which the method allows a processing time to be shortened and suppresses gel-like silica from remaining and being deposited in pores of a porous portion. The method of producing a porous glass includes: immersing the phase-separated glass in a bath containing an acid solution; setting an angle θ, which is formed by a surface to be porosified of the phase-separated glass and a bath liquid surface, to 10° or more to 90° or less; and irradiating the bath with an ultrasonic wave to etch the phase-separated glass, thereby obtaining the porous glass.

摘要翻译： 本发明提供一种多孔玻璃的制造方法，其包括用酸溶液选择性地蚀刻相分离玻璃，其中该方法允许缩短处理时间并抑制凝胶状二氧化硅残留并沉积在多孔玻璃的孔中 一部分。 制造多孔玻璃的方法包括：将相分离的玻璃浸入含有酸溶液的浴中; 将由相分离玻璃和浴液面形成的表面形成的角度θ设定为10°以上至90°以下; 并用超声波照射浴，以蚀刻相分离的玻璃，由此获得多孔玻璃。

公开(公告)号：US09278882B2

公开(公告)日：2016-03-08

申请号：US13699977

申请日：2011-05-20

申请人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

发明人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

IPC分类号： C03C11/00 ,  C03C3/089 ,  C03C3/091 ,  C03C23/00

CPC分类号： C03C11/00 ,  C03C3/089 ,  C03C3/091 ,  C03C11/005 ,  C03C23/008

摘要： Provided is a method of producing porous glass having pores with a uniform pore diameter entirely, particularly in the case of phase-separated glass, including selectively removing a denatured layer formed on the surface of glass easily. The method of producing glass includes: forming phase-separated glass containing silicon oxide, boron oxide, and an alkali metal oxide; bringing an alkaline solution held by a porous supporting member into contact with the denatured layer formed on the surface of the phase-separated glass to remove the denatured layer; and immersing the phase-separated glass with the denatured layer removed therefrom in an acid solution to form pores in the phase-separated glass.

摘要翻译： 本发明提供一种多孔玻璃的制造方法，特别是在相分离玻璃的情况下，特别是选择性地除去形成在玻璃表面上的变性层的孔隙，其孔径均匀。 制造玻璃的方法包括：形成含有氧化硅，氧化硼和碱金属氧化物的相分离玻璃; 使由多孔支撑构件保持的碱性溶液与形成在相分离玻璃的表面上的变性层接触以除去变性层; 并将其中除去的相变玻璃浸入酸溶液中以在相分离的玻璃中形成孔。

公开(公告)号：US20130333419A1

公开(公告)日：2013-12-19

申请号：US14001666

申请日：2012-02-20

申请人： Naoyuki Koketsu ,  Zuyi Zhang ,  Yoshinori Kotani ,  Akira Sugiyama ,  Kenji Takashima

发明人： Naoyuki Koketsu ,  Zuyi Zhang ,  Yoshinori Kotani ,  Akira Sugiyama ,  Kenji Takashima

IPC分类号： C03C11/00

CPC分类号： C03C11/005 ,  C03B32/00

摘要： A method for manufacturing a porous glass includes: forming a phase-separated glass by heating at a temperature in a range of 300 to 500 degrees Celsius for 3 to 50 hours for phase separation of a glass body in which the concentration of SiO2 is 50 to 70 percent by weight, the concentration of B2O3 is 15 to 40 percent by weight, the concentration of Li2O is 1.0 to 8.0 percent by weight, the concentration of Na2O is 2.0 to 8.0 percent by weight, the concentration of K2O is 0.3 to 5.0 percent by weight, the total concentration of Li2O, Na2O, and K2O is 3.5 to 15 percent by weight, and the ratio of the concentration of K2O to the total concentration of Li2O, Na2O, and K2O is 0.10 to 0.30; and forming a porous glass by etching the phase-separated glass.

摘要翻译： 制造多孔玻璃的方法包括：通过在300〜500℃的温度范围内加热3〜50小时来形成相分离玻璃，使SiO 2的浓度为50的玻璃体的相分离为50〜 70重量％，B 2 O 3的浓度为15〜40重量％，Li 2 O的浓度为1.0〜8.0重量％，Na 2 O的浓度为2.0〜8.0重量％，K 2 O的浓度为0.3〜5.0重量％ ，Li2O，Na2O，K2O的总浓度为3.5〜15重量％，K2O的浓度与Li 2 O，Na 2 O，K 2 O的总浓度的比例为0.10〜0.30， 并通过蚀刻相分离的玻璃形成多孔玻璃。

公开(公告)号：US20130224494A1

公开(公告)日：2013-08-29

申请号：US13883039

申请日：2011-11-25

申请人： Yoshinori Kotani ,  Zuyi Zhang ,  Akira Sugiyama ,  Kenji Takashima ,  Naoyuki Koketsu

发明人： Yoshinori Kotani ,  Zuyi Zhang ,  Akira Sugiyama ,  Kenji Takashima ,  Naoyuki Koketsu

IPC分类号： C03C11/00

CPC分类号： C03C11/005 ,  C03C15/00 ,  C03C17/25 ,  C03C2217/228 ,  C03C2217/23 ,  Y10T428/315

摘要： This invention provides a porous glass with a varied porous structure that shows an excellent optical performance. A method of manufacturing a porous glass comprising: a first step of forming a surface layer containing a boron compound and an alkali metal compound as main ingredients on a matrix glass containing a silicon oxide, a boron oxide and an alkali metal oxide; a second step of heat treatment the matrix glass and the surface layer for phase separation to form a phase-separated glass; and a third step of acid treatment the phase-separated glass to form the porous glass having pores.

摘要翻译： 本发明提供了具有优异的光学性能的多孔玻璃。 一种制造多孔玻璃的方法，包括：在含有氧化硅，氧化硼和碱金属氧化物的基质玻璃上形成含有硼化合物和碱金属化合物作为主要成分的表面层的第一步骤; 对基体玻璃和表面层进行相分离的热处理以形成相分离玻璃的第二步骤; 以及对相分离玻璃进行酸处理以形成具有孔的多孔玻璃的第三步骤。

公开(公告)号：US20130192306A1

公开(公告)日：2013-08-01

申请号：US13876692

申请日：2011-09-16

申请人： Akira Sugiyama ,  Zuyi Zhang ,  Yoshinori Kotani ,  Kenji Takashima

发明人： Akira Sugiyama ,  Zuyi Zhang ,  Yoshinori Kotani ,  Kenji Takashima

IPC分类号： C03C11/00

CPC分类号： C03C11/005 ,  C03C3/091

摘要： There is provided a method for producing a porous glass having high porosity and nanosized pores even at a deeper portion in the glass.A method for producing a porous glass includes the steps of preparing a glass body containing boron, subjecting the glass body to heat treatment for phase separation, and bringing the phase-separated glass body into contact with a boron-containing solution having a boron concentration of 5 to 140 ppm.

摘要翻译： 提供了即使在玻璃中的较深部分也制造具有高孔隙率和纳米孔的多孔玻璃的方法。 制造多孔玻璃的方法包括以下步骤：制备含有硼的玻璃体，使玻璃体进行相分离热处理，使相分离的玻璃体与硼浓度为 5〜140ppm。

公开(公告)号：US20130157026A1

公开(公告)日：2013-06-20

申请号：US13819272

申请日：2011-08-25

申请人： Yoshinori Kotani ,  Zuyi Zhang ,  Kenji Takashima ,  Akira Sugiyama

发明人： Yoshinori Kotani ,  Zuyi Zhang ,  Kenji Takashima ,  Akira Sugiyama

IPC分类号： C03C11/00 ,  B32B3/26 ,  B32B7/02

CPC分类号： C03C11/005 ,  B32B3/26 ,  B32B7/02 ,  C03C3/091 ,  C03C17/006 ,  C03C2217/425 ,  C03C2217/732 ,  C03C2217/91 ,  Y10T428/24967 ,  Y10T428/249969

摘要： The present invention provides a porous glass having excellent antireflection performance for visible light. A porous glass includes a porous layer which is mainly composed of silica and which has pores attributed to spinodal phase separation and pores attributed to binodal phase separation.

摘要翻译： 本发明提供一种对可见光具有优异的抗反射性能的多孔玻璃。 多孔玻璃包括主要由二氧化硅构成的多孔层，其具有由于旋节相分离的孔隙和归因于双相分离的孔。

公开(公告)号：US20130074548A1

公开(公告)日：2013-03-28

申请号：US13699977

申请日：2011-05-20

申请人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

发明人： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani

IPC分类号： C03C11/00

CPC分类号： C03C11/00 ,  C03C3/089 ,  C03C3/091 ,  C03C11/005 ,  C03C23/008

摘要： Provided is a method of producing porous glass having pores with a uniform pore diameter entirely, particularly in the case of phase-separated glass, including selectively removing a denatured layer formed on the surface of glass easily. The method of producing glass includes: forming phase-separated glass containing silicon oxide, boron oxide, and an alkali metal oxide; bringing an alkaline solution held by a porous supporting member into contact with the denatured layer formed on the surface of the phase-separated glass to remove the denatured layer; and immersing the phase-separated glass with the denatured layer removed therefrom in an acid solution to form pores in the phase-separated glass.

摘要翻译： 本发明提供一种多孔玻璃的制造方法，特别是在相分离玻璃的情况下，特别是选择性地除去形成在玻璃表面上的变性层的孔隙，其孔径均匀。 制造玻璃的方法包括：形成含有氧化硅，氧化硼和碱金属氧化物的相分离玻璃; 使由多孔支撑构件保持的碱性溶液与形成在相分离玻璃的表面上的变性层接触以除去变性层; 并将其中除去的相变玻璃浸入酸溶液中以在相分离的玻璃中形成孔。

公开(公告)号：US09162920B2

公开(公告)日：2015-10-20

申请号：US14001666

申请日：2012-02-20

申请人： Naoyuki Koketsu ,  Zuyi Zhang ,  Yoshinori Kotani ,  Akira Sugiyama ,  Kenji Takashima

发明人： Naoyuki Koketsu ,  Zuyi Zhang ,  Yoshinori Kotani ,  Akira Sugiyama ,  Kenji Takashima

IPC分类号： C03C23/00 ,  C03C11/00 ,  C03B32/00

CPC分类号： C03C11/005 ,  C03B32/00

摘要： A method for manufacturing a porous glass includes: forming a phase-separated glass by heating at a temperature in a range of 300 to 500 degrees Celsius for 3 to 50 hours for phase separation of a glass body in which the concentration of SiO2 is 50 to 70 percent by weight, the concentration of B2O3 is 15 to 40 percent by weight, the concentration of Li2O is 1.0 to 8.0 percent by weight, the concentration of Na2O is 2.0 to 8.0 percent by weight, the concentration of K2O is 0.3 to 5.0 percent by weight, the total concentration of Li2O, Na2O, and K2O is 3.5 to 15 percent by weight, and the ratio of the concentration of K2O to the total concentration of Li2O, Na2O, and K2O is 0.10 to 0.30; and forming a porous glass by etching the phase-separated glass.

摘要翻译： 制造多孔玻璃的方法包括：通过在300〜500℃的温度范围内加热3〜50小时来形成相分离玻璃，使SiO 2的浓度为50的玻璃体的相分离为50〜 70重量％，B 2 O 3的浓度为15〜40重量％，Li 2 O的浓度为1.0〜8.0重量％，Na 2 O的浓度为2.0〜8.0重量％，K 2 O的浓度为0.3〜5.0重量％ ，Li2O，Na2O，K2O的总浓度为3.5〜15重量％，K2O的浓度与Li 2 O，Na 2 O，K 2 O的总浓度的比例为0.10〜0.30， 并通过蚀刻相分离的玻璃形成多孔玻璃。

公开(公告)号：US20130216775A1

公开(公告)日：2013-08-22

申请号：US13881006

申请日：2011-11-01

申请人： Akira Sugiyama ,  Zuyi Zhang ,  Yoshinori Kotani ,  Kenji Takashima ,  Naoyuki Koketsu

发明人： Akira Sugiyama ,  Zuyi Zhang ,  Yoshinori Kotani ,  Kenji Takashima ,  Naoyuki Koketsu

IPC分类号： C03C17/02

CPC分类号： C03C17/02 ,  C03C17/006 ,  C03C2217/425 ,  Y10T428/24331

摘要： Provided is an optical member having high strength, low reflection, and a high transmittance. The optical member includes: a transparent substrate; and a porous glass layer having a spinodal-type porous structure disposed on the transparent substrate, in which at least one of the average pore diameter of a pore formed in the porous glass layer and the average skeleton diameter of a skeleton of the porous glass layer is set so that the optical member has a transmittance of 50% or more in the wavelength region of 450 nm or more and 650 nm or less.

摘要翻译： 提供了具有高强度，低反射和高透射率的光学构件。 光学构件包括：透明基板; 以及多孔玻璃层，其具有设置在所述透明基板上的旋节多孔结构，其中，形成在所述多孔玻璃层中的孔的平均孔径和所述多孔玻璃层的骨架的平均骨架直径中的至少一个 被设定为使得光学部件在450nm以上且650nm以下的波长区域具有50％以上的透射率。