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    Higher molecular weight arylene sulfide resin and process for its preparation
    1.
    发明授权
    Higher molecular weight arylene sulfide resin and process for its preparation 失效
    较高分子量的亚芳基硫醚树脂及其制备方法

    公开(公告)号：US5110901A

    公开(公告)日：1992-05-05

    申请号：US580720

    申请日：1990-09-11

    申请人： Kenneth C. Hoover ,  Earl Clark, Jr. ,  Roy E. Reger ,  Lacey E. Scoggins ,  Afif M. Nesheiwat

    发明人： Kenneth C. Hoover ,  Earl Clark, Jr. ,  Roy E. Reger ,  Lacey E. Scoggins ,  Afif M. Nesheiwat

    IPC分类号： C08G75/02

    CPC分类号： C08G75/0259

    摘要： In a first embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises at least one dihaloaromatic compound. The amount of alkali metal carboxylate present during the polymerization process ranges from about 0.01 to about 0.03 mole per each mole of sulfur present in the resulting arylene sulfide resin. The total amount of water present during the polymerization process ranges from about 1.02 to about 2.1 moles per each mole of sulfur present in the resulting arylene sulfide resin.In a second embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises a mixture of at least one dihaloaromatic compound and at least one polyhaloaromatic compound having more than two halogen substituents per molecule. The ranges of the amount of alkali metal carboxylate present during the polymerization process and the total amount of water present during the polymerization process are identical to those amounts disclosed in the first embodiment. The amount of polyhaloaromatic compound initially present ranges from about 0.0001 to about 0.01 mole per each mole of dihaloaromatic compound present prior to the initiation of the polymerization process.

    摘要翻译： 在第一个实施方案中，亚芳基硫醚树脂通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体源接触来提供，所述反应物包括至少一种 二卤化合物。 在聚合过程中存在的碱金属羧酸盐的量为所得亚芳基硫醚树脂中存在的每摩尔硫的约0.01至约0.03摩尔。 在聚合过程中存在的水的总量范围为所得亚芳基硫醚树脂中存在的每摩尔硫的约1.02至约2.1摩尔。 在第二个实施方案中，亚芳基硫醚树脂是通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体来源接触来提供的， 至少一种二卤代芳族化合物和每分子具有多于两个卤素取代基的至少一种多卤芳族化合物。 在聚合过程中存在的碱金属羧酸盐的量的范围和在聚合过程中存在的水的总量与第一实施方案中公开的量相同。 在开始聚合过程之前，存在的每摩尔二卤代芳族化合物最初存在的多卤代芳族化合物的量为约0.0001至约0.01摩尔。

    Aromatic sulfide/sulfone polymer production
    3.
    发明授权
    Aromatic sulfide/sulfone polymer production 失效
    芳香族硫化物/砜聚合物生产

    公开(公告)号：US5134224A

    公开(公告)日：1992-07-28

    申请号：US654983

    申请日：1991-02-14

    申请人： Afif M. Nesheiwat ,  Lacey E. Scoggins ,  Melvin D. Herd

    发明人： Afif M. Nesheiwat ,  Lacey E. Scoggins ,  Melvin D. Herd

    IPC分类号： C08G75/02 ,  C08G75/20

    CPC分类号： C08G75/02 ,  C08G75/20

    摘要： According to this invention, improved results in terms of molecular weight and percent yield of aromatic sulfide/sulfone polymers are achieved by the employment of a low level modifying agent within a specific range in the polymerization reaction mixture. The modifying agent employed is a salt of an amino carboxylic acid. The salt can be employed as an already existing salt of an amino carboxylic acid or can be formed in situ by employing either an amino carboxylic acid and a base; or a lactam and a base.

    摘要翻译： 根据本发明，通过在聚合反应混合物中使用特定范围内的低水平改性剂，可以获得芳族硫化物/砜聚合物的分子量和产率百分数的改进结果。 所用的改性剂是氨基羧酸的盐。 盐可以用作氨基羧酸的已经存在的盐，或者可以通过使用氨基羧酸和碱来原位形成; 或内酰胺和碱。

    Production of granular poly(arylene sulfide) polymers containing reduced amounts of oligomers
    5.
    发明授权
    Production of granular poly(arylene sulfide) polymers containing reduced amounts of oligomers 失效
    含有减少量的低聚物的粒状聚（亚芳基硫醚）聚合物的生产

    公开(公告)号：US5374709A

    公开(公告)日：1994-12-20

    申请号：US965833

    申请日：1992-10-23

    申请人： Earl Clark, Jr. ,  Lacey E. Scoggins ,  Glenn F. Kile

    发明人： Earl Clark, Jr. ,  Lacey E. Scoggins ,  Glenn F. Kile

    IPC分类号： C08G75/02 ,  C08G75/06 ,  C08G75/16

    CPC分类号： C08G75/0281 ,  C08G75/0259

    摘要： A method for removing oligomers and non-polymeric impurities from poly(arylene sulfide) polymers and producing the polymers in easily recoverable granular form is provided in which a poly(arylene sulfide) polymer associated with oligomers and non-polymeric impurities is contacted with a solvent, water, and optionally, a base, at a sufficient temperature to substantially dissolve the polymer, oligomers and impurities; then the solution is cooled to a temperature at which the poly(arylene sulfide) precipitates while oligomers and impurities remain in solution, then the precipitated polymer is separated from the solution containing the oligomers and impurities. A polymer product produced by this method is also disclosed.

    摘要翻译： 提供了一种从聚（亚芳基硫醚）聚合物中除去低聚物和非聚合物杂质并以易于回收的颗粒形式生产聚合物的方法，其中与低聚物和非聚合物杂质缔合的聚（亚芳基硫醚）聚合物与溶剂 ，水和任选的碱，以足够的温度基本上溶解聚合物，低聚物和杂质; 然后将溶液冷却至聚（亚芳基硫醚）沉淀的温度，同时将低聚物和杂质保留在溶液中，然后将沉淀的聚合物与含有低聚物和杂质的溶液分离。 还公开了通过该方法生产的聚合物产品。

    Poly(arylene sulfide)composites and methods of production
    9.
    发明授权
    Poly(arylene sulfide)composites and methods of production 失效
    聚（亚芳基硫醚）复合材料及其生产方法

    公开(公告)号：US5286561A

    公开(公告)日：1994-02-15

    申请号：US4604

    申请日：1993-01-14

    申请人： Timothy W. Johnson ,  Lacey E. Scoggins

    发明人： Timothy W. Johnson ,  Lacey E. Scoggins

    IPC分类号： C08G75/04 ,  C08G75/02 ,  C08G75/06 ,  C08J3/20 ,  C08L81/02 ,  D02G3/00

    CPC分类号： C08J3/20 ,  C08G75/0277 ,  C08J2381/02 ,  Y10T428/2933 ,  Y10T442/2025 ,  Y10T442/2549 ,  Y10T442/2631

    摘要： The present invention provides: (a) a method for producing a poly(arylene sulfide)(PAS) resin composition: (b) a PAS resin composition produced by the inventive resin composition production method; (c) a method which utilizes the inventive PAS resin composition in the production of a continuous fiber-reinforced composite; and (d) a PAS composite produced by the inventive composite production method. The PAS resin composition produced by the inventive resin composition production method comprises a crystallizable arylene sulfide polymer and a nucleating agent. The nucleating agent is admixed with the crystallizable arylene sulfide polymer by adding said nucleating agent to the polymerization reaction system. The inventive PAS resin composition solidifies to a fine-grained crystalline morphology and is well suited for use in the production of continuous fiber-reinforced composites, molded articles, and other products.

    摘要翻译： 本发明提供：（a）聚（亚芳基硫醚）（PAS）树脂组合物的制造方法：（b）通过本发明的树脂组合物制造方法制造的PAS树脂组合物; （c）利用本发明的PAS树脂组合物生产连续纤维增强复合材料的方法; 和（d）通过本发明的复合生产方法制备的PAS复合材料。 通过本发明的树脂组合物制备方法制备的PAS树脂组合物包含可结晶的亚芳基硫醚聚合物和成核剂。 通过将所述成核剂加入到聚合反应体系中，将成核剂与可结晶的亚芳基硫醚聚合物混合。 本发明的PAS树脂组合物固化成细晶粒结晶形态，并且非常适合用于生产连续纤维增强复合材料，模塑制品和其它产品。

    Arylene sulfide polymerization; arylene sulfide polymer treated with aromatic compound having more than 2 halogen substituents; processed product thereof
    10.
    发明授权
    Arylene sulfide polymerization; arylene sulfide polymer treated with aromatic compound having more than 2 halogen substituents; processed product thereof 失效
    亚芳基硫化物聚合; 用具有多于2个卤素取代基的芳族化合物处理的亚芳基硫醚聚合物; 其加工产品

    公开(公告)号：US4656231A

    公开(公告)日：1987-04-07

    申请号：US490607

    申请日：1983-05-02

    申请人： Dale O. Tieszen ,  Lacey E. Scoggins

    发明人： Dale O. Tieszen ,  Lacey E. Scoggins

    IPC分类号： C08G75/02 ,  C08G75/14

    CPC分类号： C08G75/0231 ,  C08G75/025

    摘要： A process for the production and use of branched polymers of arylene sulfide in which (A) a reaction mixture of (1) at least one p-dihalo-benzene, (2) at least one alkali metal sulfide, (3) at least one organic amide, (4) water in an amount of about 1.0 mole to about 2.4 moles per mole of alkali metal sulfide, and (5) at least one alkali metal carboxylate is contacted under polymerization conditions for a time sufficient to form arylene sulfide polymer and the arylene sulfide polymer formed in said reaction mixture is contacted under polymerization conditions with a polyhaloaromatic compound having more than two halogen substituents per molecule for a time having a range of up to about 75 minutes before entering upon termination of the polymerization process, (B) the reaction mixture is contacted with carbon dioxide, (C) volatiles are removed from the reaction mixture, (D) arylene sulfide polymer is recovered from the reaction mixture, (E) the recovered polymer is washed, and (F) the polymer is further processed, as by molding, extruding into film or sheet, or used as a coating. An embodiment of the process in which the alkali metal sulfide is produced in situ by the reaction of an excess of alkali metal hydroxide with alkali metal hydrosulfide. An embodiment in which carbon dioxide is contacted with arylene sulfide polymer formed in the reaction mixture to stabilize the polymer. A molded object, a film, a sheet, or a coating composition that is the product of the reaction and work-up process above.

    摘要翻译： 一种制备和使用亚芳基硫醚支化聚合物的方法，其中（A）（1）至少一种对二卤代苯，（2）至少一种碱金属硫化物，（3）至少一种 有机酰胺，（4）每摩尔碱金属硫化物约1.0摩尔至约2.4摩尔量的水，和（5）至少一种碱金属羧酸盐在聚合条件下接触足以形成亚芳基硫醚聚合物的时间， 在聚合反应混合物中形成的亚芳基硫醚聚合物在聚合过程终止前进入聚合过程之前，在每分子具有多于两个卤素取代基的多卤代芳族化合物接触达一至约75分钟范围内的时间，（B） 反应混合物与二氧化碳接触，（C）从反应混合物中除去挥发物，（D）从反应混合物中回收亚芳基硫化物聚合物，（E）洗涤回收的聚合物，（F） 进一步加工奥氏体，通过成型，挤出成膜或片，或用作涂层。 通过过量碱金属氢氧化物与碱金属氢硫化物的反应原位产生碱金属硫化物的方法的一个实施方案。 二氧化碳与反应混合物中形成的亚芳基硫醚聚合物接触以稳定聚合物的实施方案。 作为上述反应和后处理工序的产物的成型体，膜，片，或涂料组合物。