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1.发明授权Production of granular poly(arylene sulfide) polymers containing reduced amounts of oligomers 失效含有减少量的低聚物的粒状聚（亚芳基硫醚）聚合物的生产
公开(公告)号：US5374709A
公开(公告)日：1994-12-20
申请号：US965833
申请日：1992-10-23
CPC分类号： C08G75/0281 , C08G75/0259
摘要： A method for removing oligomers and non-polymeric impurities from poly(arylene sulfide) polymers and producing the polymers in easily recoverable granular form is provided in which a poly(arylene sulfide) polymer associated with oligomers and non-polymeric impurities is contacted with a solvent, water, and optionally, a base, at a sufficient temperature to substantially dissolve the polymer, oligomers and impurities; then the solution is cooled to a temperature at which the poly(arylene sulfide) precipitates while oligomers and impurities remain in solution, then the precipitated polymer is separated from the solution containing the oligomers and impurities. A polymer product produced by this method is also disclosed.
摘要翻译： 提供了一种从聚（亚芳基硫醚）聚合物中除去低聚物和非聚合物杂质并以易于回收的颗粒形式生产聚合物的方法，其中与低聚物和非聚合物杂质缔合的聚（亚芳基硫醚）聚合物与溶剂 ，水和任选的碱，以足够的温度基本上溶解聚合物，低聚物和杂质; 然后将溶液冷却至聚（亚芳基硫醚）沉淀的温度，同时将低聚物和杂质保留在溶液中，然后将沉淀的聚合物与含有低聚物和杂质的溶液分离。 还公开了通过该方法生产的聚合物产品。
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2.发明授权Higher molecular weight arylene sulfide resin and process for its preparation 失效较高分子量的亚芳基硫醚树脂及其制备方法
公开(公告)号：US5110901A
公开(公告)日：1992-05-05
申请号：US580720
申请日：1990-09-11
IPC分类号： C08G75/02
CPC分类号： C08G75/0259
摘要： In a first embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises at least one dihaloaromatic compound. The amount of alkali metal carboxylate present during the polymerization process ranges from about 0.01 to about 0.03 mole per each mole of sulfur present in the resulting arylene sulfide resin. The total amount of water present during the polymerization process ranges from about 1.02 to about 2.1 moles per each mole of sulfur present in the resulting arylene sulfide resin.In a second embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises a mixture of at least one dihaloaromatic compound and at least one polyhaloaromatic compound having more than two halogen substituents per molecule. The ranges of the amount of alkali metal carboxylate present during the polymerization process and the total amount of water present during the polymerization process are identical to those amounts disclosed in the first embodiment. The amount of polyhaloaromatic compound initially present ranges from about 0.0001 to about 0.01 mole per each mole of dihaloaromatic compound present prior to the initiation of the polymerization process.
摘要翻译： 在第一个实施方案中，亚芳基硫醚树脂通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体源接触来提供，所述反应物包括至少一种 二卤化合物。 在聚合过程中存在的碱金属羧酸盐的量为所得亚芳基硫醚树脂中存在的每摩尔硫的约0.01至约0.03摩尔。 在聚合过程中存在的水的总量范围为所得亚芳基硫醚树脂中存在的每摩尔硫的约1.02至约2.1摩尔。 在第二个实施方案中，亚芳基硫醚树脂是通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体来源接触来提供的， 至少一种二卤代芳族化合物和每分子具有多于两个卤素取代基的至少一种多卤芳族化合物。 在聚合过程中存在的碱金属羧酸盐的量的范围和在聚合过程中存在的水的总量与第一实施方案中公开的量相同。 在开始聚合过程之前，存在的每摩尔二卤代芳族化合物最初存在的多卤代芳族化合物的量为约0.0001至约0.01摩尔。
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公开(公告)号：US4906701A
公开(公告)日：1990-03-06
申请号：US251425
申请日：1988-09-30
申请人： Earl Clark, Jr.
发明人： Earl Clark, Jr.
IPC分类号： C08F2/32
CPC分类号： C08F2/32
摘要： In an inverse emulsion polymerization system for producing water-soluble polymers from a monomer system comprising an N-vinyl lactam and/or a vinyl-containing sulfonic acid or salt thereof utilizing a surfactant system having (1) a surfactant with a bulky lipophilic portion and a hydrophilic portion and (2) a generally straight-chain nonionic surfactant having a lipophilic hydrocarbon group and an OH-terminated hydrophilic group, i.e. an alcohol. Such a system having both the right HLB and the right chemical cobination results in a stable emulsion for the polymerization of these particular water-soluble monomers.
摘要翻译： 在由包含N-乙烯基内酰胺和/或含乙烯基的磺酸或其盐的单体体系制备水溶性聚合物的反相乳液聚合体系中，所述表面活性剂体系具有（1）具有大体积亲油部分的表面活性剂和 亲水部分和（2）具有亲油性烃基和OH-封端的亲水基团（即醇）的通常为直链的非离子表面活性剂。 具有正确的HLB和正确的化学嵌段的这种体系导致用于这些特定的水溶性单体的聚合的稳定的乳液。
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公开(公告)号：US4808698A
公开(公告)日：1989-02-28
申请号：US103480
申请日：1987-09-30
申请人： Rex L. Bobsein , Earl Clark, Jr.
发明人： Rex L. Bobsein , Earl Clark, Jr.
CPC分类号： C08G75/20 , C08G75/0236 , C08G75/025
摘要： An improved process for the production of high molecular weight aromatic sulfide/sulfone polymer comprising contacting under suitable polymerization conditions: (a) an organic amide, (b) an alkali metal sulfide or hydrosulfide, (c) water, and (d) a dihaloaromatic sulfone wherein the molar ratio of (a) to (b) is about 2:1 to about 24:1, the improvement comprising employing a molar ratio of (a) to (c) of about 0.4:1 to about 1.3:1.
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公开(公告)号：US5932671A
公开(公告)日：1999-08-03
申请号：US868728
申请日：1997-06-04
CPC分类号： C08F2/10
摘要： A process for producing a water-soluble polymer which can be useful in a subterranean formation is provided. The process comprises contacting a an olefinic compound and a thiol under a solution polymerization process for producing the water-soluble polymer.
摘要翻译： 提供了可用于地下地层的水溶性聚合物的制造方法。 该方法包括在溶液聚合方法下使烯属化合物和硫醇接触以制备水溶性聚合物。
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公开(公告)号：US4548982A
公开(公告)日：1985-10-22
申请号：US528922
申请日：1983-09-02
申请人： Earl Clark, Jr. , Howard B. Irvin
发明人： Earl Clark, Jr. , Howard B. Irvin
CPC分类号： C08F8/44 , C09K8/24 , Y10S507/903 , Y10S507/904
摘要： Polymers derived by copolymerizing a hydrophilic vinyl monomer, such as acrylic acid or methacrylic acid, with at least one hydrophobic vinyl monomer, such as an acrylic acid ester, a methacrylic acid ester, a vinyl ester of a saturated monocarboxylic acid having from 1 to 3 carbon atoms, and the like, prepared in a suitable inert, low chain transfer, organic liquid medium, such as n-pentane, n-hexane, cyclohexane, and chlorofluorocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, and neutralized by anhydrous ammonia while still slurried in the inert low chain transfer organic liquid medium, perform effectively as water loss additives for drilling fluids under high temperature conditions. Such water loss control additives are especially effective when employed in drilling fluids having high solids content. Other copolymerization techniques for preparing such polymers are also disclosed. Also disclosed are drilling fluids employing such water loss control additives as well as a method of drilling a borehole in the earth using drilling fluids employing such water loss control additives.
摘要翻译： 通过使亲水性乙烯基单体如丙烯酸或甲基丙烯酸与至少一种疏水性乙烯基单体如丙烯酸酯，甲基丙烯酸酯，饱和一元羧酸的乙烯基酯共聚而得到的聚合物，其具有1至3个 碳原子等，在合适的惰性，低链转移的有机液体介质如正戊烷，正己烷，环己烷和氯氟烃中制备，例如1,1,2-三氯-1,2,2 并在惰性低链转移有机液体介质中仍然浆化的无水氨中和，在高温条件下有效地作为钻井液的失水添加剂。 当用于具有高固体含量的钻井液时，这种失水控制添加剂是特别有效的。 还公开了制备这种聚合物的其它共聚技术。 还公开了采用这种失水控制添加剂的钻井液以及使用这种失水控制添加剂的钻井液在地球上钻井的方法。
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公开(公告)号：US4997582A
公开(公告)日：1991-03-05
申请号：US335150
申请日：1989-04-07
申请人： Earl Clark, Jr. , Billy L. Swanson
发明人： Earl Clark, Jr. , Billy L. Swanson
IPC分类号： C09K8/72
CPC分类号： C09K8/74
摘要： Methods and compositions for acid treating subterranean formations penetrated by well bores are provided. The compositions are each comprised of an aqueous acid solution, one or more acrylamide polymers dissolved in the acid solution, a liquid hydrocarbon dispersed in the acid solution, and one or more nonionic surface active agents having at least one reactive hydroxyl group per molecule. The acrylamide polymer or polymers increase the viscosity of the acid solution and the surface active agent or agents interact with the polymer of polymers whereby stabilized high viscosity results. The subterranean formation acid treating methods of the invention are carried out by introducing the high viscosity acid compositions therein, allowing the compositions to react until spent and recovering the compositions.
摘要翻译： 提供了用井眼渗透的地下地层的酸处理方法和组合物。 所述组合物各自包含酸水溶液，溶解在酸性溶液中的一种或多种丙烯酰胺聚合物，分散在酸性溶液中的液体烃，以及每分子具有至少一个反应性羟基的一种或多种非离子表面活性剂。 丙烯酰胺聚合物或聚合物增加酸溶液的粘度，并且表面活性剂或试剂与聚合物的聚合物相互作用，从而导致稳定的高粘度。 本发明的地层酸处理方法是通过在其中引入高粘度酸组合物进行的，使组合物反应直至消耗并回收组合物。
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公开(公告)号：US4775010A
公开(公告)日：1988-10-04
申请号：US142484
申请日：1988-01-06
申请人： Earl Clark, Jr. , Billy L. Swanson
发明人： Earl Clark, Jr. , Billy L. Swanson
CPC分类号： C09K8/74 , Y10S507/933
摘要： Methods and compositions for acid treating subterranean formations penetrated by well bores are provided. The compositions are each comprised of an aqueous acid solution, one or more acrylamide polymers dissolved in the acid solution, a liquid hydrocarbon dispersed in the acid solution, and one or more nonionic surface active agents having at least one reactive hydroxyl group per molecule. The acrylamide polymer or polymers increase the viscosity of the acid solution and the surface active agent or agents interact with the polymer or polymers whereby stabilized high viscosity results. The subterranean formation acid treating methods of the invention are carried out by introducing the high viscosity acid compositions therein, allowing the compositions to react until spent and recovering the compositions.
摘要翻译： 提供了用井眼渗透的地下地层的酸处理方法和组合物。 所述组合物各自包含酸水溶液，溶解在酸性溶液中的一种或多种丙烯酰胺聚合物，分散在酸性溶液中的液体烃，以及每分子具有至少一个反应性羟基的一种或多种非离子表面活性剂。 丙烯酰胺聚合物或聚合物增加酸溶液的粘度，并且表面活性剂或试剂与聚合物或聚合物相互作用，从而导致稳定的高粘度。 本发明的地层酸处理方法是通过在其中引入高粘度酸组合物进行的，使组合物反应直至消耗并回收组合物。
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9.发明授权Inverse emulsion polymerization with sorbitan fatty acid esters and ethoxylated alcohol 失效与脱水山梨糖醇脂肪酸酯和乙氧基化醇反相乳液聚合
公开(公告)号：US4764574A
公开(公告)日：1988-08-16
申请号：US939641
申请日：1986-12-09
申请人： Earl Clark, Jr.
发明人： Earl Clark, Jr.
IPC分类号： C08F2/32
CPC分类号： C08F2/32 , Y10S526/911
摘要： In an inverse emulsion polymerization system for producing water-soluble polymers from a monomer system comprising an N-vinyl lactam and/or a vinyl-containing sulfonic acid or salt thereof utilizing a surfactant system having (1) a surfactant with a bulky lipophilic portion and an OH-containing hydrophilic portion and (2) a generally straight-chain nonionic surfactant having a lipophilic hydrocarbon group and an OH-terminated hydrophilic group, i.e. an alcohol. Such a system having both the right HLB and the right chemical combination results in a stable emulsion for the polymerization of these particular water-soluble monomers.
摘要翻译： 在由包含N-乙烯基内酰胺和/或含乙烯基的磺酸或其盐的单体体系制备水溶性聚合物的反相乳液聚合体系中，所述表面活性剂体系具有（1）具有大体积亲油部分的表面活性剂和 含OH的亲水部分和（2）具有亲油性烃基和OH封端的亲水基团（即醇）的通常为直链的非离子表面活性剂。 具有正确的HLB和正确的化学组合的这种体系产生用于这些特定的水溶性单体的聚合的稳定的乳液。
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公开(公告)号：US5512261A
公开(公告)日：1996-04-30
申请号：US373828
申请日：1995-01-17
申请人： Earl Clark, Jr. , Jimmie J. Straw
发明人： Earl Clark, Jr. , Jimmie J. Straw
IPC分类号： B01D19/00 , C07B63/00 , C07D333/48 , C01B17/60 , B01D50/00
CPC分类号： C07D333/48
摘要： A process for removing sulfur dioxide in a fluid such as, for example, sulfolene or sulfolane, comprises circulating the fluid in a loop under conditions sufficient to effect the removal of sulfur dioxide from the fluid wherein the loop comprises at least one spraying device such as, for example, a spray nozzle.
摘要翻译： 用于除去流体例如环丁烯砜或环丁砜的二氧化硫的方法包括在足以使流体中除去二氧化硫的条件下在环路中循环流体，其中环路包括至少一种喷射装置，例如 ，例如喷嘴。
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