摘要:
The present invention is directed to the preparation of hybrid composite bodies composed of an essentially alkali-free, alkaline earth aluminosilicate glass matrix reinforced with SiC whiskers and continuous ceramic fibers.
摘要:
There is disclosed a laminated ceramic structure including a facing member and a backing member, the two members being bonded together either directly or through an intermediate layer, the facing member being formed from a very hard ceramic such as a carbide having a KHN.sub.100 value in excess of 1000 kg/mm.sup.2, the backing member being a glass or glass-ceramic matrix having an enhanced capability or absorbing impact energy, preferably being fiber reinforced and having an energy absorbing capacity in excess of 10 KJ/m.sup.2.
摘要翻译:公开了一种层叠陶瓷结构,其包括面向构件和背衬构件,两个构件直接地或通过中间层结合在一起,面对构件由非常硬的陶瓷形成,例如具有超过KHN100值的碳化物 1000kg / mm2的背衬构件是具有增强的能力或吸收冲击能量的玻璃或玻璃 - 陶瓷基体,优选地是纤维增强并具有超过10KJ / m 2的能量吸收能力。
摘要:
The present invention is directed to the preparation hybrid composite bodies composed of an essentially alkali-free, alkaline earth aluminosilicate glass matrix reinforced with SiC whiskers and continuous ceramic fibers.
摘要:
Fiber-reinforced ceramic matrix composites incorporating a glass-ceramic matrix of lithium aluminosilicate composition in which is disposed a fiber reinforcement phase including at least one layer of unidirectionally oriented fibers (e.g. SiC), the matrix further comprising a whisker reinforcement phase selected from the group of SiC, alumina, HfC and Si.sub.3 N.sub.4, the whiskers imparting substantially improved transverse modulus of rupture strength and interlaminar shear strength to the composite.
摘要:
This invention relates to the production of laminated structures consisting essentially of a light weight interior member prepared from a glass, glass-ceramic, or ceramic, an exterior member prepared from a glass, glass-ceramic, or ceramic, and a bonding member prepared from a glass, glass-ceramic, or ceramic. The light weight interior member may be composed of a porous body, a corrugated body, or a honeycomb body. In a preferred embodiment, at least one of said members is reinforced through the entrainment of ceramic fibers and/ or whiskers. In the most preferred embodiment, each exterior and interior member is reinforced through the entrainment of ceramic fibers and/or whiskers and the bonding member is reinforced through the entrainment of ceramic whiskers.
摘要:
The present invention is directed to the production of SiC whisker- and/or fiber-reinforced, internally-nucleated glass-ceramic matrix composite articles consisting essentially of 0.5-60% by weight SiC whiskers and/or 15-70% by volume ceramic fibers substantially uniformly distributed in a glass-ceramic matrix consisting essentially, in weight percent on the oxide basis, of 16-20%, CaO, 38.5-46% Al.sub.2 O.sub.3, 35-42% SiO.sub.2, and up to 10% total of at least one nucleating agent in the indicated proportion selected from the group consisting of 0.1-3% Cr.sub.2 O.sub.3, 0.25-3% HfO.sub.2, 2-5% MoO.sub.3, 0.25-3% Nb.sub.2 O.sub.5, 0.25-3% Ta.sub.2 O.sub.5, 0.25-3% WO.sub.3, and 1-10% ZrO.sub.2, wherein Al.sub.2 O.sub.3 is present in an amount which is at least 5 mole percent and up to 50 mole percent in excess of that present in stoichiometric triclinic anorthite, and wherein the predominant crystal phases in the glass-ceramic are triclinic anorthite and mullite and/or .alpha.-Al.sub.2 O.sub.3. Up to 1.5% As.sub.2 O.sub.3 may advantageously be included in the composition.
摘要:
The present invention is directed to SiC whisker and/or fiber reinforced glass-ceramic matrix composite articles wherein an alkaline earth aluminosilicate constitutes the predominant crystal phase. More particularly the composite articles will consist essentially of 10-60% by weight SiC whiskers and/or 15-70% by volume ceramic fibers and the glass-ceramic matrix will consist essentially, by weight on the oxide basis, of______________________________________ CaO 0-25 MgO 0-15 SrO 0-30 Na.sub.2 O 0-4 CaO + SrO 10-30 K.sub.2 O 0-6 Al.sub.2 O.sub.3 25-38 TiO.sub.2 0-12 SiO.sub.2 35-60 ZrO.sub.2 0-15 BaO 0-25 As.sub.2 O.sub.3 0-3 BaO + MgO + Na.sub.2 O + K.sub.2 O + TiO.sub.2 ZrO.sub.2 + As.sub.2 O.sub.3 0-30 ______________________________________ The preferred predominant crystal phase is selected from the group of anorthite and its pseudo-binaries, with mullite, cordierite, barium osumilite, and albite solid solution.
摘要:
Silicon-carbide-whisker-reinforced cordierite ceramic products are prepared by uniformly incorporating the whiskers in the ceramic batch, forming the batch into a product preform, e.g. by extrusion, and firing the preform according to a process wherein the conversion of the oxide batch materials to cordierite occurs under a non-oxidizing atmosphere. Significant improvements in product strength and thermal downshock resistance are obtained.
摘要:
There is disclosed a fiber-reinforced composite having a high degree of fracture toughness and being composed of a glass-ceramic matrix reinforced with silicon carbide or graphite type fibers, the predominant crystal phase of the matrix glass-ceramic being canasite, and/or agrellite, and/or fedorite.
摘要:
A sealing method and sealed assemblies incorporating novel devitrifiable sealing frits based on thermally crystallizable alkaline earth aluminosilicate glasses, are disclosed. The frits exhibit improved compatibility with refractory composites employed for the fabrication of high temperature fiber-reinforced glass-ceramic assemblies and can be cured at temperatures below those needed to cure prior art sealing compositions to provide strong seals wherein refractory crystal phases selected from the group consisting of anorthite (CaO.Al.sub.2 O.sub.3.2SiO.sub.2), celsian (BaO.Al.sub.2 O.sub.3.2SiO.sub.2), and sanidine, orthoclase or other potash feldspar (K.sub.2 O.Al.sub.2 O.sub.3.6SiO.sub.2) polymorphs constitute the principal phases.