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公开(公告)号：US5817899A
公开(公告)日：1998-10-06
申请号：US876778
申请日：1997-06-16
申请人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
发明人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
IPC分类号： C07C9/22 , C10M107/10 , C07C9/00 , C07C2/02
CPC分类号： C07C9/22 , C10M107/10 , C10M2205/028 , C10N2220/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： A dimer composition has an improved low temperature viscosity if it has less than a certain amount of normal paraffin. A 1-octene dimer should have less than 0.50 wt. % normal hexadecane, a 1-decene dimer should have less than 0.05 wt. % normal eicosane, a 1-dodecene dimer should have less than 0.60 wt. % normal tetracosane, and a 1-tetradecene dimer should have less than 0.10 wt. % normal octacosane.
摘要翻译： 如果二聚体组合物具有小于一定量的正常石蜡，则具有改善的低温粘度。 1-辛烯二聚体应具有少于0.50wt。 正十六烷值为1：1-癸烯二聚体应具有少于0.05wt。 ％正二十烷，1-十二碳烯二聚体应具有小于0.60wt。 ％正二十四烷，而1-十四碳烯二聚体应具有小于0.10wt。 ％正二十八烷。
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2.发明授权
公开(公告)号：US5550307A
公开(公告)日：1996-08-27
申请号：US298635
申请日：1994-08-31
申请人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
发明人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
CPC分类号： C10M107/10 , C07C2/20 , C07C2527/1213 , C07C2531/02
摘要： An oligomer is made by contacting an olefinic monomer with a catalyst comprising boron trifluoride, an alcohol alkoxylate, and a ketone. In one embodiment, the olefinic monomer is a straight-chain, .alpha.-olefinic monomer containing from 8 to 12 carbon atoms, the alcohol alkoxylate is 2-ethoxyethanol, the ketone is methyl ethyl ketone, and the oligomer product has a kinematic viscosity at 100.degree. C. of less than 1.7 cSt. Before removal of unreacted monomer, the oligomer product is at least 50 wt. % dimer, at least 80 wt. % dimer plus trimer, and less than 3.25 wt. % tetramer and greater.
摘要翻译： 通过使烯烃单体与包含三氟化硼，醇烷氧基化物和酮的催化剂接触来制备低聚物。 在一个实施方案中，烯烃单体是含有8至12个碳原子的直链，α-烯烃单体，醇烷氧基化物是2-乙氧基乙醇，酮是甲基乙基酮，低聚物产物的运动粘度在100 ℃小于1.7 cSt。 在除去未反应的单体之前，低聚物产物至少为50wt。 ％二聚体，至少80wt。 ％二聚体加三聚体，小于3.25wt。 四聚体和更大。
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公开(公告)号：US5420373A
公开(公告)日：1995-05-30
申请号：US217265
申请日：1994-03-24
申请人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
发明人： Kenneth D. Hope , Ting C. Ho , Barrett L. Cupples
CPC分类号： C07C2/20 , C10M107/10 , C07C2527/1213 , C07C2531/02
摘要： An oligomer is made by contacting a straight-chain, .alpha.-olefinic monomer with boron trifluoride and a hydroxy carbonyl promoter. The hydroxy carbonyl is preferably a .beta.-hydroxy-ketone, such as 4-hydroxy-4-methyl-2-pentanone. A second promoter can be used in conjunction with the boron trifluoride and the hydroxy carbonyl promoter. Possible secondary promoters include aldehydes, alcohols, alcohol alkoxylates, carboxylic acids, ethers, ketones, and their mixtures. Preferably the oligomer product has a kinematic viscosity at 100.degree. C. of less than 1.7 cSt; has a dimer to trimer and higher oligomer ratio of at least 1:1; and is at least 90 wt. % dimer and trimer of the monomer.
摘要翻译： 通过使直链α-烯烃单体与三氟化硼和羟基羰基促进剂接触来制备低聚物。 羟基羰基优选为β-羟基酮，例如4-羟基-4-甲基-2-戊酮。 第二个启动子可以与三氟化硼和羟基羰基启动子结合使用。 可能的二级助催化剂包括醛，醇，醇烷氧基化物，羧酸，醚，酮及其混合物。 优选地，低聚物产物在100℃下的运动粘度小于1.7cSt; 具有至少1:1的二聚体至三聚体和更高的低聚物比例; 并且为至少90wt。 ％二聚体和三聚体的单体。
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公开(公告)号：US4032591A
公开(公告)日：1977-06-28
申请号：US634624
申请日：1975-11-24
CPC分类号： C10M3/00 , C07C5/13 , C07C9/22 , C10M2205/00 , C10M2205/028 , C10N2240/08
摘要： An alpha-olefin oligomer synthetic lubricant having an improved viscosity-volatility relationship is prepared from an alpha-olefin such as 1-decene.
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公开(公告)号：US4213001A
公开(公告)日：1980-07-15
申请号：US955210
申请日：1978-10-27
CPC分类号： C07C2/20 , C07C2527/1213
摘要： A method of homopolymerizing a 1-olefin to a product including the trimer and tetramer by utilizing boron trifluoride under pressure in the presence of a suspended particulate adsorbent material. For example, 1-decene is homopolymerized at a temperature of about 25.degree. C. in the presence of a suspension of about two weight percent silica and boron trifluoride at a pressure of 125 psi.
摘要翻译： 在悬浮颗粒吸附剂材料存在下，通过利用三氟化硼在压力下使包含三聚体和四聚物的产物均聚在一起的方法。 例如，在125psi的压力下，在大约二重量百分比的二氧化硅和三氟化硼的悬浮液的存在下，1-癸烯在约25℃的温度下均聚。
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公开(公告)号：US4045508A
公开(公告)日：1977-08-30
申请号：US633677
申请日：1975-11-20
CPC分类号： C07C2/20 , C07C2527/1213 , Y10S585/925 , Y10S585/926
摘要： The trimer to tetramer ratio of an alpha-olefin oligomer is varied over a significant range in a continuous, multi-stage alpha-olefin oligomerization process including a first stage tank reactor and a final tube reactor by controlling the amount of conversion taking place in each stage. The multi-stage process is used to prepare various poly(l-decene) oligomer mixtures having different oligomer proportions for use as synthetic lubricants.
摘要翻译： 在连续的多级α-烯烃低聚方法中，α-烯烃低聚物的三聚体与四聚体的比例在包括第一级罐式反应器和最终的管式反应器的连续的多级α-烯烃低聚方法中变化，通过控制在每个反应器中发生的转化量 阶段。 多级方法用于制备具有不同低聚物比例的各种聚（1-癸烯）低聚物混合物，用作合成润滑剂。
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公开(公告)号：US4045507A
公开(公告)日：1977-08-30
申请号：US633671
申请日：1975-11-20
CPC分类号： C07C2/20 , C07C2527/1213 , Y10S585/925 , Y10S585/926
摘要： The trimer to tetramer ratio of an alpha-olefin oligomer is varied over a significant range in a continuous, multi-stage alpha-olefin oligomerization process including a series of at least two flow-through tank reactors by controlling the amount of conversion taking place in each stage. The multi-stage process is used to prepare various poly(l-decene) oligomer mixtures having different oligomer proportions for use as synthetic lubricants.
摘要翻译： 在连续的多级α-烯烃低聚方法中，α-烯烃低聚物的三聚物与四聚体的比例在一个显着的范围内变化，包括一系列至少两个流通的罐式反应器，通过控制发生的转化量 每个阶段 多级方法用于制备具有不同低聚物比例的各种聚（1-癸烯）低聚物混合物，用作合成润滑剂。
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8.再颁专利Deactivating and removing aluminum and titanium contaminant from Ziegler-Natta polymerization mixtures 失效从齐格勒 - 纳塔聚合混合物中去除和去除铝和钛的污染物
公开(公告)号：USRE29004E
公开(公告)日：1976-10-12
申请号：US640248
申请日：1975-12-12
IPC分类号： C08F6/02
CPC分类号： C08F6/02
摘要： A polymerization reaction product comprising a solution of a poly(1-alkene) and a hydrocarbon polymerization solvent is purified of Ziegler-Natta aluminum and titanium containing catalyst residue by treating with flux-calcined diatomite to deactivate and insolubilize the aluminum and titanium and filtering out the insolubilized aluminum and titanium.
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公开(公告)号：US5994605A
公开(公告)日：1999-11-30
申请号：US759766
申请日：1996-12-03
申请人： Russell J. Bak , Barrett L. Cupples
发明人： Russell J. Bak , Barrett L. Cupples
CPC分类号： C10G50/02
摘要： A synthetic lubricant material is produced by forming a catalyst complex of a boron trifluoride catalyst and at least one alcohol promoter in the absence of olefinic monomer, then oligomerizing a C.sub.4-16 olefinic monomer by adding the olefinic monomer to a reaction vessel containing the catalyst complex, under boron trifluoride pressure, to produce an oligomer product. At least 50 weight % of the olefinic monomer is C.sub.8-16 olefinic monomer.
摘要翻译： 通过在不存在烯属单体的情况下形成三氟化硼催化剂和至少一种醇促进剂的催化剂络合物，然后通过将烯属单体加入到含有催化剂络合物的反应容器中来使C4-16烯烃单体低聚来制备合成润滑剂材料 在三氟化硼压力下，制备低聚物产物。 至少50重量％的烯烃单体是C8-16烯烃单体。
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公开(公告)号：US4282392A
公开(公告)日：1981-08-04
申请号：US916476
申请日：1978-06-19
IPC分类号： C07C2/22 , C10M107/10 , C07C9/14
CPC分类号： C10M3/00 , C10M107/10 , C10M2205/028 , C10N2230/08 , C10N2240/08 , C10N2240/12 , C10N2240/121
摘要： An alpha-olefin oligomer synthetic lubricant having an improved viscosity-volatility relationship is prepared from an alpha-olefin such as 1-decene.
摘要翻译： 由α-烯烃如1-癸烯制备具有改善的粘度 - 挥发性关系的α-烯烃低聚物合成润滑剂。
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