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公开(公告)号：US4084009A
公开(公告)日：1978-04-11
申请号：US774059
申请日：1977-03-03
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , A24B15/34 , C07C13/23 , C07C29/40 , C07C29/50 , C07C45/59 , C07D317/72 , C11B9/00 , A23L1/226
CPC分类号： A23G4/06 , A23L27/203 , A24B15/34 , C07C13/23 , C07C29/40 , C07C45/34 , C07C45/59 , C07D317/72 , C11B9/0034 , C07C2101/16
摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma, perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of hydroxy cyclohexenone derivatives having the generic formula: ##STR1## wherein one of X and Y is a keto moiety having the structure: ##STR2## and the other of X and Y is a carbinol moiety having the structure: ##STR3## and wherein R is C.sub.1 -C.sub.5 alkyl.
摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品风味和香气，烟草香料和香气，香料和香料制品香气增强，增强和赋予组合物以及作为食品，口香糖，牙膏，药用产品的方法和组合物， 烟草，香料和香料赋予的具有以下通式的羟基环己烯酮衍生物的芳香赋予材料：其中X和Y之一是具有以下结构的酮部分：X和Y是具有 结构：
，其中R是C 1 -C 5烷基。 -
2.发明授权4-Hydroxy-2,4,6,6-tetramethyl cyclohex-2-en-1-one perfume compositions 失效4-羟基-2,4,6,6-四甲基环己-2-烯-1-酮香料组合物
公开(公告)号：US4119574A
公开(公告)日：1978-10-10
申请号：US851681
申请日：1977-11-15
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , A24B15/34 , C07C13/23 , C07C29/40 , C07C29/50 , C07C45/59 , C07D317/72 , C11B9/00
CPC分类号： A23G4/06 , A23L27/203 , A24B15/34 , C07C13/23 , C07C29/40 , C07C45/34 , C07C45/59 , C07D317/72 , C11B9/0034 , C07C2101/16
摘要： Processes and compositions are described for the use in perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as perfume and perfumed article aroma imparting materials of hydroxy cyclohexenone derivatives having the generic formula: ##STR1## wherein one of X and Y is a keto moiety having the structure: ##STR2## and the other of X and Y is a carbinol moiety having the structure: ##STR3## wherein R is C.sub.1 -C.sub.5 alkyl. Addition of one or more hydroxy cyclohexenone derivatives having the formula: ##STR4## to consumable materials is indicated to produce: In perfumes, colognes and perfumed articles, green, minty, herbaceous, strong fruity aromas with earthy, mossy notes.
摘要翻译： 描述了用于香料和香料制品香气增强，增强和赋予组合物的方法和组合物，以及具有以下通式的羟基环己烯酮衍生物的香料和香料制品香气赋予材料：其中X和Y之一是酮 具有以下结构的部分：＆lt; IMAGE＆gt; X和Y中的另一个是具有以下结构的甲醇部分：其中R是C 1 -C 5烷基。
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公开(公告)号：US4076854A
公开(公告)日：1978-02-28
申请号：US774058
申请日：1977-03-03
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C11D3/50 , C11D9/44 , A23L1/226
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C11D3/50 , C11D9/442 , C07C2101/16
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl.
摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强，增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品，口香糖，牙膏，药用产品，烟草，香料和香料制品香气赋予材料：其中R是C 1 -C 5烷基之一，当R 2为R 1时，R 1为甲基 是氢，当R 2是甲基时，R 1是氢。
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公开(公告)号：US4041084A
公开(公告)日：1977-08-09
申请号：US683246
申请日：1976-05-05
CPC分类号： C07C45/62 , A24B15/345 , C07C45/63 , C07C45/69 , C11B9/0042
摘要： Tricyclic alcohol compounds having the formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond; and wherein, when the dashed line is a carbon-carbon single bond, one of R.sub.2 or R.sub.3 is hydrogen; useful in preparing compositions for augmenting or enhancing the flavor and/or aroma of consumble products including foods, tobacco and perfumes.
摘要翻译： 具有下式的三环醇化合物：其中R1，R2，R3，R4，R5和R6各自选自氢和甲基; 其中虚线是碳 - 碳单键或碳 - 碳双键; 并且其中，当虚线为碳 - 碳单键时，R 2或R 3中的一个为氢; 可用于制备用于增强或增强消费产品（包括食品，烟草和香料）的风味和/或香气的组合物。
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公开(公告)号：US4021494A
公开(公告)日：1977-05-03
申请号：US713428
申请日：1976-08-11
CPC分类号： C11B9/0042 , Y10S426/805
摘要： Described is a process for producing an organic tricyclic alcohol having the formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond; and wherein when the dashed line is a carbon-carbon single bond, one of R.sub.2 or R.sub.3 is hydrogen.
摘要翻译： 描述了一种制备具有下式的有机三环醇的方法：其中R 1，R 2，R 3，R 4，R 5和R 6各自选自氢和甲基; 其中虚线是碳 - 碳单键或碳 - 碳双键; 并且其中当虚线为碳 - 碳单键时，R 2或R 3中的一个为氢。
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公开(公告)号：US3996169A
公开(公告)日：1976-12-07
申请号：US614078
申请日：1975-09-17
CPC分类号： C11B9/0042 , A23L27/203 , A24B15/345 , C11B9/00 , C11D3/50 , C11D9/00
摘要： Processes and compositions for altering, modifying, enhancing (or imparting) the aroma of (or to) consumable products including colognes, perfumes and perfumed articles using as the essential ingredient at least one organic tricyclic alcohol having the formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1 is limited to hydrogen when (i) the dashed line is a carbon-carbon single bond; (ii) R.sub.2, R.sub.3, R.sub.4, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 is hydrogen and (iii) R.sub.5 is hydrogen or methyl and wherein when the dashed line is a carbon-carbon single bond, one of R.sub.3 or R.sub.4 is hydrogen.
摘要翻译： 用于使用至少一种具有下式的有机三环醇作为必需成分来改变，改进，增强（或赋予）消耗品的香味（包括古龙水，香水和香料）的方法和组合物，其中每种 R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10选自氢和甲基; 其中虚线是碳 - 碳单键或碳 - 碳双键; 其中当（i）虚线是碳 - 碳单键时，R1限制为氢; （ii）R 2，R 3，R 4，R 6，R 7，R 8，R 9和R 10是氢，（iii）R 5是氢或甲基，并且其中当虚线是碳 - 碳单键时，R 3或R 4中的一个是氢 。
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公开(公告)号：US3989760A
公开(公告)日：1976-11-02
申请号：US633800
申请日：1975-11-20
CPC分类号： C11B9/0042
摘要： Processes and compositions for altering the flavor and/or aroma of consumable products including foods, tobacco and perfumes utilizing as the essential ingredient the novel organic tricyclic alcohol having the formula: ##SPC1##And a process for preparing the above-mentioned compounds involving first intimately admixing a tetramethyl cyclohexadienone having the structure: ##SPC2##With 3-butenyl lithium having the structure: ##SPC3##Thereby forming a triene compound having the structure: ##SPC4##And then heating the triene compound at an elevated temperature and pressure thereby producing a metallo tricyclic compound having the structure: ##SPC5##Which is then hydrolyzed to form the tricyclic alcohol of this invention having the structure: ##SPC6##
摘要翻译： 用于改变消费品（包括食品，烟草和香料）的风味和/或芳香的方法和组合物，其利用具有下式的新型有机三环醇作为必需成分：
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8.发明授权Processes for producing cis alkyl-2-methyl-3-pentenoates and isomer mixtures containing high proportions of cis alkyl-2-methyl-3-pentenoates 失效顺式烷基-2-甲基-3-戊烯酸甲酯和含高比例顺式烷基-2-甲基-3-戊烯酸酯的异构体混合物的方法
公开(公告)号：US3931293A
公开(公告)日：1976-01-06
申请号：US490719
申请日：1974-07-22
摘要： Methods for producing cis-alkyl-2-methyl-3-pentenoates and isomeric mixtures containing high proportions (greater than 50%) of cis C.sub.2 -C.sub.6 alkyl-2-methyl-3-pentenoates.
摘要翻译： 顺式 - 烷基-2-甲基-3-戊烯酸酯和含有高比例（大于50％）顺式C 2 -C 6烷基-2-甲基-3-戊烯酸酯的异构体混合物的方法。
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公开(公告)号：US4201639A
公开(公告)日：1980-05-06
申请号：US8886
申请日：1979-02-02
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
CPC分类号： C07C13/23 , A24B15/34 , C11B9/0034 , C07C2101/16 , Y10S204/912
摘要： Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen comprising the step of reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene or a 1-alkyl-3,4,4-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product.
摘要翻译： 描述了制备具有以下通式的环己二烯衍生物的方法：其中R是C 1 -C 5烷基之一，当R 2为氢时R 1为甲基，包括使1-烷基-3,5,5-三甲基环己烷 1,3-二烯或1-烷基-3,4,4-三甲基环己-1,3-二烯与氧在光存在下，紫外线敏化剂和碱性催化剂; 并分馏蒸馏生成的产物。
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公开(公告)号：US4186149A
公开(公告)日：1980-01-29
申请号：US8779
申请日：1979-02-02
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C07C45/00
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C07C2101/16
摘要： Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## by means of reacting a compound having the structure: ##STR2## with mineral acid selected from the group consisting of dilute hydrochloric acid, dilute phosphoric acid and dilute sulfuric acid; wherein R is C.sub.1 -C.sub.5 alkyl. The products produced by this process are useful for their organoleptic properties in perfumes, foodstuffs and tobaccos.
摘要翻译： 描述了通过使具有以下结构的化合物与选自稀盐酸，稀磷酸和稀硫酸的无机酸反应制备具有以下通式的环己二烯衍生物的方法：＆lt; IMAGE＆gt; 其中R是C 1 -C 5烷基。 通过该方法生产的产品对于其在香料，食品和烟草中的感官特性是有用的。
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