公开(公告)号：US20060194065A1

公开(公告)日：2006-08-31

申请号：US11374421

申请日：2006-03-14

申请人： Kenneth Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt

发明人： Kenneth Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt

IPC分类号： B32B27/40

CPC分类号： C08G18/3218 ,  C08G18/4854 ,  C08G18/5012 ,  C08G18/5015 ,  C08G18/6674 ,  C08G18/833 ,  C08J3/005 ,  C08J2375/04 ,  C09D175/08 ,  C09D201/02 ,  Y10T428/31504 ,  Y10T428/31551 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

摘要： Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced. Advantageously, only a minimal amount (such as, e.g., about 2 weight %) of polymeric surface modifier is needed. Being able to achieve desired properties (such as biocidal activity, wettability modification, etc.) without needing much polymeric surface modifier is highly advantageous.

摘要翻译： 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。 有利地，仅需要最小量（例如约2重量％）的聚合物表面改性剂。 能够实现期望的性质（例如杀生物活性，润湿性改性等）而不需要很多聚合物表面改性剂是非常有利的。

公开(公告)号：US20060135729A1

公开(公告)日：2006-06-22

申请号：US11353689

申请日：2006-02-13

申请人： Aslam Malik ,  Thomas Archibald ,  Roland Carlson ,  Kenneth Wynne ,  Edward Kresge

发明人： Aslam Malik ,  Thomas Archibald ,  Roland Carlson ,  Kenneth Wynne ,  Edward Kresge

IPC分类号： C08G18/28 ,  C08G65/00 ,  C08L75/00

CPC分类号： C08G18/5015 ,  C08G65/18 ,  C08G65/226

摘要： This invention is directed to mono- and bis-substituted oxetane monomers having fluorinated alkoxymethylene side chains, hydroxy-terminated prepolymers derived from these mono- and bis-substituted oxetane monomers and tetrahydrofuran (THF), and polymers produced from these prepolymers, as well as the synthesis processes associated with each, and the use of the monomers, prepolymers and ultimate polymers, both directly and as components of numerous compositions.

公开(公告)号：US20050179170A1

公开(公告)日：2005-08-18

申请号：US11085154

申请日：2005-03-22

申请人： Kenneth Wynne ,  Younosuke Ohsaka ,  Suresh Shenoy ,  Sadashige Irie ,  Takako Ohsaka

发明人： Kenneth Wynne ,  Younosuke Ohsaka ,  Suresh Shenoy ,  Sadashige Irie ,  Takako Ohsaka

IPC分类号： B01J3/00 ,  C08F2/00 ,  C08J9/12 ,  C08K3/20 ,  H05B6/00

CPC分类号： C08J9/122 ,  B01J3/008 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2327/12 ,  C08K3/20 ,  Y02P20/544 ,  C08L27/12

摘要： Fluoropolymer materials containing tetrafluoroethylene monomers, such as PTFE, are significantly swollen by supercritical carbon dioxide at high temperatures and pressures. The swollen fluoropolymer is processable by molding, extrusion, and other techniques. In addition, the fluoropolymer may be sintered at significantly lower temperatures compared to a nonswollen fluoropolymer material. The melting temperature of fluorinated polymers containing tetrafluoroethylene and triflouroethylene monomers which are swollen with supercritical carbon dioxide is significantly reduced, thereby permitting manufacturing operations such as extruding and molding to be performed at lower temperatures and with reduced risk of decomposition.

公开(公告)号：US20050154217A1

公开(公告)日：2005-07-14

申请号：US10999362

申请日：2004-11-29

申请人： Aslam Malik ,  Thomas Archibald ,  Roland Carlson ,  Kenneth Wynne ,  Edward Kresge

发明人： Aslam Malik ,  Thomas Archibald ,  Roland Carlson ,  Kenneth Wynne ,  Edward Kresge

IPC分类号： C07D305/06 ,  C08G18/50 ,  C08G65/18 ,  C08G65/22 ,  C07D35/02

CPC分类号： C08G18/5015 ,  C08G65/18 ,  C08G65/226

摘要： This invention is directed to mono- and bis-substituted oxetane monomers having fluorinated alkoxymethylene side chains, hydroxy-terminated prepolymers derived from these mono- and bis-substituted oxetane monomers and tetrahydrofuran (THF), and polymers produced from these prepolymers, as well as the synthesis processes associated with each, and the use of the monomers, prepolymers and ultimate polymers, both directly and as components of numerous compositions.

摘要翻译： 本发明涉及具有氟化烷氧基亚甲基侧链的单取代和双取代的氧杂环丁烷单体，由这些单取代和双取代的氧杂环丁烷单体衍生的羟基封端的预聚物和四氢呋喃（THF），以及由这些预聚物制备的聚合物 与各自相关的合成方法，以及单体，预聚物和极性聚合物的使用，直接地和作为许多组合物的组分。

公开(公告)号：US20060154083A1

公开(公告)日：2006-07-13

申请号：US11290803

申请日：2005-12-01

申请人： Kenneth Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt ,  James Wynne

发明人： Kenneth Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt ,  James Wynne

IPC分类号： B32B27/40

CPC分类号： C08G18/3218 ,  C08G18/4854 ,  C08G18/5012 ,  C08G18/5015 ,  C08G18/6674 ,  C08G18/833 ,  C08J3/005 ,  C08J2375/04 ,  C09D175/08 ,  C09D201/02 ,  Y10T428/31504 ,  Y10T428/31551 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

摘要： Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced. Advantageously, only a minimal amount (such as, e.g., about 2 weight %) of polymeric surface modifier is needed. Being able to achieve desired properties (such as biocidal activity, wettability modification, etc.) without needing much polymeric surface modifier is highly advantageous.

公开(公告)号：US20060088716A1

公开(公告)日：2006-04-27

申请号：US11289422

申请日：2005-11-30

申请人： Kenneth Wynne

发明人： Kenneth Wynne

IPC分类号： B32B27/40

CPC分类号： C08J3/005 ,  C08G18/3218 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/833 ,  C08J2375/04 ,  C09D201/02 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/3158 ,  Y10T428/31583 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

摘要： Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced.

摘要翻译： 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物的表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。

公开(公告)号：US20050239951A1

公开(公告)日：2005-10-27

申请号：US11166169

申请日：2005-06-27

申请人： Kenneth Wynne ,  Younosuke Ohsaka ,  Takako Ohsaka ,  Suresh Shenoy ,  Sadashige Irie

发明人： Kenneth Wynne ,  Younosuke Ohsaka ,  Takako Ohsaka ,  Suresh Shenoy ,  Sadashige Irie

IPC分类号： B01J3/00 ,  C08F2/00 ,  C08J9/12 ,  C08K3/20

CPC分类号： C08J9/122 ,  B01J3/008 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2327/12 ,  C08K3/20 ,  Y02P20/544 ,  C08L27/12

摘要： Fluoropolymer materials containing tetrafluoroethylene monomers, such as PTFE, are significantly swollen by supercritical carbon dioxide at high temperatures and pressures. The swollen fluoropolymer is processable by molding, extrusion, and other techniques. In addition, the fluoropolymer may be sintered at significantly lower temperatures compared to a nonswollen fluoropolymer material. The melting temperature of fluorinated polymers containing tetrafluoroethylene and triflouroethylene monomers which are swollen with supercritical carbon dioxide is significantly reduced, thereby permitting manufacturing operations such as extruding and molding to be performed at lower temperatures and with reduced risk of decomposition.

公开(公告)号：US20050084683A1

公开(公告)日：2005-04-21

申请号：US10882238

申请日：2004-07-02

申请人： Kenneth Wynne

发明人： Kenneth Wynne

IPC分类号： B05D1/36 ,  B32B27/40 ,  C08L20060101

CPC分类号： C08J3/005 ,  C08G18/3218 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/833 ,  C08J2375/04 ,  C09D201/02 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/3158 ,  Y10T428/31583 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

摘要： Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced.

摘要翻译： 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物的表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。