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1.发明授权Lubricant antioxidant compositions containing a metal compound and a hindered amine 有权含有金属化合物和受阻胺的润滑剂抗氧化剂组合物公开(公告)号：US07875579B2
公开(公告)日：2011-01-25
申请号：US12041317
申请日：2008-03-03
IPC分类号： C10M141/10 , C10M163/00 , C10M137/10
CPC分类号： C10M133/02 , C10M133/40 , C10M135/36 , C10M159/18 , C10M2215/221 , C10M2215/222 , C10M2219/108 , C10M2227/09 , C10N2230/06 , C10N2230/10 , C10M2215/064 , C10N2210/06
摘要： An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.
摘要翻译： 一种抗氧化润滑剂组合物具有至少50重量％的润滑油基础油和油溶性金属化合物，该金属化合物为润滑剂组合物提供1至2,000ppm的金属，该金属化合物选自钼，钨 钛和硼化合物以及油溶性受阻胺，其向润滑剂组合物提供约0.001至约2重量％的油溶性受阻胺，以及任选地，提供0.001至约2重量％的油的油溶性二芳基胺 - 可溶性二芳基胺与润滑剂组合物。
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公开(公告)号：US07935663B2
公开(公告)日：2011-05-03
申请号：US12041130
申请日：2008-03-03
IPC分类号： C10M159/18
CPC分类号： C10M133/02 , C10M133/40 , C10M135/36 , C10M159/18 , C10M2215/221 , C10M2215/222 , C10M2219/108 , C10M2227/09 , C10N2230/06 , C10N2230/10 , C10M2215/064 , C10N2210/06
摘要： Novel molybdenum compounds are prepared by reacting a hindered amine with a molybdenum source, in the presence of one of (a) water, (b) a diol and water, and (c) the reaction product of a fatty oil and a multifunctional amine, and water. Lubricant compositions containing these new compounds are more stabilized against oxidation and have improved friction reducing properties. Synergy is observed when the novel compounds are combined with a diaryl amine in a lubricant composition.
摘要翻译： 在（a）水，（b）二醇和水之一的存在下，通过使受阻胺与钼源反应制备新的钼化合物，和（c）脂肪油和多官能胺的反应产物， 和水。 含有这些新化合物的润滑剂组合物更耐氧化稳定并具有改善的摩擦降低性能。 当新型化合物与润滑剂组合物中的二芳基胺组合时，观察到协同作用。
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3.发明授权Lubricant antioxidant compositions containing a metal compound and a hindered amine 有权含有金属化合物和受阻胺的润滑剂抗氧化剂组合物公开(公告)号：US08093190B2
公开(公告)日：2012-01-10
申请号：US12964850
申请日：2010-12-10
IPC分类号： C01G39/06 , C10M163/00 , C10M141/10 , C10M137/10
CPC分类号： C10M133/02 , C10M133/40 , C10M135/36 , C10M159/18 , C10M2215/221 , C10M2215/222 , C10M2219/108 , C10M2227/09 , C10N2230/06 , C10N2230/10 , C10M2215/064 , C10N2210/06
摘要： An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.
摘要翻译： 一种抗氧化润滑剂组合物具有至少50重量％的润滑油基础油和油溶性金属化合物，该金属化合物为润滑剂组合物提供1至2,000ppm的金属，该金属化合物选自钼，钨 钛和硼化合物以及油溶性受阻胺，其向润滑剂组合物提供约0.001至约2重量％的油溶性受阻胺，以及任选地，提供0.001至约2重量％的油的油溶性二芳基胺 - 可溶性二芳基胺与润滑剂组合物。
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4.发明授权Molybdenum dialkyldithiocarbamate compositions and lubricating compositions containing the same 有权二烷基二硫代氨基甲酸钼组合物和含有它们的润滑组合物公开(公告)号：US09012383B2
公开(公告)日：2015-04-21
申请号：US13425560
申请日：2012-03-21
IPC分类号： C10M135/18 , C07F11/00 , C10M139/00
CPC分类号： C10M135/18 , C07F11/005 , C10M139/00 , C10M2205/0285 , C10M2219/068 , C10M2227/066 , C10N2220/028 , C10N2230/70 , C10N2240/10 , C10N2270/00 , C10N2210/06
摘要： A novel molybdenum dithiocarbamate composition is produced by preparing a di-tridecylamine (DTDA) intermediate from a butylene feedstock comprising greater than 50% 2-butylene, and preparing a molybdenum dithiocarbamate composition from the DTDA intermediate. The resulting molybdenum dithiocarbamate composition are according to formula (1), wherein R1 to R4 are C11-C14 isoalkyl groups, and X represents oxygen and/or sulfur atoms, and R1 to R4 comprise, on average, greater than 98% C13:
摘要翻译： 通过从包含大于50％的2-丁烯的丁烯原料制备二十三胺（DTDA）中间体，并从DTDA中间体制备二硫代氨基甲酸钼组合物来制备新的二硫代氨基甲酸钼组合物。 所得的二硫代氨基甲酸钼组合物根据式（1），其中R 1至R 4为C 11 -C 14异烷基，X为氧和/或硫原子，且R 1至R 4平均包含大于98％的C 13：
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5.发明申请MOLYBDENUM DIALKYLDITHIOCARBAMATE COMPOSITIONS AND LUBRICATING COMPOSITIONS CONTAINING THE SAME 有权钼酸二烷基铝酸酯组合物和含有该组合物的润滑组合物公开(公告)号：US20120264666A1
公开(公告)日：2012-10-18
申请号：US13425560
申请日：2012-03-21
IPC分类号： C07F11/00 , C10M135/18
CPC分类号： C10M135/18 , C07F11/005 , C10M139/00 , C10M2205/0285 , C10M2219/068 , C10M2227/066 , C10N2220/028 , C10N2230/70 , C10N2240/10 , C10N2270/00 , C10N2210/06
摘要： A novel molybdenum dithiocarbamate composition is produced by preparing a di-tridecylamine (DTDA) intermediate from a butylene feedstock comprising greater than 50% 2-butylene, and preparing a molybdenum dithiocarbamate composition from the DTDA intermediate. The resulting molybdenum dithiocarbamate composition are according to formula (1), wherein R1 to R4 are C11-C14 isoalkyl groups, and X represents oxygen and/or sulfur atoms, and R1 to R4 comprise, on average, greater than 98% C13:
摘要翻译： 通过从包含大于50％的2-丁烯的丁烯原料制备二十三胺（DTDA）中间体，并从DTDA中间体制备二硫代氨基甲酸钼组合物来制备新的二硫代氨基甲酸钼组合物。 所得的二硫代氨基甲酸钼组合物根据式（1），其中R 1至R 4为C 11 -C 14异烷基，X为氧和/或硫原子，且R 1至R 4平均包含大于98％的C 13：
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公开(公告)号：US07589226B2
公开(公告)日：2009-09-15
申请号：US11255730
申请日：2005-10-21
申请人： Kevin J. Chase , Ronald Tepper
发明人： Kevin J. Chase , Ronald Tepper
IPC分类号： C07C333/04
CPC分类号： C10M159/12 , C07C333/20 , C07F5/025 , C07F5/04 , C10M139/00 , C10M141/12 , C10M169/06 , C10M2203/1006 , C10M2207/1285 , C10M2223/045 , C10M2227/061 , C10N2210/01 , C10N2230/06 , C10N2250/10
摘要： A novel hydroxyalkyldithiocarbamate borate ester compound is presented according to the formula: where R=alkyl C1 to C25; R′=H or CO2R; R″=(CH2)mOH where m=1 to 8, or alkyl C1 to C25; n=1 to 8. The borate ester compound is prepared by reacting boric acid with a novel hydroxyalkyldithiocarbamate ester compound according to the formula, and optionally with an alcohol: where R, R′, R″ and n are as above. The hydroxyalkyldithiocarbamate ester is prepared by reacting a hydroxyalkylamine with CS2, and an acrylate or maleate compound. A lubricating composition is based on a major amount of lubricating oil and a minor amount of the hydroxyalkyldithiocarbamate borate ester.
摘要翻译： 一种新型的羟基烷基二硫代氨基甲酸硼酸酯化合物呈现下式：其中R = C1-C25烷基; R'= H或CO 2 R; R“=（CH 2）m OH，其中m = 1至8，或烷基C1至C25; n = 1-8。硼酸酯化合物是通过使硼酸与下式的新的羟基烷基二硫代氨基甲酸酯化合物反应制备的，并且任选地与醇反应：其中R，R'，R“和n如上所述。 羟基烷基二硫代氨基甲酸酯酯是通过使羟烷基胺与CS2和丙烯酸酯或马来酸酯化合物反应来制备的。 润滑组合物基于大量的润滑油和少量的羟基烷基二硫代氨基甲酸硼酸酯酯。
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7.发明授权Process for producing highly sulfurized molybdenum oxysulfide dithiocarbamates 有权生产高度硫化的硫氧化二硫代二硫代氨基甲酸盐的方法公开(公告)号：US07524799B2
公开(公告)日：2009-04-28
申请号：US11297039
申请日：2005-12-08
申请人： Kevin J. Chase , Ronald J. Tepper
发明人： Kevin J. Chase , Ronald J. Tepper
IPC分类号： C10M135/18
CPC分类号： C10M135/18 , C10M2219/068 , C10N2210/06 , C10N2230/06 , C10N2230/10 , C10N2250/10
摘要： A processes for preparing highly sulfurized molybdenum oxysulfide dithiocarbamates (Mo DTCs) by reacting: [A] a tertiary amine, [B] a hexavalent molybdenum compound, [C] carbon disulfide, [D] water, and [E] a secondary amine are disclosed. The Mo DTCs can be efficiently produced with high sulfur contents and in high yields with low corrosive action and excellent friction properties. The produced Mo DTCs can be used in either grease or lubricating oils as friction modifiers, antiwear agents, extreme pressure agents and antioxidants.
摘要翻译： 通过使[A]叔胺，[B]六价钼化合物，[C]二硫化碳，[D]水和[E]仲胺反应制备高度硫化的硫氧化二硫代二硫代氨基甲酸酯（Mo DTC）的方法： 披露 Mo DTC可以高硫含量高效率生产，具有低腐蚀性和优异的摩擦性能。 生产的Mo DTC可用于润滑脂或润滑油中，作为摩擦改性剂，抗磨剂，极压剂和抗氧化剂。
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公开(公告)号：US07544644B2
公开(公告)日：2009-06-09
申请号：US11256341
申请日：2005-10-21
申请人： Kevin J. Chase , Ronald Tepper
发明人： Kevin J. Chase , Ronald Tepper
IPC分类号： C10M139/00 , C10M163/00 , C07F5/02
CPC分类号： C10M159/12 , C07C333/20 , C07F5/025 , C07F5/04 , C10M139/00 , C10M141/12 , C10M169/06 , C10M2203/1006 , C10M2207/1285 , C10M2223/045 , C10M2227/061 , C10N2210/01 , C10N2230/06 , C10N2250/10
摘要： A novel hydroxyalkyldithiocarbamate borate ester compound is presented according to the formula: where R=alkyl C1 to C25; R′=H or CO2R; R″=(CH2)mOH where m=1 to 8, or alkyl C1 to C25; n=1 to 8. The borate ester compound is prepared by reacting boric acid with a novel hydroxyalkyldithiocarbamate ester compound according to the formula, and optionally with an alcohol: where R, R′, R″ and n are as above. The hydroxyalkyldithiocarbamate ester is prepared by reacting a hydroxyalkylamine with CS2, and an acrylate or maleate compound. A lubricating composition is based on a major amount of lubricating oil and a minor amount of the hydroxyalkyldithiocarbamate borate ester.
摘要翻译： 一种新型的羟基烷基二硫代氨基甲酸硼酸酯化合物呈现下式：其中R = C1-C25烷基; R'= H或CO 2 R; R“=（CH 2）m OH，其中m = 1至8，或烷基C1至C25; n = 1-8。硼酸酯化合物是通过使硼酸与下式的新的羟基烷基二硫代氨基甲酸酯化合物反应制备的，并且任选地与醇反应：其中R，R'，R“和n如上所述。 羟基烷基二硫代氨基甲酸酯酯是通过使羟烷基胺与CS2和丙烯酸酯或马来酸酯化合物反应来制备的。 润滑组合物基于大量的润滑油和少量的羟基烷基二硫代氨基甲酸硼酸酯酯。
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公开(公告)号：US09228150B2
公开(公告)日：2016-01-05
申请号：US13437303
申请日：2012-04-02
IPC分类号： C10M135/18
CPC分类号： C10M135/18 , C10M2219/068 , C10N2210/02 , C10N2230/06 , C10N2230/10 , C10N2230/36 , C10N2240/102 , C10N2240/104
摘要： A lubricating oil composition comprising a zinc dithiocarbamate fraction, for use in a gasoline or diesel engine equipped with fluoroelastomer seals, wherein said zinc dithiocarbamate fraction consists essentially of zinc dithiocarbamate molecules per Formula I: having alkyl groups R1, R2, R3, and R4, wherein the weighted total average for carbon chain lengths for all molecules together is 9 or more:
摘要翻译： 一种润滑油组合物，其包含二硫代氨基甲酸锌馏分，用于配备有含氟弹性体密封件的汽油或柴油机，其中所述二硫代氨基甲酸锌馏分基本上由每个式I的二硫代氨基甲酸锌分子组成：具有烷基R1，R2，R3和R4， 其中所有分子的碳链长度的加权总平均值为9或更大：
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公开(公告)号：US20120258896A1
公开(公告)日：2012-10-11
申请号：US13437303
申请日：2012-04-02
IPC分类号： C10M135/18 , C07C333/20
CPC分类号： C10M135/18 , C10M2219/068 , C10N2210/02 , C10N2230/06 , C10N2230/10 , C10N2230/36 , C10N2240/102 , C10N2240/104
摘要： A lubricating oil composition comprising a zinc dithiocarbamate fraction, for use in a gasoline or diesel engine equipped with fluoroelastomer seals, wherein said zinc dithiocarbamate fraction consists essentially of zinc dithiocarbamate molecules per Formula I: having alkyl groups R1, R2, R3, and R4, wherein the weighted total average for carbon chain lengths for all molecules together is 9 or more:
摘要翻译： 一种润滑油组合物，其包含二硫代氨基甲酸锌馏分，用于配备有含氟弹性体密封件的汽油或柴油机，其中所述二硫代氨基甲酸锌馏分基本上由每个式I的二硫代氨基甲酸锌分子组成：具有烷基R1，R2，R3和R4， 其中所有分子的碳链长度的加权总平均值为9或更大：
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