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公开(公告)号:US06534569B2
公开(公告)日:2003-03-18
申请号:US09768492
申请日:2001-01-24
申请人: Khaled Mahmud , James A. Belmont , Yakov E. Kutsovsky , Wayne Devonport , Meng-Jiao Wang , Collin P. Galloway , Gregory J. Mehos
发明人: Khaled Mahmud , James A. Belmont , Yakov E. Kutsovsky , Wayne Devonport , Meng-Jiao Wang , Collin P. Galloway , Gregory J. Mehos
IPC分类号: C08K300
CPC分类号: C08J3/215
摘要: A variety of methods to prepare a polymer composition containing at least one polymer and at least one modified pigment are described. The methods, in part, involve introducing a slurry containing at least one modified pigment into an emulsion or solution polymer prior to dewatering. Other polymer systems can be used including aqueous based polymerizations and solvent-based polymerizations, which can include free radical polymerizations. Other methods involve the formation of a modified pigment in the presence of an emulsion or solution polymer and then recovering the polymer composition containing the modified pigment. Compositions containing at least one modified pigment and the emulsion or solution polymer are also described as well as uses for the polymer compositions of the present invention.
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公开(公告)号:US06448309B2
公开(公告)日:2002-09-10
申请号:US09813439
申请日:2001-03-21
IPC分类号: C08K324
CPC分类号: C08K5/5406 , C01P2002/88 , C01P2004/04 , C01P2006/12 , C01P2006/19 , C08K9/06 , C09C1/50 , C09C1/56 , C09C1/565 , C08L21/00
摘要: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance in the absence of a coupling agent, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
摘要翻译: 公开了包括弹性体和经硅处理的炭黑的弹性体化合物,并且任选地包括偶联剂。 弹性体组合物在不含偶联剂的情况下表现出较差的耐磨性,与含有未处理的炭黑的弹性体相比,在高温下具有较低的滞后和在低温下可比或增加的滞后。 考虑并公开了使用这种弹性体的各种弹性体和制剂。 还公开了掺入弹性体和氧化的,硅处理的炭黑的弹性体化合物。 还公开了制备与处理过的炭黑混合的弹性体的方法。
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公开(公告)号:US07199176B2
公开(公告)日:2007-04-03
申请号:US10192403
申请日:2002-07-10
IPC分类号: C08K3/04
CPC分类号: C08K5/5406 , C01P2002/88 , C01P2004/04 , C01P2006/12 , C01P2006/19 , C08K9/06 , C09C1/50 , C09C1/56 , C09C1/565 , C08L21/00
摘要: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance in the absence of a coupling agent, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
摘要翻译: 公开了包括弹性体和经硅处理的炭黑的弹性体化合物,并且任选地包括偶联剂。 弹性体组合物在不含偶联剂的情况下表现出较差的耐磨性,与含有未处理的炭黑的弹性体相比,在高温下具有较低的滞后和在低温下可比或增加的滞后。 考虑并公开了使用这种弹性体的各种弹性体和制剂。 还公开了掺入弹性体和氧化的,硅处理的炭黑的弹性体化合物。 还公开了制备与处理过的炭黑混合的弹性体的方法。
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公开(公告)号:US6028137A
公开(公告)日:2000-02-22
申请号:US750017
申请日:1997-08-14
IPC分类号: C08J3/22 , C08J3/20 , C08J5/00 , C08K3/04 , C08K3/34 , C08K5/54 , C08K9/06 , C08L21/00 , C08L101/00 , C09C1/48 , C09C1/50 , C09C1/56 , C08K3/00
CPC分类号: C08K5/5406 , C08K9/06 , C09C1/50 , C09C1/56 , C01P2002/88 , C01P2004/04 , C01P2006/12 , C01P2006/19
摘要: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance in the absence of a coupling agent, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
摘要翻译: PCT No.PCT / US96 / 07310 Sec。 371日期1997年8月14日 102(e)日期1997年8月14日PCT提交1996年5月21日PCT公布。 第WO96 / 37547号公报 日期1996年11月28日公开是弹性体化合物,包括弹性体和经硅处理的炭黑,并且任选地包括偶联剂。 弹性体组合物在不含偶联剂的情况下表现出较差的耐磨性,与含有未处理的炭黑的弹性体相比,在高温下具有较低的滞后和在低温下可比或增加的滞后。 考虑并公开了使用这种弹性体的各种弹性体和制剂。 还公开了掺入弹性体和氧化的,硅处理的炭黑的弹性体化合物。 还公开了制备与处理过的炭黑混合的弹性体的方法。
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公开(公告)号:US06323273B1
公开(公告)日:2001-11-27
申请号:US09392803
申请日:1999-09-09
IPC分类号: C08K300
CPC分类号: C08K5/5406 , C01P2002/88 , C01P2004/04 , C01P2006/12 , C01P2006/19 , C08K9/06 , C09C1/50 , C09C1/56 , C09C1/565 , C08L21/00
摘要: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance in the absence of a coupling agent, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
摘要翻译: 公开了包括弹性体和经硅处理的炭黑的弹性体化合物,并且任选地包括偶联剂。 弹性体组合物在不含偶联剂的情况下表现出较差的耐磨性,与含有未处理的炭黑的弹性体相比,在高温下具有较低的滞后和在低温下可比或增加的滞后。 考虑并公开了使用这种弹性体的各种弹性体和制剂。 还公开了掺入弹性体和氧化的,硅处理的炭黑的弹性体化合物。 还公开了制备与处理过的炭黑混合的弹性体的方法。
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公开(公告)号:US06197274B1
公开(公告)日:2001-03-06
申请号:US08937154
申请日:1997-09-25
IPC分类号: C01D300
CPC分类号: C09C3/063 , C01P2004/50 , C01P2004/61 , C01P2004/84 , C01P2006/21 , C08K3/04 , C08K9/02 , C09C1/56 , C09C3/006 , C09C3/08 , C09C3/12 , C08L21/00
摘要: Silica coated carbon blacks are disclosed and can be prepared by coating a fine dispersion of carbon black, such as a carbon black having an attached organic group(s). Compositions and articles of manufacture, including elastomeric compositions, containing such carbon black are also disclosed.
摘要翻译: 公开了二氧化硅涂覆的炭黑,并且可以通过涂布炭黑的细分散体(例如具有附着的有机基团的炭黑)来制备。 还公开了包含这种炭黑的组合物和制品,包括弹性体组合物。
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7.
公开(公告)号:US5916934A
公开(公告)日:1999-06-29
申请号:US750016
申请日:1997-02-25
IPC分类号: C08J3/22 , C08J5/00 , C08K9/00 , C08K9/02 , C08L21/00 , C08L101/00 , C09C1/48 , C09C1/56 , C08K9/04
CPC分类号: C09C1/56 , C07C323/09 , C08K9/02 , C01P2004/84
摘要: Disclosed are elastomeric compounds including an elastomer, a silica coated carbon black, and optionally including a coupling agent. Elastomeric compounds incorporating an elastomer and an oxidized, partially coated carbon black are also disclosed. Also disclosed are silica coated carbon black/elastomeric formulations using a variety of elastomers useful in a variety of product applications.
摘要翻译: PCT No.PCT / US96 / 07309 Sec。 371日期1997年2月25日 102(e)日期1997年2月25日PCT提交1996年5月21日PCT公布。 公开号WO96 / 37546 日期1996年11月28日公开是弹性体化合物,包括弹性体,二氧化硅涂覆的炭黑,并且任选地包括偶联剂。 还公开了包含弹性体和氧化的,部分涂覆的炭黑的弹性体化合物。 还公开了使用可用于各种产品应用的各种弹性体的二氧化硅涂覆的炭黑/弹性体制剂。
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8.
公开(公告)号:US5904762A
公开(公告)日:1999-05-18
申请号:US837493
申请日:1997-04-18
申请人: Khaled Mahmud , Meng-Jiao Wang
发明人: Khaled Mahmud , Meng-Jiao Wang
IPC分类号: C08K3/34 , C08K3/00 , C08K3/04 , C08K9/06 , C08L21/00 , C09C1/50 , C09C1/56 , C09C3/12 , C09C1/44
CPC分类号: C09C1/56 , C08K3/04 , C08K9/06 , C09C1/50 , C01P2004/50 , C01P2006/12
摘要: A method of making an aggregate comprising at least a carbon phase and a silicon-containing species phase is disclosed. The method involves introducing a first feedstock into a first stage of a multi-stage reactor, and introducing a second feedstock into the reactor at a location downstream of the first stage. The first and second feedstock comprise a carbon black-yielding feedstock, and at least one feedstock also comprises a silicon-containing compound. The reactor is operated at a sufficient temperature to decompose the silicon-containing compound and to pyrolize the carbon black-yielding feedstock. An additional method is disclosed which involves making an aggregate comprising a carbon phase and a silicon-containing species phase using multi-stage reactor having at least three stages for introducing a feedstock, wherein at least one of the feedstocks comprises a carbon black-yielding feedstock and wherein at least one of the feedstock comprises a silicon-containing compound. Besides producing the aggregate comprising a carbon phase and a silicon-containing species phase, silica and/or carbon black may also result from the processes of the present invention. A further method is disclosed which involves making an aggregate comprising a carbon phase and a metal-containing species phase using a multi-stage reactor having at least two stages for introducing feedstocks, wherein at least one of the feedstocks comprises a carbon black-yielding feedstock and where at least one of the feedstocks comprises a metal-containing compound. The aggregates of the present invention when incorporated into elastomeric compositions preferably lead to improved wet skid resistance properties.
摘要翻译: 公开了一种制备包含至少一个碳相和含硅物质相的聚集体的方法。 该方法包括将第一原料引入多级反应器的第一级,并且在第一级下游的位置将第二原料引入反应器。 第一和第二原料包括产生炭黑的原料,并且至少一种原料还包含含硅化合物。 反应器在足够的温度下运行以分解含硅化合物并且对产生炭黑的原料进行热解。 公开了一种额外的方法,其涉及使用具有至少三个阶段的多级反应器制备包含碳相和含硅物质相的聚集体,用于引入原料,其中至少一种原料包含产生炭黑的原料 并且其中所述原料中的至少一种包含含硅化合物。 除了生产包含碳相和含硅物质相的骨料外,二氧化硅和/或炭黑也可以由本发明的方法产生。 公开了一种另外的方法,其涉及使用具有至少两个阶段的多级反应器来制备包含碳相和含金属物质相的聚集体以引入原料,其中至少一种原料包含产生炭黑的原料 并且其中至少一种原料包含含金属的化合物。 当结合到弹性体组合物中时,本发明的聚集体优选地导致改进的抗湿滑性能。
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公开(公告)号:US5830930A
公开(公告)日:1998-11-03
申请号:US446141
申请日:1995-05-22
申请人: Khaled Mahmud , Meng-Jiao Wang , Robert A. Francis
发明人: Khaled Mahmud , Meng-Jiao Wang , Robert A. Francis
CPC分类号: C09C1/56 , C08K9/06 , C09C1/50 , C01P2004/04 , C01P2006/19
摘要: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
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10.
公开(公告)号:US06709506B2
公开(公告)日:2004-03-23
申请号:US09975699
申请日:2001-10-11
申请人: Khaled Mahmud , Meng-Jiao Wang , Yakov Kutsovsky
发明人: Khaled Mahmud , Meng-Jiao Wang , Yakov Kutsovsky
IPC分类号: C08K902
CPC分类号: C09C1/56 , C01P2004/50 , C01P2006/12 , C08K3/04 , C08K9/06 , C09C1/50 , Y02T10/862 , C08L21/00
摘要: An aggregate including a carbon phase and a silicon-containing species phase is described, wherein a difference between BET (N2) surface area and t-area of the aggregate is from about 2 to 10 m2/g; a difference between BET (N2) surface area and t-area of from about 1 to 50 m2/after HF treatment; a ratio of from about 0.1 to 10; a weight average aggregate size measured by DCP after HF treatment that is reduced by about 5% to 40%; a silica ash content in the aggregate of from about 0.05% to 1% based on the weight of the aggregate after HF treatment and based on ash resulting from silicon-containing compound; and a BET surface area of silica ash in the aggregate of from about 200 m2/g to 700 m2/g, wherein the silicon-containing species phase is present primarily at the surface of the aggregate.
摘要翻译: 描述了包含碳相和含硅物质相的聚集体,其中BET(N2)表面积和聚集体的t面积之间的差为约2至10m 2 / g; HF处理后的BET(N2)表面积和t-面积之间的差异为约1〜50m 2 / 约0.1至10的比率; 通过HF处理后的DCP测量的重量平均聚集体尺寸减少约5%至40%; 基于HF处理后的骨料的重量和基于由含硅化合物产生的灰分,总灰分中的二氧化硅灰分含量为约0.05%至1% 和聚集体中二氧化硅灰分的BET表面积为约200m 2 / g至700m 2 / g,其中含硅物质相主要存在于聚集体的表面。
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