公开(公告)号：US6110994A

公开(公告)日：2000-08-29

申请号：US990715

申请日：1997-12-15

Applicant: Joel M. Cooke ,  Collin P. Galloway ,  Mark A. Bissell ,  Curtis E. Adams ,  Michael C. Yu ,  James A. Belmont ,  Robert M. Amici

Inventor： Joel M. Cooke ,  Collin P. Galloway ,  Mark A. Bissell ,  Curtis E. Adams ,  Michael C. Yu ,  James A. Belmont ,  Robert M. Amici

IPC: C09C1/48 ,  C08K9/04 ,  C08L101/00 ,  C09C1/56 ,  C09C3/08 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09D17/00 ,  C08K9/00

CPC classification number: C09C1/48 ,  C08K9/04 ,  C09C1/56 ,  C09C3/08 ,  C09D11/037 ,  C09D11/324 ,  C09D11/36 ,  C09D17/005 ,  C09D7/1225 ,  C01P2006/22 ,  C08K3/04

Abstract: Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: --Ar--CO.sub.2 --R or --(--C.sub.n H.sub.2n --)--CO.sub.2 --R, where R is an organic group, monomeric group, or a polymeric group. The third type of modified carbon product contains a) a carbon product having attached at least one organic group directly attached to the carbon product, b) at least one ionic group, ionizable group, or a mixture thereof attached to the organic group, and c) at least one counter-ionic group or counter-ionizable group with at least one organic group, monomeric group, or polymeric group, or mixture thereof, where the counter-ionic or counter-ionizable group is attached to the ionic and/or ionizable group. A method of improving the dispersion of carbon products in polymers is also disclosed which involves dispersing the modified carbon products described above in a polymer to form a polymeric product.

Abstract translation: 公开了可形成含有改性碳产物和聚合物的聚合产物的一部分的各种改性碳产品。 公开的一种类型的改性碳产物是连接有至少一个有机基团，单体基团或聚合物基团的碳产物。 公开的另一种类型的改性碳产物是具有下式的碳产物：-Ar-CO 2 -R或 - （ - C n H 2n - ） - CO 2 -R，其中R是有机基团，单体基团或聚合物 组。 第三种类型的改性碳产物包含a）具有连接至少一个与碳产物连接的有机基团的碳产物，b）连接到有机基团上的至少一个离子基团，可离子化基团或其混合物，c ）至少一种具有至少一个有机基团，单体基团或聚合物基团或其混合物的反离子基团或可逆离子基团，其中所述反离子或可逆离子基团连接到离子和/或可离子化的基团 组。 还公开了一种改进聚合物中碳产物分散的方法，其中包括将上述改性碳产物分散在聚合物中以形成聚合物。

公开(公告)号：US6042643A

公开(公告)日：2000-03-28

申请号：US105007

申请日：1998-06-26

Applicant: James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

Inventor： James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

IPC: C01B20060101 ,  C08K9/04 ,  C08L21/00 ,  C09B39/00 ,  C09C1/56 ,  C09C1/58 ,  C09C3/08 ,  C09D5/02 ,  C09D7/00 ,  C09D11/00 ,  C09D11/02 ,  C09D11/18 ,  D01F1/04 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  D21H21/28 ,  C09C1/48 ,  C08K3/04

CPC classification number: C04B35/63 ,  C08K9/04 ,  C09B39/00 ,  C09C1/56 ,  C09C1/565 ,  C09C1/58 ,  C09C3/08 ,  C09D11/037 ,  C09D11/18 ,  C09D11/324 ,  C09D5/028 ,  C09D7/007 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/19 ,  C04B2235/424 ,  C04B2235/425 ,  D21H21/285 ,  Y10S524/925

Abstract: Processes for preparing a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.

公开(公告)号：US07501091B2

公开(公告)日：2009-03-10

申请号：US09752656

申请日：2000-12-29

Applicant: Beth C. Munoz ,  Kenneth J. Pierce ,  Collin P. Galloway

Inventor： Beth C. Munoz ,  Kenneth J. Pierce ,  Collin P. Galloway

IPC: C12Q1/68 ,  G01N15/06 ,  G01N27/00

CPC classification number: G01N27/126 ,  G01N33/0031 ,  G01N2291/02863 ,  Y10T436/11

Abstract: A sensor or a sensor array connected to an electrical measuring apparatus is disclosed. In one embodiment, at least one sensor contains a layer of conductive modified particles which forms an electrical pathway or electrical circuit between two electrodes which are connected to an electrical measuring apparatus. In another embodiment, the first sensor contains at least one region of a nonconducting material and also a region that contains one or more modified particles. The modified particles are preferably conductive. An electrical path exists though the regions of the nonconducting material and the region containing the modified particles. The modified particles are conductive and more preferably are pigment particles such as modified carbon black, wherein the modified particles have attached at least one organic group. Alternatively, or in addition, the modified particle can be an aggregate having a carbon phase and a silicon-containing species phase and/or a metal-containing species phase wherein the aggregate optionally has attached at least one organic group. A sensor array for detecting an analyte in a fluid is also disclosed wherein each sensor emits a different response signature to an analyte wherein at least one of the sensors contains at least the modified particles as described above. Also, the present invention relates to a method for detecting the presence of an analyte in a fluid. The method involves contacting one or more sensors as described above with the analyte to generate a response and detecting the response with a detector that is operatively associated with each sensor in order to detect the presence of an analyte. Other advantages and embodiments are further described.

Abstract translation: 公开了一种连接到电测量装置的传感器或传感器阵列。 在一个实施例中，至少一个传感器包含导电改性颗粒层，其形成连接到电测量设备的两个电极之间的电路或电路。 在另一个实施方案中，第一传感器包含至少一个不导电材料的区域以及含有一个或多个改性颗粒的区域。 改性颗粒优选是导电的。 通过不导电材料的区域和含有改性颗粒的区域存在电路径。 改性粒子是导电性的，更优选为改性炭黑等颜料粒子，其中，改性粒子具有至少一个有机基团。 或者或另外，改性颗粒可以是具有碳相和含硅物质相和/或含金属物质相的骨料，其中所述骨料任选地具有至少一个有机基团。 还公开了一种用于检测流体中的分析物的传感器阵列，其中每个传感器向分析物发射不同的响应特征，其中至少一个传感器至少包含如上所述的改性颗粒。 此外，本发明还涉及用于检测流体中分析物的存在的方法。 该方法包括将如上所述的一个或多个传感器与分析物接触以产生响应，并用与每个传感器可操作地相关联的检测器检测响应，以便检测分析物的存在。 进一步描述其它优点和实施例。

公开(公告)号：US07294185B2

公开(公告)日：2007-11-13

申请号：US10806080

申请日：2004-03-22

Applicant: James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

Inventor： James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

IPC: C09D11/00

CPC classification number: C04B35/63 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/19 ,  C04B2235/424 ,  C04B2235/425 ,  C08K9/04 ,  C09B39/00 ,  C09C1/56 ,  C09C1/565 ,  C09C1/58 ,  C09C3/08 ,  C09D5/028 ,  C09D7/41 ,  C09D11/037 ,  C09D11/18 ,  C09D11/324 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  D21H21/285 ,  Y10S524/925 ,  C08L21/00

Abstract: Processes for preparing a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.

Abstract translation: 制备具有连接到炭黑上的有机基团的炭黑产品的方法。 在一个方法中，至少一种重氮盐在不存在足以减少重氮盐的外部施加电流的情况下与炭黑反应。 在另一方法中，至少一种重氮盐与质子反应介质中的炭黑反应。 对本发明方法制备的炭黑产品以及在塑料组合物，橡胶组合物，纸组合物和纺织品组合物中的这种炭黑产品的用途进行了描述。

公开(公告)号：US07056962B2

公开(公告)日：2006-06-06

申请号：US09752227

申请日：2000-12-29

Applicant: Joseph E. Johnson ,  Nanying Bian ,  Collin P. Galloway

Inventor： Joseph E. Johnson ,  Nanying Bian ,  Collin P. Galloway

IPC: C08K9/00 ,  C08K9/04 ,  C09D11/10 ,  B32B27/00

CPC classification number: G03F7/202 ,  B41C1/10 ,  B41C1/1033 ,  C01P2002/60 ,  C01P2004/60 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/21 ,  C01P2006/60 ,  C09B67/0004 ,  C09B67/0013 ,  C09B67/0033 ,  C09B67/0089 ,  C09B67/009 ,  C09B68/24 ,  C09B68/26 ,  C09B68/4257 ,  C09B68/443 ,  C09B68/446 ,  C09B68/4475 ,  C09B69/00 ,  C09C1/44 ,  C09C1/50 ,  C09C1/52 ,  C09C1/56 ,  C09C3/08 ,  C09C3/10 ,  C09D5/028 ,  C09D11/037 ,  C09D11/32 ,  C09D11/322 ,  C09D11/34 ,  C09D11/36 ,  Y10T428/2998

Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula: —X—[NIon]pR wherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer of from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group. In addition, other types of modified pigment products are described as well as their incorporation into inks, coatings, toners, films, plastics, polymers, elastomers, and the like. Methods of making the modified pigment products are also described.

Abstract translation: 描述了各种改性颜料产品，其优选能够分散在各种材料如涂料，油墨，调色剂，薄膜，塑料，聚合物，弹性体等中。 改性颜料是具有附着基团的颜料，例如聚合物基团，除了吸附之外，还可以通过其它方式。 描述了一种改性颜料产品，其包含具有至少一个基团的颜料，所述颜料具有下式：<？in-line-formula description =“In-Line Formulas”end =“lead”→X- 其中X包括芳族基团或烷基，NIon包括至少一种非离子基团（例如， R表示氢或包含芳基或烷基，p表示1至500的整数。还描述了包含连接有至少一个环氧烷基或至少一个聚合基团的颜料的改性颜料产品。 此外，还描述了其它类型的改性颜料产品以及它们掺入油墨，涂料，调色剂，薄膜，塑料，聚合物，弹性体等中。 还描述了制备改性颜料产品的方法。

公开(公告)号：US06534569B2

公开(公告)日：2003-03-18

申请号：US09768492

申请日：2001-01-24

Applicant: Khaled Mahmud ,  James A. Belmont ,  Yakov E. Kutsovsky ,  Wayne Devonport ,  Meng-Jiao Wang ,  Collin P. Galloway ,  Gregory J. Mehos

Inventor： Khaled Mahmud ,  James A. Belmont ,  Yakov E. Kutsovsky ,  Wayne Devonport ,  Meng-Jiao Wang ,  Collin P. Galloway ,  Gregory J. Mehos

IPC: C08K300

CPC classification number: C08J3/215

Abstract: A variety of methods to prepare a polymer composition containing at least one polymer and at least one modified pigment are described. The methods, in part, involve introducing a slurry containing at least one modified pigment into an emulsion or solution polymer prior to dewatering. Other polymer systems can be used including aqueous based polymerizations and solvent-based polymerizations, which can include free radical polymerizations. Other methods involve the formation of a modified pigment in the presence of an emulsion or solution polymer and then recovering the polymer composition containing the modified pigment. Compositions containing at least one modified pigment and the emulsion or solution polymer are also described as well as uses for the polymer compositions of the present invention.

公开(公告)号：US06494946B1

公开(公告)日：2002-12-17

申请号：US09257237

申请日：1999-02-25

Applicant: James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

Inventor： James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

IPC: C09C144

CPC classification number: C04B35/63 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/19 ,  C04B2235/424 ,  C04B2235/425 ,  C08K9/04 ,  C09B39/00 ,  C09C1/56 ,  C09C1/565 ,  C09C1/58 ,  C09C3/08 ,  C09D5/028 ,  C09D7/41 ,  C09D11/037 ,  C09D11/18 ,  C09D11/324 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  D21H21/285 ,  Y10S524/925 ,  C08L21/00

Abstract: Processes for preparing a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.

Abstract translation: 制备具有连接到炭黑上的有机基团的炭黑产品的方法。 在一个方法中，至少一种重氮盐在不存在足以减少重氮盐的外部施加电流的情况下与炭黑反应。 在另一方法中，至少一种重氮盐与质子反应介质中的炭黑反应。 对本发明方法制备的炭黑产品以及在塑料组合物，橡胶组合物，纸组合物和纺织品组合物中的这种炭黑产品的用途进行了描述。

公开(公告)号：US5851280A

公开(公告)日：1998-12-22

申请号：US572525

申请日：1995-12-14

Applicant: James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

Inventor： James A. Belmont ,  Robert M. Amici ,  Collin P. Galloway

IPC: C01B20060101 ,  C08K9/04 ,  C08L21/00 ,  C09B39/00 ,  C09C1/56 ,  C09C1/58 ,  C09C3/08 ,  C09D5/02 ,  C09D7/00 ,  C09D11/00 ,  C09D11/02 ,  C09D11/18 ,  D01F1/04 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  D21H21/28

CPC classification number: C04B35/63 ,  C08K9/04 ,  C09B39/00 ,  C09C1/56 ,  C09C1/565 ,  C09C1/58 ,  C09C3/08 ,  C09D11/037 ,  C09D11/18 ,  C09D11/324 ,  C09D5/028 ,  C09D7/007 ,  D01F11/14 ,  D06M11/74 ,  D06P1/44 ,  D21H17/69 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/19 ,  C04B2235/424 ,  C04B2235/425 ,  D21H21/285 ,  Y10S524/925

Abstract: Processes for preparing a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.

公开(公告)号：US07649031B2

公开(公告)日：2010-01-19

申请号：US11406218

申请日：2006-04-18

Applicant: Joseph E. Johnson ,  Nanying Bian ,  Collin P. Galloway

Inventor： Joseph E. Johnson ,  Nanying Bian ,  Collin P. Galloway

IPC: C08K9/00

CPC classification number: G03F7/202 ,  B41C1/10 ,  B41C1/1033 ,  C01P2002/60 ,  C01P2004/60 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/21 ,  C01P2006/60 ,  C09B67/0004 ,  C09B67/0013 ,  C09B67/0033 ,  C09B67/0089 ,  C09B67/009 ,  C09B68/24 ,  C09B68/26 ,  C09B68/4257 ,  C09B68/443 ,  C09B68/446 ,  C09B68/4475 ,  C09B69/00 ,  C09C1/44 ,  C09C1/50 ,  C09C1/52 ,  C09C1/56 ,  C09C3/08 ,  C09C3/10 ,  C09D5/028 ,  C09D11/037 ,  C09D11/32 ,  C09D11/322 ,  C09D11/34 ,  C09D11/36 ,  Y10T428/2998

Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula: —X-[NIon]pR wherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer of from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group. In addition, other types of modified pigment products are described as well as their incorporation into inks, coatings, toners, films, plastics, polymers, elastomers, and the like. Methods of making the modified pigment products are also described.

Abstract translation: 描述了各种改性颜料产品，其优选能够分散在各种材料如涂料，油墨，调色剂，薄膜，塑料，聚合物，弹性体等中。 改性颜料是具有附着基团的颜料，例如聚合物基团，除了吸附之外，还可以通过其它方式。 描述了一种改性颜料产品，其包含连接至少一个包含下式的基团的颜料：-X- [NIon] pR其中X包含芳族基团或烷基，NIon包含至少一种非离子基团R 表示氢或包含芳族基团或烷基，p表示1〜500的整数。还描述了包含具有至少一个环氧烷基团或至少一个聚合物基团的颜料的改性颜料产品。 此外，还描述了其它类型的改性颜料产品以及它们掺入油墨，涂料，调色剂，薄膜，塑料，聚合物，弹性体等中。 还描述了制备改性颜料产品的方法。

公开(公告)号：US06822781B1

公开(公告)日：2004-11-23

申请号：US09694855

申请日：2000-10-24

Applicant: Robert M. Amici ,  Dennis M. Dalton ,  Collin P. Galloway

Inventor： Robert M. Amici ,  Dennis M. Dalton ,  Collin P. Galloway

IPC: G09G308

CPC classification number: G02B26/026 ,  G09F9/372

Abstract: A gyricon display containing modified particles is disclosed. The gyricon display has an arrangement of bichromal or polychromal elements which are disposed between a first and second electrode. One of the electrodes is substantially visually transparent. The display also has means for creating a potential difference between the two electrodes. Also, each bichromal element has two hemispheres, wherein one of the hemispheres has at least a surface containing at least one modified colored pigment having attached at least one organic group and the other hemisphere has at least a surface with a different color and different electrical property. The organic group preferably includes at least one ionic, ionizable group, or both. Each bichromal or polychromal element is enclosed within a shell wherein a liquid is present between the shell and the element so that the element is free to rotate in response. Methods of making the gyricon display are also disclosed.

Abstract translation: 公开了包含改性颗粒的陀螺仪显示器。 陀螺仪显示器具有布置在第一和第二电极之间的双色或多色元件的布置。 其中一个电极基本上是视觉上透明的。 显示器还具有用于在两个电极之间产生电位差的装置。 此外，每个双色元件具有两个半球，其中一个半球具有至少一个含有至少一个附着至少一个有机基团的改性着色颜料的表面，另一个半球具有至少一个具有不同颜色和不同电性能的表面 。 有机基团优选包括至少一个离子，可离子化基团或两者。 每个双色或多色元件被封装在壳体内，其中在壳体和元件之间存在液体，使得元件响应地自由旋转。 还公开了制作陀飞轮显示器的方法。