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    Production of bisphenol monoester
    1.
    发明授权
    Production of bisphenol monoester 失效
    双酚A单体的生产

    公开(公告)号：US5214193A

    公开(公告)日：1993-05-25

    申请号：US834373

    申请日：1992-02-12

    申请人： Kikumitsu Inoue ,  Manji Sasaki ,  Kazuaki Yamamoto ,  Shinichi Yachigo

    发明人： Kikumitsu Inoue ,  Manji Sasaki ,  Kazuaki Yamamoto ,  Shinichi Yachigo

    IPC分类号： C07C37/20 ,  C07C67/52 ,  C07C69/017 ,  C07C69/54 ,  C07C69/773

    CPC分类号： C07C69/54 ,  C07C37/20 ,  C07C67/08 ,  C07C67/52 ,  C07C69/017

    摘要： A bisphenol monoester represented by the formula (I): ##STR1## wherein R.sup.1 is hydrogen or alkyl, R.sup.2 and R.sup.3 are each alkyl, and R.sup.4 is alkyl, alkenyl or phenyl, is produced by continuous two step reactions in which an aldehyde R.sup.1 -CHO and 2,4-dialkylphenol are subjected to a condensation reaction in a C.sub.6 -C.sub.10 aliphatic or C.sub.6 -C.sub.12 aromatic hydrocarbon solvent, and then a resulting bisphenol compound dissolved in the solvent is subjected to an esterification with a carboxylic acid R.sup.4 --COOH or its derivative. Prior to the esterification, the organic layer containing the bisphenol compound is subjected to a dehydration treatment, thereby enabling the two steps to proceed continuously without isolating the intermediate bisphenol compound. A purification process for the bisphenol monoester of the formula (I) is also disclosed in which the monoester is purified from a mixed solvent comprising a C.sub.6 -C.sub.12 aromatic hydrocarbon solvent and a C.sub.1 -C.sub.8 alcohol or C.sub.2 -C.sub.3 aliphatic nitrile solvent.

    Butadiene polymer composition containing phenolic compound and phosphorus-containing compound
    2.
    发明授权
    Butadiene polymer composition containing phenolic compound and phosphorus-containing compound 失效
    丁二烯聚合物组合物含有酚类化合物和含磷化合物

    公开(公告)号：US5045581A

    公开(公告)日：1991-09-03

    申请号：US287287

    申请日：1988-12-21

    申请人： Takeshi Takata ,  Shinichi Yachigo ,  Manji Sasaki ,  Kikumitsu Inoue ,  Shinya Tanaka

    发明人： Takeshi Takata ,  Shinichi Yachigo ,  Manji Sasaki ,  Kikumitsu Inoue ,  Shinya Tanaka

    IPC分类号： C08K5/13 ,  C08K5/134 ,  C08K5/49 ,  C08K5/52 ,  C08K5/526 ,  C08L9/00 ,  C08L53/00 ,  C08L53/02

    CPC分类号： C08K5/134 ,  C08K5/526

    摘要： A butadiene polymer composition containing a phenolic compound represented by the formula: ##STR1## wherein R.sub.1 is an alkyl having 1 to 4 carbon atoms, R.sub.2 and R.sub.3 are each independently a group represented by --C(CH.sub.3).sub.2 --R' in which R' is an alkyl having 1 to 5 carbon atoms or phenyl, and R.sub.4 is hydrogen or methyl, and a phosphorus-containing compound represented by the formula: ##STR2## wherein R.sub.5 and R.sub.6 are each independently an alkyl having 1 to 9 carbon atoms.The composition is stable against the thermal deterioration and discoloration in the absence of oxygen as well as against the exposure to oxides of nitrogen gas.

    摘要翻译： 一种丁二烯聚合物组合物，其含有由下式表示的酚类化合物：其中R 1是具有1至4个碳原子的烷基，R 2和R 3各自独立地是由-C（CH 3）2 -R'表示的基团，其中R '是具有1至5个碳原子的烷基或苯基，R4是氢或甲基，以及由下式表示的含磷化合物：其中R 5和R 6各自独立地为具有1至9个碳原子的烷基。 该组合物对于在不存在氧气的情况下的热劣化和变色以及暴露于氮气的氧化物是稳定的。

    Hydroxyphenylpropionic ester having novel crystal structure
    4.
    发明授权
    Hydroxyphenylpropionic ester having novel crystal structure 失效
    具有新晶体结构的羟基苯丙酸酯

    公开(公告)号：US5338869A

    公开(公告)日：1994-08-16

    申请号：US87866

    申请日：1993-07-09

    申请人： Kikumitsu Inoue ,  Manji Sasaki ,  Shinichi Yachigo

    发明人： Kikumitsu Inoue ,  Manji Sasaki ,  Shinichi Yachigo

    IPC分类号： C07D493/10 ,  G01N23/20 ,  C07D319/06

    CPC分类号： C07D493/10

    摘要： A hydroxyphenylpropionic ester represented by the formula of ##STR1## which has a crystal structure showing a sharp X-ray diffraction peak at a diffraction angle 2.theta.=7.9.degree. by X-ray diffraction measurement using an X-ray of a Cu-K.sub..alpha. wavelength. This novel crystal exhibits largely advantageous effects in industrial production and usage of the ester because of its high purity, high quality, excellent filterability owing to the large crystal growth, and excellent fluidity owing to the large bulk specific gravity.

    摘要翻译： 由下式表示的羟基苯基丙酸酯，其具有通过X射线衍射测定在衍射角2θ= 7.9°处显示出尖锐X射线衍射峰的晶体结构，使用X射线 Cu-Kα波长。 由于其高纯度，高质量，由于大的晶体生长而具有优异的过滤性，并且由于体积比重大而具有优异的流动性，因此该新颖的晶体在工业生产和酯的使用方面具有很大的有益效果。

    Hydroquinone type compound and its use as stabilizer for synthetic resin
    5.
    发明授权
    Hydroquinone type compound and its use as stabilizer for synthetic resin 失效
    对苯二酚类化合物及其作为合成树脂的稳定剂

    公开(公告)号：US4939196A

    公开(公告)日：1990-07-03

    申请号：US291965

    申请日：1988-12-30

    申请人： Manji Sasaki ,  Shinichi Yachigo ,  Kikumitsu Inoue ,  Shinya Tanaka ,  Fumitoshi Kojima ,  Takeshi Takata

    发明人： Manji Sasaki ,  Shinichi Yachigo ,  Kikumitsu Inoue ,  Shinya Tanaka ,  Fumitoshi Kojima ,  Takeshi Takata

    IPC分类号： C07C69/54 ,  C07C65/28 ,  C08K5/10 ,  C08K5/13 ,  C08L9/00

    CPC分类号： C07C65/28 ,  C08K5/10

    摘要： A compound represented by the formula of ##STR1## wherein R.sub.1 represents an alkyl having 1 to 5 carbon atoms;R.sub.2 represents an alkyl having 1 to 18 carbon atoms, an alkenyl having 2 to 5 carbon atoms, an aralkyl having 7 to 9 carbon atoms, phenyl, an aliphatic acyl having 2 to 5 carbon atoms, or benzoyl;R.sub.3 represents hydrogen or an alkyl having 1 to 11 carbon atoms; andR.sub.4 represents hydrogen or methyl.The compound is useful as a stabilizer for synthetic resins such as butadiene polymers. The butadiene polymer containing the compound is stable against thermal deterioration in the absence of oxygen, as well as against thermal oxidative deeterioration and thermal oxidative discoloration.

    摘要翻译： 由下式表示的化合物：其中R 1表示具有1至5个碳原子的烷基; R 2表示碳原子数1〜18的烷基，碳原子数2〜5的烯基，碳原子数7〜9的芳烷基，苯基，碳原子数2〜5的脂肪族酰基或苯甲酰基。 R3代表氢或具有1至11个碳原子的烷基; R4表示氢或甲基。 该化合物可用作合成树脂如丁二烯聚合物的稳定剂。 含有该化合物的丁二烯聚合物对于不存在氧的热劣化以及热氧化脱臭和热氧化变色是稳定的。

    Butadiene polymer composition contains phenolic compound and sulfur-containing compound
    6.
    发明授权
    Butadiene polymer composition contains phenolic compound and sulfur-containing compound 失效
    丁二烯聚合物组合物含有酚类化合物和含硫化合物

    公开(公告)号：US5047461A

    公开(公告)日：1991-09-10

    申请号：US288992

    申请日：1988-12-23

    申请人： Takeshi Takata ,  Shinichi Yachigo ,  Manji Sasaki ,  Kikumitsu Inoue ,  Shinya Tanaka

    发明人： Takeshi Takata ,  Shinichi Yachigo ,  Manji Sasaki ,  Kikumitsu Inoue ,  Shinya Tanaka

    IPC分类号： C08K5/13 ,  C08K5/134 ,  C08K5/36 ,  C08K5/372 ,  C08L9/00 ,  C08L53/00 ,  C08L53/02

    CPC分类号： C08K5/134 ,  C08K5/372

    摘要： A butadiene polymer composition containing a phenolic compound represented by the formula: ##STR1## wherein R.sub.1 is an alkyl having 1 to 4 carbon atoms;R.sub.2 and R.sub.3 are each independently a group represented by --C(CH.sub.3).sub.2 --R' in which R' is an alkyl having 1 to 5 carbon atoms or phenyl, andR.sub.4 is hydrogen or methyl,and a sulfur-containing compound represented by the formula:(R.sub.5 --S--CH.sub.2 CH.sub.2 COOCH.sub.2).sub.4 Cwherein R.sub.5 is an alkyl having 4 to 20 carbon atoms. The composition is stable against the thermal deterioation and discoloration in the absence of oxygen as well as against the thermal and oxidative deterioration in the presence of oxygen.

    摘要翻译： 一种丁二烯聚合物组合物，其含有由下式表示的酚类化合物：其中R 1为具有1至4个碳原子的烷基; R2和R3各自独立地是由-C（CH3）2-R'表示的基团，其中R'是具有1至5个碳原子的烷基或苯基，R4是氢或甲基，以及由 式（R5-S-CH2CH2COOCH2）4C，其中R5是具有4-20个碳原子的烷基。 该组合物对于在不存在氧的情况下的热消除和变色以及在存在氧的情况下的热和氧化劣化方面是稳定的。