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公开(公告)号:US20070231221A1
公开(公告)日:2007-10-04
申请号:US11759096
申请日:2007-06-06
申请人: Kim Aasberg-Petersen , Ib Dybkjter , Peter Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Hansen
发明人: Kim Aasberg-Petersen , Ib Dybkjter , Peter Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Hansen
IPC分类号: B01J12/00
CPC分类号: C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0844 , C01B2203/1035 , C01B2203/143 , C01B2203/148 , C01B2203/82
摘要: Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要翻译: 用于从烃原料生产合成气的方法和系统,包括以下步骤:串联的吸热和/或绝热催化蒸汽重整和自热蒸汽重整,其中蒸汽重整在一个或多个吸热阶段串联或在 与离开绝热重整阶段的原料气体的中间加热串联的一个或多个绝热蒸汽重整级,并且其中以至少一个氢气与碳之间的氢与碳的摩尔比为小于4.5的一氧化碳的气体加入 吸热或绝热蒸汽重整阶段和/或在自热蒸汽重整步骤之前。
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公开(公告)号:US07241401B2
公开(公告)日:2007-07-10
申请号:US10667389
申请日:2003-09-23
申请人: Kim Aasberg-Petersen , Ib Dybkjaer , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
发明人: Kim Aasberg-Petersen , Ib Dybkjaer , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
CPC分类号: C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0844 , C01B2203/1035 , C01B2203/143 , C01B2203/148 , C01B2203/82
摘要: Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要翻译: 用于从烃原料生产合成气的方法和系统,包括以下步骤:串联的吸热和/或绝热催化蒸汽重整和自热蒸汽重整,其中蒸汽重整在一个或多个吸热阶段串联或在 与离开绝热重整阶段的原料气体的中间加热串联的一个或多个绝热蒸汽重整级,并且其中以至少一个氢气与碳之间的氢与碳的摩尔比为小于4.5的一氧化碳的气体加入 吸热或绝热蒸汽重整阶段和/或在自热蒸汽重整步骤之前。
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公开(公告)号:US07717971B2
公开(公告)日:2010-05-18
申请号:US11759096
申请日:2007-06-06
申请人: Kim Aasberg-Petersen , Ib Dybkjær , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
发明人: Kim Aasberg-Petersen , Ib Dybkjær , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
IPC分类号: B01J8/00
CPC分类号: C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0844 , C01B2203/1035 , C01B2203/143 , C01B2203/148 , C01B2203/82
摘要: Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要翻译: 用于从烃原料生产合成气的方法和系统,包括以下步骤:串联的吸热和/或绝热催化蒸汽重整和自热蒸汽重整,其中蒸汽重整在一个或多个吸热阶段串联或在 与离开绝热重整阶段的原料气体的中间加热串联的一个或多个绝热蒸汽重整级,并且其中以至少一个氢气与碳之间的氢与碳的摩尔比为小于4.5的一氧化碳的气体加入 吸热或绝热蒸汽重整阶段和/或在自热蒸汽重整步骤之前。
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公开(公告)号:US07087192B2
公开(公告)日:2006-08-08
申请号:US10667392
申请日:2003-09-23
申请人: Thomas Rostrup-Nielsen , Niels Erikstrup , Peter Seier Christensen , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
发明人: Thomas Rostrup-Nielsen , Niels Erikstrup , Peter Seier Christensen , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
IPC分类号: C01B3/38
CPC分类号: C01B3/384 , C01B3/382 , C01B2203/0233 , C01B2203/0816 , C01B2203/1011 , C01B2203/1023 , C01B2203/1035 , C01B2203/142 , Y02P20/129
摘要: Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon feedstock and steam and/or CO2 in the flue gas containing waste heat section from the fired tubular reformer (b) adiabatic reforming of the reaction mixture outside the waste heat section by contact with a solid reforming catalyst (c) repeating steps (a) and (b) until the desired reaction mixture composition and temperature is reached (d) feeding the reaction mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the adiabatic reforming of the reaction mixture is conducted in the process gas piping system in the flue gas-containing waste heat section, the piping system having adiabatic zones outside the heating section and containing solid reforming catalysts comprising one or more catalyzed structured elements.
摘要翻译: 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置,包括以下步骤:(a)加热烃原料和蒸汽和/或CO的反应混合物 (b)通过与固体重整催化剂(c)接触使反应混合物在废热段外部进行绝热重整,重复步骤(a), 和(b)直到达到所需的反应混合物组成和温度(d)将反应混合物进料到烧制的管状重整器中,并进一步将混合物重整成所需的组成和温度,其中反应混合物的绝热重整在 含烟道气废热段的处理气体管道系统,该管道系统在加热段外部具有绝热区,并含有固体重整催化剂,其包含一个或多个催化的st 被推翻的元素。
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公开(公告)号:US07094363B2
公开(公告)日:2006-08-22
申请号:US10668295
申请日:2003-09-24
申请人: Peter Seier Christensen , Thomas Rostrup Nielsen , Niels Erikstrup , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
发明人: Peter Seier Christensen , Thomas Rostrup Nielsen , Niels Erikstrup , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
IPC分类号: C01B3/38
CPC分类号: C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/0816 , C01B2203/0844 , C01B2203/1011 , C01B2203/1035 , C01B2203/143 , Y02P20/129 , Y02P20/142
摘要: Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.
摘要翻译: 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置,包括以下步骤:(a)加热烃和蒸汽和/或CO的反应混合物, 在与来自燃烧的管状重整器的含有废热部分的废气的一体化的加热蒸汽重整单元中,其中反应混合物的重整通过与固体重整催化剂(b)接触而进行的,所述固体重整催化剂(b) 重整混合物到烧制的管式重整器中,并进一步将混合物重整成所需的组成和温度,其中加热的蒸汽重整单元包括含有反应段的管道系统,固体重整催化剂包含催化剂颗粒和/或催化的结构化元素,管道系统 与含烟气的废热段集成的工艺气体管道系统的一部分。
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公开(公告)号:US07074347B2
公开(公告)日:2006-07-11
申请号:US10669375
申请日:2003-09-25
申请人: Niels Erikstrup , Thomas Rostrup-Nielsen , Peter Seier Christensen , Jens-Henrik Bak Hansen , Ib Dybkjer , Kim Aasberg-Petersen
发明人: Niels Erikstrup , Thomas Rostrup-Nielsen , Peter Seier Christensen , Jens-Henrik Bak Hansen , Ib Dybkjer , Kim Aasberg-Petersen
IPC分类号: C01B3/26
CPC分类号: C10G2/32 , C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C01B2203/0844 , C01B2203/1011 , C01B2203/1023 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , Y02P20/52
摘要: Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and in one or more steam reformers in series, the heat for the steam reforming reactions in the one or more steam reformers being provided by indirect heat exchange with the combined effluents from the one or more steam reformers with the autothermal steam reformer, and wherein carbon monoxide containing gas is added to the feedstock prior to the steam reforming in the autothermal steam reformer and/or prior to the steam reforming in the one or more steam reformers, the carbon monoxide containing gas having a molar ratio of hydrogen to carbon of less than 4.5 and being added in an amount resulting in a product stream having a molar ratio of hydrogen to carbon monoxide of between about 1.8 and 2.3.
摘要翻译: 通过在自热蒸汽重整器和一个或多个蒸汽重整器中并联的含烃原料的催化蒸汽重整制备合成气的方法,一个或多个蒸汽重整器中的蒸汽重整反应的热量由 与来自一个或多个蒸汽重整器的混合流出物与自热蒸汽重整器的间接热交换,并且其中在自热蒸汽重整器中的蒸汽重整之前和/或在蒸汽重整之前将一氧化碳的气体加入原料中 所述一种或多种蒸汽重整器,含有一氧化碳的气体,氢与碳的摩尔比小于4.5,加入量使氢与一氧化碳的摩尔比在约1.8至2.3之间的产物流 。
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公开(公告)号:US20060143984A1
公开(公告)日:2006-07-06
申请号:US11359466
申请日:2006-02-23
申请人: Peter Christensen , Thomas Nielsen , Niels Erikstrup , Kim Assberg-Petersen , Jens-Henrik Hansen , Ib Dybkjer
发明人: Peter Christensen , Thomas Nielsen , Niels Erikstrup , Kim Assberg-Petersen , Jens-Henrik Hansen , Ib Dybkjer
CPC分类号: C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/0816 , C01B2203/0844 , C01B2203/1011 , C01B2203/1035 , C01B2203/143 , Y02P20/129 , Y02P20/142
摘要: Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.
摘要翻译: 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置,包括以下步骤:(a)加热烃和蒸汽和/或CO的反应混合物, 在与来自燃烧的管状重整器的含有废热部分的废气的一体化的加热蒸汽重整单元中,其中反应混合物的重整通过与固体重整催化剂(b)接触而进行的,所述固体重整催化剂(b) 重整混合物到烧制的管式重整器中,并进一步将混合物重整成所需的组成和温度,其中加热的蒸汽重整单元包括含有反应段的管道系统,固体重整催化剂包含催化剂颗粒和/或催化的结构化元素,管道系统 与含烟气的废热段集成的工艺气体管道系统的一部分。
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公开(公告)号:US07547332B2
公开(公告)日:2009-06-16
申请号:US11359466
申请日:2006-02-23
申请人: Peter Scier Christensen , Thomas Rostrup Nielsen , Niels Erikstrup , Kim Assberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjer
发明人: Peter Scier Christensen , Thomas Rostrup Nielsen , Niels Erikstrup , Kim Assberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjer
IPC分类号: B01J7/00
CPC分类号: C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/0816 , C01B2203/0844 , C01B2203/1011 , C01B2203/1035 , C01B2203/143 , Y02P20/129 , Y02P20/142
摘要: Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.
摘要翻译: 用于通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置,包括以下步骤:(a)在加热的蒸汽重整单元中加热烃和蒸汽和/或CO 2的反应混合物, 含有来自燃烧管式重整器的废热段的烟气,其中通过与固体重整催化剂(b)接触进行反应混合物的重整,所述固体重整催化剂(b)将部分蒸汽重整的混合物进料到烧制的管式重整器中,并进一步将混合物重整成所需组成 和温度,其中所述加热的蒸汽重整单元包括管道系统,其包含具有包含催化剂颗粒和/或催化的结构化元素的固体重整催化剂的反应段,所述管道系统是与含烟道气的废热集成的工艺气体管道系统的一部分 部分。
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公开(公告)号:US08841042B2
公开(公告)日:2014-09-23
申请号:US12778520
申请日:2010-05-12
申请人: Niels Erikstrup , Harald Usterud , Sune Danø
发明人: Niels Erikstrup , Harald Usterud , Sune Danø
CPC分类号: H01M8/249 , H01M8/04014 , H01M8/04089 , H01M8/2425 , H01M8/2457 , H01M8/2484 , H01M8/2485 , H01M2008/1293 , Y02E60/50 , Y02E60/525 , Y02P70/56
摘要: A large, scalable SOFC system based on modules, which may be connected in series on the cathode gas side. The fuel cell stacks are aligned side by side and assembled into a stack module with cathode inlets on one face of the module and the cathode outlets on the other face of the module. The stack modules are serially connected in a simple manner by placing the stack modules one after the other, so that the outlet face of the first module faces the inlet face of the second module and so on. In the chamber between two stack modules, the air is cooled for example by addition of cold quench air or by a heat exchanger. This offers compactness, simple stack/system interface and improved system performance. The modules are designed for manufacturability, well-balanced heat management and high fuel utilization.
摘要翻译: 基于模块的大型,可扩展的SOFC系统,其可以串联连接在阴极气体侧。 燃料电池堆并排排列并组装成具有在模块的一个面上的阴极入口和模块另一面上的阴极出口的堆叠模块。 堆叠模块通过将堆叠模块一个接一个地简单地串联连接,使得第一模块的出口面朝向第二模块的入口面等等。 在两个堆叠模块之间的室中,例如通过加入冷骤冷空气或通过热交换器来冷却空气。 这提供了紧凑性,简单的堆栈/系统接口和改进的系统性能。 这些模块设计用于可制造性,均衡的热管理和高燃料利用率。
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公开(公告)号:US07794676B2
公开(公告)日:2010-09-14
申请号:US11792289
申请日:2005-12-12
申请人: Niels Erikstrup , Søren Gyde Thomsen , Michael Boe
发明人: Niels Erikstrup , Søren Gyde Thomsen , Michael Boe
IPC分类号: B01J8/44 , B01J8/02 , B01J10/00 , B01J12/00 , B01J7/02 , B01J35/02 , B01J10/02 , B01J12/02 , B01J14/00 , B01J19/00 , F28D7/00
CPC分类号: B01J8/025 , B01J8/008 , B01J8/0285 , B01J2208/00132 , B01J2208/00884 , C01B3/384 , C01B2203/0233 , C01B2203/0844 , C01B2203/1604 , C01B2203/1609 , Y02P20/52
摘要: Reactor for a catalytic conversion reaction comprising within a catalyst housing a perforated catalyst support plate supporting a catalyst bed, the perforated catalyst support plate being supported by a plurality of elongated support elements, and catalyst particles in the catalyst bed being placed outside the elongated support elements, the perforated catalyst support plate being attached to the lower ends of the elongated support elements, the perforated catalyst support plate being divided into a plurality of perforated catalyst support plate segments, at least one perforated catalyst support plate segment being supported by an elongated support element.
摘要翻译: 用于催化转化反应的反应器包括在催化剂内容纳支撑催化剂床的穿孔催化剂载体板,多孔催化剂载体板由多个细长支撑元件支撑,催化剂床中的催化剂颗粒位于细长支撑元件外部 穿孔催化剂支撑板附接到细长支撑元件的下端,穿孔催化剂支撑板被分成多个穿孔的催化剂支撑板段,至少一个穿孔的催化剂支撑板段由细长的支撑元件支撑 。
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