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公开(公告)号：US5068311A
公开(公告)日：1991-11-26
申请号：US538780
申请日：1990-06-15
摘要： The invention relates to high molecular weight thermoplastically deformable branched aliphatic polyamides prepared by polycondensation of lactams and/or polyamide-forming diamine/dicarboxylic acid reaction mixtures and/or amino acids in the presence of small amounts of specific diamino-alcohols and approximately equivalent amounts of polycarboxylic acids (preferably dicarboxylic acids), and to a process for their preparation, which is distinguished by considerably shortened polycondensation times, without crosslinked products being formed. If appropriate, the process additionally utilizes a solid phase after-condensation, in which rapid further condensation to products which are indeed branched but are soluble in m-cresol and have an increased melt viscosity takes place.
摘要翻译： 本发明涉及通过在少量特定二氨基醇存在下内酰胺和/或形成聚酰胺的二胺/二羧酸反应混合物和/或氨基酸进行缩聚而制备的高分子量热塑性可变支化脂族聚酰胺和大约等量的 多元羧酸（优选二羧酸），以及它们的制备方法，其特征在于显着缩短缩聚时间，没有形成交联产物。 如果合适，该方法另外使用固相缩合后，其中快速进一步冷凝到确实是支化但可溶于间甲酚并且具有增加的熔体粘度的产物。
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公开(公告)号：US4959452A
公开(公告)日：1990-09-25
申请号：US182336
申请日：1988-04-18
申请人： Rolf-Volker Meyer , Rolf Dhein , Martin Wandel , Harald Selbeck , Friedrich Fahnler , Hans-Detlef Heinz , Peter-Rolf Muller
发明人： Rolf-Volker Meyer , Rolf Dhein , Martin Wandel , Harald Selbeck , Friedrich Fahnler , Hans-Detlef Heinz , Peter-Rolf Muller
摘要： This invention relates to thermoplastically deformable branched aliphatic polyamides prepared by the hydrolytic polycondensation of lactams in the presence of small quantities of .alpha.-amino-.epsilon.-caprolactam (ACL) and approximately equivalent quantities of polycarboxylic acids (preferably dicarboxylic acids) and to a process for their preparation which is distinguished by considerably reduced polycondensation times without giving rise to cross-linked products. The process optionally in addition employs a solid phase after-condensation in which rapid further condensation takes place to the products with increased melt viscosity which are branched but are still soluble in m-cresol.
摘要翻译： 本发明涉及通过在少量α-氨基 - ε-己内酰胺（ACL）和约等量的多元羧酸（优选二羧酸）存在下内酰胺的水解缩聚而制备的热塑性可变形支化脂族聚酰胺， 它们的制备方法，其显着缩短缩聚时间，而不会产生交联产物。 该方法任选地另外使用固相后冷凝，其中对具有分支但仍可溶于间甲酚的熔体粘度增加的产物进行快速进一步冷凝。
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3.发明授权.alpha.-amino-.epsilon.-caprolactam-modified polyamide of dicarboxylic acids/diamines 失效二羧酸/二胺的α-氨基 - ε-己内酰胺改性聚酰胺
公开(公告)号：US4892927A
公开(公告)日：1990-01-09
申请号：US182335
申请日：1988-04-18
申请人： Rolf-Volker Meyer , Rolf Dhein , Michael Dietrich , Heinz Bonten , Hans-Detlef Heinz , Peter-Rolf Muller
发明人： Rolf-Volker Meyer , Rolf Dhein , Michael Dietrich , Heinz Bonten , Hans-Detlef Heinz , Peter-Rolf Muller
摘要： This invention relates to thermoplastically deformable, high molecular weight, slightly branched aliphatic polyamides prepared by the polycondensation of polyamide-forming, aliphatic diamine/dicarboxylic acid mixtures, optionally with the addition of lactams and special amino acids, in the presence of small quantities of .alpha.-amino-.epsilon.-caprolactam, and optionally their thermal solid phase after-condensation.
摘要翻译： 本发明涉及通过聚酰胺形成的脂肪族二胺/二羧酸混合物的缩聚制备的热塑性可变形的高分子量的微支化脂族聚酰胺，任选地加入内酰胺和特殊的氨基酸，在少量α - 氨基 - ε-己内酰胺，以及任选的它们的热固相后冷凝。
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公开(公告)号：US5128401A
公开(公告)日：1992-07-07
申请号：US642877
申请日：1991-01-18
申请人： Hans-Detlef Heinz , Aziz El-Sayed , Werner Kloker , Ralf Dujardin
发明人： Hans-Detlef Heinz , Aziz El-Sayed , Werner Kloker , Ralf Dujardin
摘要： A polymeric molding compositon based on aliphatic polyamides contains as additives polyarylene sulfides and polyphenolic compounds free from tertiary alkyl group ortho to the phenolic-OH groups is useful in producing molded articles such as films, fibers and shaped objects.
摘要翻译： 基于脂族聚酰胺的聚合物模塑组合物包含作为添加剂的聚亚芳基硫化物和不含酚-OH基团的叔烷基的多酚化合物可用于生产模制品如膜，纤维和成形物。
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5.发明授权
公开(公告)号：US5128400A
公开(公告)日：1992-07-07
申请号：US594724
申请日：1990-10-09
申请人： Hans-Detlef Heinz , Aziz E. Sayed , Ralf Dujardin , Rolf Dhein
发明人： Hans-Detlef Heinz , Aziz E. Sayed , Ralf Dujardin , Rolf Dhein
CPC分类号： C08K5/13
摘要： The invention relates to thermoplastic molding compounds based on polyamides and bisphenols having glass temperatures equal to or above those of the polyamides used, the bisphenols corresponding to the following formula ##STR1## The invention also relates to a process for their production and to their use for the production of moldings, films, fibers and other articles.
摘要翻译： 本发明涉及基于具有等于或高于所用聚酰胺的玻璃温度的聚酰胺和双酚的热塑性模塑化合物，对应于下式的双酚（I）本发明还涉及其制备方法和 它们用于生产模制品，薄膜，纤维和其他物品。
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6.发明授权Polyarylene sulphide modified with aryl sulfonic acid containing amino or hydroxyl group 失效用含有氨基酸或羟基的亚磺酸改性的聚氨酯硫化物
公开(公告)号：US5086129A
公开(公告)日：1992-02-04
申请号：US570858
申请日：1990-08-22
IPC分类号： C08L81/02 , C08G75/0213 , C08G75/029 , C08G75/06
CPC分类号： C08G75/0213 , C08G75/029
摘要： This invention relates to polyarylene sulphides, particularly polyphenylene sulphides, which are modified with hydroxyl or amino groups.
摘要翻译： 本发明涉及用羟基或氨基改性的聚亚芳基硫醚，特别是聚亚苯基硫化物。
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公开(公告)号：US4996256A
公开(公告)日：1991-02-26
申请号：US358065
申请日：1989-05-30
CPC分类号： C08K5/32
摘要： The invention relates to new, free-flowing arylene sulfide polymers (PAS) preferably phenylene sulfide polymers, which crystallize with delay, optionally additionally display improved resistance to UV radiation, and are prepared by mixing PAS with aromatic mononitro compounds in the melt, preferably with the application of shearing forces.
摘要翻译： 本发明涉及新的自由流动的亚芳基硫醚聚合物（PAS），优选苯硫醚聚合物，其延迟结晶，任选地另外显示出改进的抗UV辐射性，并且通过将PAS与芳族单硝基化合物在熔体中混合制备， 剪切力的应用。
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公开(公告)号：US5247030A
公开(公告)日：1993-09-21
申请号：US888258
申请日：1992-05-22
IPC分类号： C08G75/02
CPC分类号： C08G75/0213 , C08G75/029
摘要： This invention relates to polyarylene sulphides (PAS), preferably polyphenylene sulphides (PPS), which are modified with carboxyl groups or dicarboxylic acid anhydride groups.
摘要翻译： 本发明涉及用羧基或二羧酸酐基团改性的聚亚芳基硫醚（PAS），优选聚苯硫醚（PPS）。
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公开(公告)号：US5126429A
公开(公告)日：1992-06-30
申请号：US656594
申请日：1991-02-19
CPC分类号： C08G69/34
摘要： This invention relates to amorphous, flexible elastomeric polyamides based on dimer fatty acids and special disecondary diamines which have a glass transition temperature below 10.degree. C., to the production of these elastomeric polyamides and to their use as rubbers, plasticizers and, in particular, high-impact modifiers for thermoplastics or as flexible segments for the synthesis of thermoplastic elastomers and as additives for other purposes.
摘要翻译： 本发明涉及基于二聚脂肪酸和玻璃化转变温度低于10℃的特殊二元二胺的无定形柔性弹性聚酰胺，涉及这些弹性体聚酰胺的生产，以及它们用作橡胶，增塑剂，特别是， 用于热塑性塑料的高冲击改性剂或用于合成热塑性弹性体的柔性链段以及用于其它目的的添加剂。
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公开(公告)号：US5102935A
公开(公告)日：1992-04-07
申请号：US403133
申请日：1989-09-05
申请人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
发明人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
摘要： The invention relates to new, free-flowing polyamide molding compounds and blends, characterized in that they are prepared by mixing of polyamides known per se in the melt with low molecular weight, liquid-crystalline esters and/or ester amides corresponding to formula (I) and/or liquid-crystalline, oligomeric esters and/or ester amides corresponding to formula (II) and, optionally, other additives, at least one polymeric blending component being used as a further additive in the case of polyamide blends, and to the use of these liquid-crystalline (LC) additives I and/or II as flow promoters in polyamide molding compounds and blends and to a process for the production of the new polyamide molding compounds and blends. The invention also relates to the new oligomeric esters and/or ester amides corresponding to formula (II).
摘要翻译： 本发明涉及新的自由流动的聚酰胺模塑料和共混物，其特征在于它们通过将熔体中本身已知的聚酰胺与对应于式（I）的低分子量，液晶酯和/或酯酰胺 ）和/或对应于式（II）的液晶，低聚酯和/或酯酰胺和任选的其它添加剂，在聚酰胺共混物的情况下使用至少一种聚合共混组分作为另外的添加剂，并且 使用这些液晶（LC）添加剂I和/或II作为聚酰胺模塑料和共混物中的流动促进剂，以及生产新的聚酰胺模塑料和共混物的方法。 本发明还涉及对应于式（II）的新的低聚酯和/或酯酰胺。
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