公开(公告)号：US4985155A

公开(公告)日：1991-01-15

申请号：US324070

申请日：1989-03-16

申请人： Koichiro Yamada ,  Masaki Tanaka ,  Toshio Ohba ,  Hiroshi Ohashi

发明人： Koichiro Yamada ,  Masaki Tanaka ,  Toshio Ohba ,  Hiroshi Ohashi

IPC分类号： D06M15/263 ,  C08F283/12 ,  D06M15/643

CPC分类号： D06M15/643 ,  Y10S8/01

摘要： The fabric finishing agent is a solution of a graft copolymer composed of an organopolysiloxane moiety and a grafting moiety thereon obtained by the graft copolymerization of an acrylic or methacrylic monomer, optionally, in combination with monomers of other types. The fabric finishing agent is capable of imparting various kinds of fabric materials with greatly improved soft but non-sticky feeling of touch with resilient elasticity and the effect of treatment is durable and resistant against laundering and dry cleaning.

摘要翻译： 织物整理剂是由有机聚硅氧烷部分和其上的接枝部分组成的接枝共聚物的溶液，其通过丙烯酸或甲基丙烯酸单体的接枝共聚获得，任选地与其它类型的单体组合。 织物整理剂能够赋予各种织物材料，具有大大提高的弹性弹性的柔软但不粘的触感，并且处理效果耐久，耐洗涤和干洗。

公开(公告)号：US5102930A

公开(公告)日：1992-04-07

申请号：US381336

申请日：1989-07-18

申请人： Morizo Nakazato ,  Toshio Ohba ,  Masaki Tanaka ,  Hideki Hagiwara

发明人： Morizo Nakazato ,  Toshio Ohba ,  Masaki Tanaka ,  Hideki Hagiwara

IPC分类号： C08L83/06 ,  C08K3/36 ,  C08L83/04 ,  C09D183/04 ,  C09D183/06 ,  D06M11/00 ,  D06M11/46 ,  D06M11/79 ,  D06M13/02 ,  D06M13/248 ,  D06M13/256 ,  D06M13/50 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M15/647 ,  D06M15/65 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12

CPC分类号： D06M15/65 ,  C08L83/04 ,  D06M11/79 ,  D06M13/513 ,  D06M15/647 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/26

摘要： A novel silicone-based fabric finishing agent is proposed which is particularly suitable for finishing a fabric material containing keratinous fibers, e.g., wool, for imparting the fabric material with excellent shrink-proofness and soft and pleasant feeling of touch even after repeated laundering treatments. The fabric finishing agent is an aqueous emulsion of a hydroxy-containing organopolysiloxane with admixture of a mixture of colloidal silica and a reaction product of an amino-functional alkoxy silane or a hydrolysis product thereof with an acid anhydride, an epoxy-functional alkoxy silane compound and a curing catalyst.

摘要翻译： 提出了一种新型的有机硅基织物整理剂，其特别适合于整理含有角质纤维如羊毛的织物材料，以使织物材料具有优异的防缩性，并且即使在重复的洗涤处理之后也具有柔软和舒适的触感。 织物整理剂是含羟基的有机聚硅氧烷的水乳液，其具有胶体二氧化硅与氨基官能的烷氧基硅烷或其水解产物与酸酐的反应产物，环氧官能的烷氧基硅烷化合物 和固化催化剂。

公开(公告)号：US4891398A

公开(公告)日：1990-01-02

申请号：US231471

申请日：1988-08-12

申请人： Masaki Tanaka ,  Hiroshi Ohashi

发明人： Masaki Tanaka ,  Hiroshi Ohashi

IPC分类号： C08L83/04 ,  C08G59/00 ,  C08G59/18 ,  C08L63/00 ,  C08L83/06 ,  C08L83/08 ,  D06M15/65 ,  D06M101/00 ,  D06M101/16 ,  D06M101/30 ,  D06M101/32

CPC分类号： D06M15/65

摘要： A fiber treatment composition comprising an aqueous dispersion containing;(A) 100 parts by weight of a finely particulate epoxy group-containing organosilasesquioxane substantially represented by general unit formula (I):R.sup.1 SiO.sub.3/2 (I)wherein said organic group having an epoxy group comprises from 0.1 to 50 mol % of the whole R.sup.1 ; and;(B) from 10 to 900 parts by weight of an amino group-containing organopolysiloxane represented by general unit formula (II): ##EQU1## wherein R.sup.2 is a monovalent hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group or a hydroxyl group; Z is a particular amino group; and 1

摘要翻译： 一种纤维处理组合物，其包含含水分散体， （A）100重量份基本上由通式（I）表示的细颗粒状含环氧基的有机硅烷基二硅氧烷：R1SiO3 / 2（I）其中所述具有环氧基的有机基团占整个的0.1〜50摩尔％ R1; 和; （B）10〜900重量份的由通式（II）表示的含氨基的有机聚硅氧烷：其中R2是碳原子数1〜20的一价烃基，烷氧基或 羟基; Z是特定的氨基; 和1

公开(公告)号：US5232611A

公开(公告)日：1993-08-03

申请号：US608761

申请日：1990-11-05

申请人： Hiroshi Ohashi ,  Masaki Tanaka

发明人： Hiroshi Ohashi ,  Masaki Tanaka

IPC分类号： D06M11/00 ,  D06M11/79 ,  D06M13/02 ,  D06M13/322 ,  D06M13/463 ,  D06M13/50 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M15/647 ,  D06M15/65 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10

CPC分类号： D06M15/65 ,  D06M15/643 ,  D06M15/6433 ,  D06M15/6436 ,  D06M15/647 ,  Y10T428/31663

摘要： This invention discloses a fiber treatment agent characterized in that it comprises:(A) 100 parts by weight of an organopolysiloxane with no less than 2 hydroxyl groups and/or alkoxyl groups bonded to Si atoms per molecule,(B) 0.5-50 parts by weight of silica and/or a polysilsesquioxane,(C) 0.1-20 parts by weight of an organoalkoxysilane containing amide groups and carboxyl groups, and/or its partial hydrolysis condensate,(D) 0.1-20 parts by weight of an organoalkoxysilane containing amino groups or epoxy groups and/or its partial hydrolysis condensate, and(E) 0.01-10 parts by weight of a curing catalyst, and characterized in that it is also a cationic or non-ionic emulsion.

摘要翻译： 本发明公开了一种纤维处理剂，其特征在于，它包括：（A）100重量份具有不少于2个羟基和/或每个分子与Si原子键合的烷氧基的有机聚硅氧烷，（B）0.5-50份 二氧化硅和/或聚倍半硅氧烷的重量，（C）0.1-20重量份含有酰胺基和羧基的有机烷氧基硅烷和/或其部分水解缩合物，（D）0.1-20重量份含氨基的有机烷氧基硅烷 基团或环氧基团和/或其部分水解缩合物，和（E）0.011-10重量份的固化催化剂，其特征在于它也是阳离子或非离子乳液。

公开(公告)号：US4617340A

公开(公告)日：1986-10-14

申请号：US740983

申请日：1985-06-04

申请人： Masaki Tanaka ,  Hiroshi Ohashi

发明人： Masaki Tanaka ,  Hiroshi Ohashi

IPC分类号： C08G18/61 ,  C08G77/46 ,  C08L83/05 ,  D06M15/564 ,  D06M15/568 ,  D06M15/643 ,  D06M15/647 ,  D06M15/653 ,  C08L83/00

CPC分类号： C08G77/46 ,  C08G18/61 ,  D06M15/564 ,  D06M15/568 ,  D06M15/6436 ,  D06M15/647 ,  D06M15/653 ,  Y10T428/31663

摘要： The inventive fabric treatment agent can impart excellent hydrophilicity to fabric materials of, in particular, synthetic fibers with durability and launderability. The principal ingredient of the agent is a copolymer composed of three types of moieties including (a) a diorganopolysiloxane terminated at both molecular chain ends each with a non-silanolic hydroxy group or other active hydrogen-containing group, e.g. --SH, --COOH and --NH.sub.2, (b) a polyol compound having polyoxyalkylene linkages which is typically a polyoxyethylene glycol and (c) a diisocyanate compound which serves as a coupling agent between the moieties (a) and (b).

摘要翻译： 本发明的织物处理剂可以赋予具有耐久性和洗涤性的特别是合成纤维的织物材料优异的亲水性。 试剂的主要成分是由三种类型的部分组成的共聚物，其包括（a）在两个分子链末端封端的二有机聚硅氧烷，每个分子链端均具有非硅烷醇羟基或其它含活性氢基团。 -SH，-COOH和-NH 2，（b）具有聚氧化烯键的多元醇化合物，其通常为聚氧乙烯二醇，和（c）作为部分（a）和（b）之间的偶联剂的二异氰酸酯化合物。

公开(公告)号：US5025076A

公开(公告)日：1991-06-18

申请号：US315879

申请日：1989-02-27

申请人： Masaki Tanaka ,  Hiroshi Ohashi ,  Yoshinobu Takahashi

发明人： Masaki Tanaka ,  Hiroshi Ohashi ,  Yoshinobu Takahashi

IPC分类号： C08L83/08 ,  D06M13/02 ,  D06M13/50 ,  D06M15/643

CPC分类号： D06M15/6436 ,  C08L83/08

摘要： A silicone-based fabric finishing agent which comprises: an aminoalkyl-substituted diorganopolysiloxane; a reaction product of an aminoalkyl-substituted organopolysiloxane and an epoxy-containing organic compound; a hydrolysis product of an epoxy-containing hydrolyzable organosilane coupound; and, optionally, an aminoalkyl-substituted organopolysiloxane having a specified viscosity, each in a specified proportion is particularly suitable for the softening treatment of waddings of synthetic fibers, e.g., polyester fibers, and advantageous over conventional silicone-based fabric treatment agents with respect to the excellent softness and smoothness of the treated wadding, which is freed from the problem of discoloration or yellowing caused in the course of the heat treatment and by the lapse of time, as well as the durability of these effects to withstand dry cleaning.

摘要翻译： 一种硅氧烷基织物整理剂，其包含：氨基烷基取代的二有机聚硅氧烷; 氨基烷基取代的有机聚硅氧烷与含环氧基的有机化合物的反应产物; 含环氧基的可水解有机硅烷的水解产物; 和任选地，具有特定粘度的氨基烷基取代的有机聚硅氧烷，各自以特定比例特别适用于合成纤维（例如聚酯纤维）的缠绕的软化处理，并且相对于常规的有机硅基织物处理剂，相对于 处理过的填料的柔软性和平滑性优异，可以避免在热处理过程中引起的变色或变黄的时间以及时间的流逝，以及这些耐干洗效果的耐久性。

公开(公告)号：US4725635A

公开(公告)日：1988-02-16

申请号：US48695

申请日：1987-05-12

申请人： Fumio Okada ,  Masaki Tanaka ,  Hiroshi Ohashi

发明人： Fumio Okada ,  Masaki Tanaka ,  Hiroshi Ohashi

IPC分类号： D06M13/50 ,  C08K5/1515 ,  C08K5/5435 ,  D06M13/02 ,  D06M13/11 ,  D06M13/165 ,  D06M13/203 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M101/00 ,  D06M101/16 ,  C08K5/15

CPC分类号： D06M13/513 ,  C08K5/1515 ,  C08K5/5435 ,  D06M13/11 ,  D06M13/203 ,  Y10T428/31663

摘要： The silicone-based fiber finishing agent is particularly suitable for synthetic fiber-made fabric materials such as waddings of polyester fibers to impart excellent softness and smoothness in touch and free from yellowing even by heating with high resistance against dry cleaning. The fiber finishing agent comprises (A) an organopolysiloxane of a substantially linear molecular structure terminated at each molecular chain end with a silanolic hydroxy group or alkoxy group and having at least one amino-substituted hydrocarbon group bonded to the silicon atom in a molecule, (B) an epoxy-containing alkoxy silane compound such as methyl dimethoxy 3-glycidyloxypropyl silane and (C) an epoxy-containing organic compound free from silicon such as glycidyl alcohol and glycidyl methacrylate.

摘要翻译： 硅氧烷类纤维整理剂特别适用于合成纤维制造的织物材料，例如聚酯纤维的缠绕，以赋予极好的柔软性和平滑感，并且即使通过加热而具有高的抗干洗性也不会发黄。 纤维整理剂包含（A）在每个分子链末端具有硅烷醇羟基或烷氧基并在分子中具有至少一个与硅原子键合的氨基取代烃基的基本上线性分子结构的有机聚硅氧烷（ B）含环氧基的烷氧基硅烷化合物如甲基二甲氧基3-缩水甘油氧基丙基硅烷和（C）不含硅的含环氧基的有机化合物，如缩水甘油基醇和甲基丙烯酸缩水甘油酯。

公开(公告)号：US4617344A

公开(公告)日：1986-10-14

申请号：US732239

申请日：1985-05-08

申请人： Masaki Tanaka ,  Hiroshi Ohashi

发明人： Masaki Tanaka ,  Hiroshi Ohashi

IPC分类号： D06N3/04 ,  C08G77/00 ,  C08G77/06 ,  C08G77/28 ,  C08G77/30 ,  C08L83/00 ,  C08L83/04 ,  C08L83/07 ,  C08L83/08 ,  C10M105/76 ,  C10N40/00 ,  C10N40/36 ,  C10N50/02 ,  C10N50/08 ,  D06M15/643

CPC分类号： D06M15/643 ,  C08G77/30

摘要： The organopolysiloxane in the inventive latex is modified with phosphonate ester-containing groups such as those expressed by the formula --Si--CH.sub.2 CH.sub.2 --PO(OEt).sub.2 (Et: ethyl group) and --Si--CH.sub.2 CH.sub.2 CH.sub.2 --PO(ODd).sub.2 (Dd: dodecyl group) and exhibits excellent performance in the applications as a fabric treatment agent and the like. The inventive organopolysiloxane latex can be prepared by the polymerizing reaction of an organosilicon compound or, preferably, an organopolysiloxane and a phosphonate ester-modified alkoxysilane emulsified together in an aqueous medium containing a surface active agent of the class of the organic sulfonic acid type or a sulfate ester type ones which serves both as an emulsifier and as an acid catalyst.

摘要翻译： 本发明胶乳中的有机聚硅氧烷用含有膦酸酯的基团进行改性，例如由式-Si-CH2CH2-PO（OEt）2（Et：乙基）和-Si-CH2CH2CH2-PO（ODd）2（Dd ：十二烷基），并且在作为织物处理剂等的应用中表现出优异的性能。 本发明的有机聚硅氧烷胶乳可以通过将有机硅化合物或优选有机聚硅氧烷和膦酸酯改性的烷氧基硅烷在含有有机磺酸型的表面活性剂的水性介质中乳化的膦酸酯改性烷氧基硅烷的聚合反应来制备， 用作乳化剂和作为酸催化剂的硫酸酯型。

公开(公告)号：US4987180A

公开(公告)日：1991-01-22

申请号：US288903

申请日：1988-12-23

申请人： Hiroyuki Ohata ,  Masaki Tanaka ,  Hiroshi Ohashi ,  Kiyoji Suemoto ,  Hidekazu Iida ,  Hiroshi Saga

发明人： Hiroyuki Ohata ,  Masaki Tanaka ,  Hiroshi Ohashi ,  Kiyoji Suemoto ,  Hidekazu Iida ,  Hiroshi Saga

IPC分类号： D06M15/263 ,  C08F283/12 ,  C08L51/08 ,  C09D183/04 ,  D06M13/02 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M15/65 ,  C08L83/04

CPC分类号： D06M15/6433 ,  C08F283/122 ,  C08F283/124 ,  D06M15/643 ,  D06M15/65

摘要： An excellently pleasant feeling of softness and elastic resilience can be imparted to a fabric material treated with the inventive fabric finishing agent which is an aqueous emulsion of a copolymer obtained by the emulsion polymerization, in an aqueous emulsion of an organopolysiloxane having radical-polymerizable groups, e.g., vinyl groups, or mercapto-substituted hydrocarbon groups, e.g., 3-mercaptopropyl groups, as the polymerization medium of an acrylic or methacrylic monomer, e.g., alkyl acrylates and methacrylates, in a specified amount relative to the amount of the organopolysiloxane. The acrylic or methacrylic monomer may be partly replaced with a polyfunctional monomer, e.g., acrylic and methacrylic acids, N-methylol acrylamide, glycidyl methacrylate, 2-hydroxyethyl methacrylate and the like, and/or a monomer of the third class, e.g., styrene and acrylonitrile. The emulsion may be further admixed with an organohydrogen polysiloxane as a crosslinking agent and a catalyst for the crosslinking reaction.

摘要翻译： 可以通过本发明的织物整理剂（其是通过乳液聚合获得的共聚物的水性乳液）在具有可自由基聚合基团的有机聚硅氧烷的水性乳液中处理柔软性和弹性回弹性的令人愉快的感觉， 例如乙烯基或巯基取代的烃基，例如3-巯基丙基，作为丙烯酸或甲基丙烯酸单体的聚合介质，例如丙烯酸烷基酯和甲基丙烯酸烷基酯，相对于有机聚硅氧烷的量为规定量。 丙烯酸或甲基丙烯酸单体可以部分地被多官能单体例如丙烯酸和甲基丙烯酸，N-羟甲基丙烯酰胺，甲基丙烯酸缩水甘油酯，甲基丙烯酸2-羟乙酯等，和/或第三类的单体例如苯乙烯 和丙烯腈。 乳液可以进一步与作为交联剂的有机氢聚硅氧烷和用于交联反应的催化剂混合。

公开(公告)号：US4894412A

公开(公告)日：1990-01-16

申请号：US195650

申请日：1988-05-18

申请人： Fumio Okada ,  Masaki Tanaka ,  Hiroshi Ohashi

发明人： Fumio Okada ,  Masaki Tanaka ,  Hiroshi Ohashi

IPC分类号： B01F17/00 ,  B01F17/54 ,  C08G77/06 ,  C08G77/26 ,  C08G77/28 ,  C08L83/04 ,  C08L83/08 ,  C11D3/37 ,  D06M15/643

CPC分类号： C11D3/3742 ,  B01F17/0071 ,  B01F17/0085 ,  C08G77/26 ,  D06M15/6436

摘要： A process for preparing a self-crosslinkable aminosiloxane emulsion, comprising:dispersing by emulsification in water in the presence of a cationic surface active agent and a nonionic surface active agent:(A) a specific organosilicon compound that may have a hydroxyl group and/or an alkoxy group;(B) a specific organosilicon compound having a nitrogen-containing monovalent hydrocarbon group; and(C) a specific organosilane having a hydroxyl group and/or an alkoxy group, and or a partial hydrolysis-condensation product thereof;subsequently carrying out emulsion polymerization in the presence of an alkaline catalyst; andthereafter neutralizing the reaction product.The resulting emulsion is useful as softening agents, smoothing agents or feeling improver for all sorts of textiles, and binders between fibers.

摘要翻译： 一种制备自交联氨基硅氧烷乳液的方法，包括：在阳离子表面活性剂和非离子表面活性剂存在下，通过乳化分散在水中：（A）可具有羟基和/或具有羟基的特定有机硅化合物 烷氧基 （B）具有含氮一价烃基的特定有机硅化合物; 和（C）具有羟基和/或烷氧基的特定有机硅烷，或其部分水解缩合产物; 随后在碱性催化剂存在下进行乳液聚合; 然后中和反应产物。 所得乳液可用作各种纺织品的软化剂，平滑剂或感觉改进剂，以及纤维之间的粘合剂。