摘要:
A polymer film producing apparatus has a moving support on which dope containing polymer and solvent is cast to form a cast film. The cast film is stripped from the support to obtain a polymer film containing the solvent, and the polymer film is dried. A first gas flow duct has gas nozzles for causing a first dry gas to flow toward the cast film. A second gas flow duct has a gas outlet disposed downstream from the gas nozzles, and positioned higher than a height of the gas nozzles relative to the support, for causing a second dry gas to flow toward the cast film in a moving direction of the support. Furthermore, the first gas flow duct includes a gas blow wall for defining the first flow path by opposing to the support. The gas blow wall has the gas nozzles.
摘要:
A polymer film producing apparatus has a moving support on which dope containing polymer and solvent is cast to form a cast film. The cast film is stripped from the support to obtain a polymer film containing the solvent, and the polymer film is dried. A first gas flow duct has gas nozzles for causing a first dry gas to flow toward the cast film. A second gas flow duct has a gas outlet disposed downstream from the gas nozzles, and positioned higher than a height of the gas nozzles relative to the support, for causing a second dry gas to flow toward the cast film in a moving direction of the support. Furthermore, the first gas flow duct includes a gas blow wall for defining the first flow path by opposing to the support. The gas blow wall has the gas nozzles.
摘要:
A nozzle (55b) is disposed on a bottom (55a) of an air duct (55), and a drying air (56) is fed out from a nozzle (55b) toward a casting film (69). A data of a wind speed of the drying air (56) is input on a key board (100) to a controller (58), in which a height H of the air duct (55) from a casting belt (46) is calculated from the input wind velocity V. On the basis of the calculated height H, the controller (58) drives a shift device (102) to shift the air duct (55) up- and downwardly, such that the height H may be in the range of 20 mm to 300 mm.
摘要:
A surfactant is added to a polymer solution (21) which is a coating fluid comprising an organic solvent and a polymer. The surfactant contains a fluorine atom and reduces the surface tension of the coating fluid. The coating fluid (21) is applied to a casting band (26) as a support. Dew condensation is caused to occur on the surface of the polymer film (40) formed by coating fluid application. The organic solvent and droplets are vaporized to thereby cause droplets to come into the film and form voids. By the use of the polymer solution (21), which comprises a mixture of an organic solvent, a polymer, and a fluorine-atom-containing surfactant for surface tension reduction, a structure having such fine pores is formed and a film (12) of a honeycomb structure is obtained. This film is reduced in the adhesion of dust, etc. and has an even micropore structure
摘要:
A polymer film, wherein when any point in the polymer film is taken as a center, a maximum difference between high and low film thicknesses within a range of 60 mm diameter is not more than 1 μm, an RMS value of a film thickness is 0 μm to 0.15 μm or a difference between maximum and minimum values of slow axis angle in any 60 mm×60 mm square in the polymer film is 0° to 0.40°; and a solution casting film-forming method comprising: casting a dope on a support; peeling the casted film, wherein a dry wind of 3 m/s to 15 m/s is applied to the casted film within 15 seconds from the casting, and wherein before the dry wind is applied to the casted film, an air floating on a surface of the casted film has a wind velocity of less than 3 m/s.
摘要:
A polymer film, wherein when any point in the polymer film is taken as a center, a maximum difference between high and low film thicknesses within a range of 60 mm diameter is not more than 1 μm, an RMS value of a film thickness is 0 μm to 0.15 μm or a difference between maximum and minimum values of slow axis angle in any 60 mm×60 mm square in the polymer film is 0° to 0.40°; and a solution casting film-forming method comprising: casting a dope on a support; peeling the casted film, wherein a dry wind of 3 m/s to 15 m/s is applied to the casted film within 15 seconds from the casting, and wherein before the dry wind is applied to the casted film, an air floating on a surface of the casted film has a wind velocity of less than 3 m/s.
摘要:
A polymer solution (21) is prepared by dissolving poly-.ε.-caprolactone and amphipathic polyacrylamide in an organic solvent. The polymer solution (21) is cast from a casting die (25) onto a casting belt (26) to form a casting film (40). Air (35) from a blowing and suctioning device (34) is sent to the casting film (40) to generate droplets (44). The relative speed of drying air (37) to the moving speed of the casting belt (26) is adjusted at 5 m/min in parallel flow. The water in the drying air (37) is condensed in the casting film (40) to form the droplets (44). The droplets (44) are evaporated after evaporating the organic solvent in the casting film (40), so that a honeycomb-structure film (12) can be obtained.
摘要:
A cellulose acylate film that has a maximum thickness difference (P−V value) of 1 μm or less within a range of a diameter of 60 mm with an arbitrary point as center, and that has an in-plane retardation Re(λ) satisfying a relationship Re(590))≦5 nm and a thickness-direction retardation Rth(λ) satisfying a relationship |Rth(590)|≦60 nm, wherein Re(λ) represents an in-plane retardation (Re) value (unit: nm) at a wavelength of λnm; and Rth(λ)) represents a thickness-direction retardation (Rth) value (unit: nm) at a wavelength of λnm.
摘要:
A polymer solution (21) is prepared by dissolving poly-.ε.-caprolactone and amphipathic polyacrylamide in an organic solvent. The polymer solution (21) is cast from a casting die (25) onto a casting belt (26) to form a casting film (40). Air (35) from a blowing and suctioning device (34) is sent to the casting film (40) to generate droplets (44). The relative speed of drying air (37) to the moving speed of the casting belt (26) is adjusted at 5 m/min in parallel flow. The water in the drying air (37) is condensed in the casting film (40) to form the droplets (44). The droplets (44) are evaporated after evaporating the organic solvent in the casting film (40), so that a honeycomb-structure film (12) can be obtained.
摘要:
A multilayer film including a porous layer, which is formed from a first polymer and has a plurality of pores, and a support (33) for supporting the porous layer is produced. The porous layer is obtained by applying a coating liquid to the support (33). The coating liquid is a solution containing the first polymer and a solvent. The support (33) is formed from a second polymer capable of being dissolved into the solvent for forming the coating liquid. Water vapor is condensed from ambient water on the applied coating liquid, and the solvent is evaporated from the coating layer within 20 minutes. Thereafter, the water drops are evaporated from the coating layer. A plurality of pores are uniformly formed in the coating layer. Thereby, it is possible to produce a multilayer film having a thickness which achieves excellent handleability.