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公开(公告)号：US5502230A
公开(公告)日：1996-03-26
申请号：US514529
申请日：1995-08-14
摘要： In the process of the present invention, disilanes are reacted with hydrogen chloride in the presence of a catalyst comprising(A) palladium(O) or platinum(O), and(B) an organic compound selected from among tertiary amines, carboxamides, alkylureas, tertiary phosphines, phosphoramides, quaternary ammonium halides, quaternary phosphonium halides or mixtures thereof to give hydrogen-containing methylchlorosilanes.
摘要翻译： 在本发明的方法中，在包含（A）钯（O）或铂（O）的催化剂存在下，使二硅烷与氯化氢反应，和（B）选自叔胺，甲酰胺，烷基脲 ，叔膦，磷酰胺，季铵卤化物，季鏻卤化物或其混合物，得到含氢的甲基氯硅烷。
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公开(公告)号：US06323357B1
公开(公告)日：2001-11-27
申请号：US09814193
申请日：2001-03-21
IPC分类号： C07F716
CPC分类号： C07F7/16 , Y02P20/584
摘要： A process for the direct synthesis of organochlorosilanes using CuCl prepared from the copper-containing residues from the direct synthesis of organochlorosilanes, where, in the preparation of the CuCl, in a first step, copper from an aqueous suspension of the copper-containing residues is oxidized to CuCl2 using mineral acid and oxidant, where mineral acid or oxidant or mineral acid and oxidant contain chlorine, giving an aqueous CuCl2 solution, and in a second step, the aqueous CuCl2 solution is reduced to CuCl using elemental iron.
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公开(公告)号：US06175030B1
公开(公告)日：2001-01-16
申请号：US09523600
申请日：2000-03-13
IPC分类号： C07F716
CPC分类号： C07F7/16
摘要： In a process for the direct synthesis of methylchlorosilanes, chloromethane is reacted with a catalyst composition comprising silicon, copper catalyst, zinc promoter and pyrogenic silicic acid.
摘要翻译： 在直接合成甲基氯硅烷的方法中，氯甲烷与包含硅，铜催化剂，锌促进剂和致热硅酸的催化剂组合物反应。
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公开(公告)号：US07368590B2
公开(公告)日：2008-05-06
申请号：US10598850
申请日：2005-03-17
摘要： Aluminum chloride is removed effectively from compound mixtures containing organochlorosilanes such as are produced in the direct synthesis, by adding a diluent containing organochlorosilanes and optionally chloromethane to a solids content 71° C. of less than 25%, and evaporating this diluted mixture into a volatile product stream and an AlCl3-containing solid.
摘要翻译： 通过加入含有有机氯硅烷和任选的氯甲烷的稀释剂至<15％的固体含量和沸点> 71℃的化合物的浓度，将氯化铝有效地从含有有机氯硅烷的混合物混合物中除去， 小于25％，并将该稀释的混合物蒸发成挥发性产物流和含AlCl 3的固体。
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公开(公告)号：US07550620B2
公开(公告)日：2009-06-23
申请号：US11856731
申请日：2007-09-18
IPC分类号： C07F7/16
CPC分类号： C07F7/16
摘要： The invention relates to a process for the direct synthesis of methylchlorosilanes by reaction of chloromethane with a contact composition comprising silicon and copper catalyst, wherein the concentration of oxygen in the chloromethane used is reduced by mixing a) chloromethane which contains oxygen, and b) chloromethane which contains a gaseous boron compound.
摘要翻译： 本发明涉及通过氯甲烷与包含硅和铜催化剂的接触组合物的反应直接合成甲基氯硅烷的方法，其中所用氯甲烷中的氧浓度通过混合a）含有氧的氯甲烷和b）氯甲烷 其含有气态硼化合物。
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公开(公告)号：US07205426B2
公开(公告)日：2007-04-17
申请号：US11231509
申请日：2005-09-21
申请人： Wilfried Kalchauer , Jochen Gross
发明人： Wilfried Kalchauer , Jochen Gross
IPC分类号： C07F7/04
CPC分类号： C07F7/16
摘要： A process for the direct synthesis of methylchlorosilanes by reaction of chloromethane with a contact composition comprising silicon, copper catalyst and from 10 to 90 ppm of strontium leads to increased selectivity and higher production rate.
摘要翻译： 通过氯甲烷与包含硅，铜催化剂和10至90ppm锶的接触组合物的反应直接合成甲基氯硅烷的方法导致增加的选择性和更高的生产速率。
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公开(公告)号：US07153992B2
公开(公告)日：2006-12-26
申请号：US11341094
申请日：2006-01-27
申请人： Wilfried Kalchauer , Jochen Gross
发明人： Wilfried Kalchauer , Jochen Gross
IPC分类号： C07F7/04
CPC分类号： C07F7/16
摘要： The invention relates to a process for the direct synthesis of methylchlorosilanes by reaction of chloromethane with a contact composition comprising silicon, copper catalyst and a total proportion of sodium and potassium of from 10 to 400 ppm.
摘要翻译： 本发明涉及一种直接合成甲基氯硅烷的方法，该方法是通过氯甲烷与包含硅，铜催化剂和总比例为10至400ppm的钠和钾的接触组合物的反应来进行的。
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公开(公告)号：US5981784A
公开(公告)日：1999-11-09
申请号：US282688
申请日：1999-03-31
CPC分类号： C07F7/16
摘要： In the direct synthesis of methylchlorosilanes by reacting methyl chloride with a catalyst composition which comprises silicon, copper catalyst, zinc promoters and tin promoters and/or antimony promoters, a catalyst composition is used which was activated in advance by treatment with HCl under specific activation conditions.
摘要翻译： 在甲基氯硅烷与包含硅，铜催化剂，锌促进剂和锡促进剂和/或锑促进剂的催化剂组合物的反应中甲基氯硅烷的直接合成中，使用催化剂组合物，其预先通过在特定活化条件下用HCl处理而活化 。
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公开(公告)号：US20060063946A1
公开(公告)日：2006-03-23
申请号：US11231509
申请日：2005-09-21
申请人： Wilfried Kalchauer , Jochen Gross
发明人： Wilfried Kalchauer , Jochen Gross
IPC分类号： C07F7/16
CPC分类号： C07F7/16
摘要： A process for the direct synthesis of methylchlorosilanes by reaction of chloromethane with a contact composition comprising silicon, copper catalyst and from 10 to 90 ppm of strontium leads to increased selectivity and higher production rate.
摘要翻译： 通过氯甲烷与包含硅，铜催化剂和10至90ppm锶的接触组合物的反应直接合成甲基氯硅烷的方法导致增加的选择性和更高的生产速率。
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公开(公告)号：US06211394B1
公开(公告)日：2001-04-03
申请号：US09625811
申请日：2000-07-26
IPC分类号： C07F716
CPC分类号： C07F7/16
摘要： The invention relates to a continuous process for the direct synthesis of methylchlorosilanes by reacting chloromethane with a catalyst composition comprising silicon, zinc promoter and copper catalyst which is selected from a) copper oxide, b) mixtures of at least 80% by weight of copper oxide and copper(I) chloride, c) copper(I) chloride and d) mixtures of at least 80% by weight of copper(I) chloride and copper oxide, where copper catalysts a), b), c) or d) are employed alternately in such a way that copper catalyst a) or b) is followed by c) or d), or copper catalyst c) or d) is followed by copper catalyst a) or b).
摘要翻译： 本发明涉及通过氯甲烷与包含硅，锌助催化剂和铜催化剂的催化剂组合物直接合成甲基氯硅烷的连续方法，所述催化剂组合物选自a）氧化铜，b）至少80重量％的氧化铜和 c）氯化铜（I），c）氯化铜（I）和d）至少80重量％的氯化铜（I）和氧化铜的混合物，其中铜催化剂a），b），c）或d）交替使用 铜催化剂a）或b）之后是c）或d），或铜催化剂c）或d）之后是铜催化剂a）或b）。
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