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1.发明授权Process for preparing alkylchlorosilanes from the residues of direct synthesis of alkylchlorosilanes 失效从直接合成烷基氯硅烷的残留物制备烷基氯硅烷的方法
公开(公告)号：US5877337A
公开(公告)日：1999-03-02
申请号：US012365
申请日：1998-01-23
摘要： Alkylchlorosilanes are prepared continuously from the residue of direct synthesis of alkylchlorosilanes containing liquid constituents with a boiling point of at least 70.degree. C. at 1013 hPa and solid constituents, by heating the residue with hydrogen chloride at temperatures of from 300.degree. C. to 800.degree. C. in a tubular reactor with internals which can be rotated.
摘要翻译： 烷基氯硅烷从含有液体组分的烷基氯硅烷的残留物连续制备，该组分含有沸点为1013hPa的沸点至少为70℃，固体组分通过用氯化氢在300℃至800℃的温度下加热残余物 在具有能够旋转的内部的管式反应器中。
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2.发明授权Separation of methylchlorosilanes from high boiling residues of methylchlorosilane synthesis 失效甲基氯硅烷与甲基氯硅烷合成高沸点残留物的分离
公开(公告)号：US5288892A
公开(公告)日：1994-02-22
申请号：US48597
申请日：1993-04-19
申请人： Bernd Pachaly , Anton Schinabeck
发明人： Bernd Pachaly , Anton Schinabeck
摘要： A process for separating methylchlorosilanes from high boiling residues from the methylchlorosilane synthesis, in which cleavable methylchlorodisilanes which are present in the residues and which have at least two chlorine atoms attached to one silicon atom are cleaved with hydrogen chloride in the presence of a catalyst which remains in the reaction mixture, which comprises cleaving the methylchlorodisilanes in the presence of by-products which are more volatile than the cleavable methylchlorodisilanes in the high boiling residues from the methylchlorosilane synthesis which have a boiling point of at least 70.degree. C. under normal conditions and continuously removing the more volatile by-products from the reaction mixture along with the methylchlorosilanes and the noncleavable methylchlorodisilanes.
摘要翻译： 从甲基氯硅烷合成中分离甲基氯硅烷与高沸点残留物的方法，其中存在于残基中并具有至少两个氯原子连接到一个硅原子上的可切割甲基氯代二硅烷在氯化氢的存在下在残留的催化剂 在反应混合物中，其包括在正常条件下沸点为至少70摄氏度的甲基氯代硅烷合成的高沸点残余物中比可切割甲基氯代二硅烷更易挥发的副产物切割甲基氯代二硅烷; 与甲基氯硅烷和不可裂解的甲基氯代二硅烷连续除去反应混合物中更易挥发的副产物。
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3.发明授权
公开(公告)号：US4298753A
公开(公告)日：1981-11-03
申请号：US209447
申请日：1980-11-24
摘要： A continuous process for preparing silanes and siloxanes having SiOC groups which comprises (a) introducing in a liquid phase a chlorosilane and a hydroxyl-containing aliphatic compound in parallel flow into a first stage of a first reactor in an amount such that from 0.5 to 0.9 gram-mole of hydroxyl group is present per gram-atom of Si-bonded chlorine; (b) removing the liquid reaction mixture from the first reactor; (c) introducing the reaction mixture at the head of a column used as the second reactor which is maintained at an elevated temperature; (d) adding a hydroxyl-containing aliphatic compound as a gas at the lower end of the column or at a point between the lower end and the upper end of the lower one-third of the column, in an amount at least sufficient to completely react with the Si-bonded chlorine present in the reaction mixture obtained from the first stage and (e) removing the silane containing SiOC groups or polysiloxane containing SiOC groups from the column at a point below the point of addition of the hydroxyl-containing aliphatic compound.
摘要翻译： 一种用于制备具有SiOC基团的硅烷和硅氧烷的连续方法，其包括（a）以液相方式将氯硅烷和含羟基的脂族化合物平行流入第一反应器的第一阶段，其量使得为0.5至0.9 每克原子的硅键合氯存在克分子的羟基; （b）从第一反应器中除去液体反应混合物; （c）将反应混合物引入用作第二反应器的柱头，保持在升高的温度; （d）在柱的下端或在塔的下三分之一的下端和上端之间的点处加入含羟基的脂族化合物作为气体，其量至少足以完全 与从第一阶段获得的反应混合物中存在的Si键合的氯反应，和（e）在含羟基的脂族化合物的加入点以下的点从塔中除去含有SiOC基团的含硅烷的硅烷或聚硅氧烷 。
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公开(公告)号：US06169195A
公开(公告)日：2001-01-02
申请号：US09484978
申请日：2000-01-18
申请人： Anton Schinabeck , Konrad Mautner
发明人： Anton Schinabeck , Konrad Mautner
IPC分类号： C07F708
摘要： The invention relates to a process for cleavage of chlorohydrocarbons which are present as an impurity in organochlorosilanes, in which the chlorohydrocarbons are brought into contact with steel surfaces which comprise nickel as an alloying constituent, and are cleaved into olefins and hydrogen chloride.
摘要翻译： 本发明涉及在有机氯硅烷中作为杂质存在的氯代烃的裂解方法，其中氯代烃与包含镍作为合金成分的钢表面接触，并且被切割成烯烃和氯化氢。
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公开(公告)号：US5476958A
公开(公告)日：1995-12-19
申请号：US418218
申请日：1995-04-06
申请人： Konrad Mautner , Anton Schinabeck
发明人： Konrad Mautner , Anton Schinabeck
摘要： In the process for the removal of olefins from the silanes or silane mixtures obtained during methylchlorosilane synthesis, the olefins are reacted with hydrogen in the presence of hydrogenation catalysts.
摘要翻译： 在甲基氯硅烷合成过程中从硅烷或硅烷混合物中除去烯烃的过程中，烯烃与氢气在氢化催化剂存在下反应。
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6.发明授权
公开(公告)号：US5264084A
公开(公告)日：1993-11-23
申请号：US933141
申请日：1992-08-21
CPC分类号： C07F7/16 , C07F7/20 , Y10S203/06
摘要： A process for separating alkenes from a methylchlorosilane mixture by adding at least a stoichiometric amount of hydrogen chloride necessary for saturating the alkenes in the methylchlorosilane mixture and thereafter removing resulting chloroalkanes by distillation.
摘要翻译： 通过向甲基氯硅烷混合物中加入至少化学计量量的饱和烯烃所需的氯化氢，然后通过蒸馏除去所得的氯代烷烃，从甲基氯硅烷混合物中分离烯烃的方法。
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公开(公告)号：US5502230A
公开(公告)日：1996-03-26
申请号：US514529
申请日：1995-08-14
摘要： In the process of the present invention, disilanes are reacted with hydrogen chloride in the presence of a catalyst comprising(A) palladium(O) or platinum(O), and(B) an organic compound selected from among tertiary amines, carboxamides, alkylureas, tertiary phosphines, phosphoramides, quaternary ammonium halides, quaternary phosphonium halides or mixtures thereof to give hydrogen-containing methylchlorosilanes.
摘要翻译： 在本发明的方法中，在包含（A）钯（O）或铂（O）的催化剂存在下，使二硅烷与氯化氢反应，和（B）选自叔胺，甲酰胺，烷基脲 ，叔膦，磷酰胺，季铵卤化物，季鏻卤化物或其混合物，得到含氢的甲基氯硅烷。
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