公开(公告)号：US06682650B2

公开(公告)日：2004-01-27

申请号：US09873241

申请日：2001-06-05

申请人： Kosaku Honna ,  Yasuhiro Araki ,  Yasuo Miki ,  Hiromichi Shimada

发明人： Kosaku Honna ,  Yasuhiro Araki ,  Yasuo Miki ,  Hiromichi Shimada

IPC分类号： B01J2906

CPC分类号： B01J29/166 ,  B01J29/088 ,  B01J29/106 ,  B01J2229/14 ,  B01J2229/186 ,  C10G2300/107

摘要： A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf. A catalyt having a hydrogenation catalytic metal loaded on the above catalyst support exhibits

摘要翻译： 一种催化剂载体，其包括Al / Si原子比为0.01-0.1的沸石和孔径在5-30nm范围内的中孔，以及与介孔的内壁复合的超细颗粒。 超细颗粒是选自Ti，Zr和Hf的金属的氧化物的颗粒。 具有负载在上述催化剂载体上的氢化催化剂的催化剂表现出

公开(公告)号：US20100087692A1

公开(公告)日：2010-04-08

申请号：US12531454

申请日：2008-04-14

申请人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

发明人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

IPC分类号： C07C5/32 ,  C07C5/02

CPC分类号： C10G45/44 ,  C10G9/00 ,  C10G9/14 ,  C10G45/00 ,  C10G45/52 ,  C10G45/54 ,  C10G65/04 ,  C10G69/06 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2400/20 ,  C10G2400/30

摘要： The present invention provides a hydrogenation method capable of converting cracked kerosene into the raw materials for petrochemical cracking having a high thermal decomposition yield by a hydrogenation reaction. The present invention is a petrochemical process for producing at least any of ethylene, propylene, butane, benzene or toluene by carrying out a thermal decomposition reaction at least using naphtha for the main raw material, wherein cracked kerosene produced from a thermal cracking furnace is hydrogenated using a Pd or Pt catalyst in a two-stage method consisting of a first stage (I), in which a hydrogenation reaction is carried out within the range of 50 to 180° C., and a second stage (II), in which a hydrogenation reaction is carried out within the range of 230 to 350° C., followed by re-supplying all or a portion of these hydrogenated hydrocarbons to a thermal cracking furnace.

摘要翻译： 本发明提供一种氢化方法，其能够将裂解的煤油转化为通过氢化反应具有高热分解产率的石化裂化原料。 本发明是通过对主要原料至少使用石脑油进行热分解反应来制造乙烯，丙烯，丁烷，苯或甲苯中的至少任一种的石油化学方法，其中由热裂解炉生产的裂解煤油被氢化 使用由第一阶段（I）组成的两阶段方法的Pd或Pt催化剂，其中氢化反应在50至180℃的范围内进行，第二阶段（II），其中 氢化反应在230〜350℃的范围内进行，然后将全部或部分氢化烃再供给热裂解炉。