公开(公告)号：US20100087692A1

公开(公告)日：2010-04-08

申请号：US12531454

申请日：2008-04-14

申请人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

发明人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

IPC分类号： C07C5/32 ,  C07C5/02

CPC分类号： C10G45/44 ,  C10G9/00 ,  C10G9/14 ,  C10G45/00 ,  C10G45/52 ,  C10G45/54 ,  C10G65/04 ,  C10G69/06 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2400/20 ,  C10G2400/30

摘要： The present invention provides a hydrogenation method capable of converting cracked kerosene into the raw materials for petrochemical cracking having a high thermal decomposition yield by a hydrogenation reaction. The present invention is a petrochemical process for producing at least any of ethylene, propylene, butane, benzene or toluene by carrying out a thermal decomposition reaction at least using naphtha for the main raw material, wherein cracked kerosene produced from a thermal cracking furnace is hydrogenated using a Pd or Pt catalyst in a two-stage method consisting of a first stage (I), in which a hydrogenation reaction is carried out within the range of 50 to 180° C., and a second stage (II), in which a hydrogenation reaction is carried out within the range of 230 to 350° C., followed by re-supplying all or a portion of these hydrogenated hydrocarbons to a thermal cracking furnace.

摘要翻译： 本发明提供一种氢化方法，其能够将裂解的煤油转化为通过氢化反应具有高热分解产率的石化裂化原料。 本发明是通过对主要原料至少使用石脑油进行热分解反应来制造乙烯，丙烯，丁烷，苯或甲苯中的至少任一种的石油化学方法，其中由热裂解炉生产的裂解煤油被氢化 使用由第一阶段（I）组成的两阶段方法的Pd或Pt催化剂，其中氢化反应在50至180℃的范围内进行，第二阶段（II），其中 氢化反应在230〜350℃的范围内进行，然后将全部或部分氢化烃再供给热裂解炉。

公开(公告)号：US5852214A

公开(公告)日：1998-12-22

申请号：US832667

申请日：1997-04-04

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Etsuko Mitarai

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Etsuko Mitarai

IPC分类号： C07C231/12 ,  C07C233/05

CPC分类号： C07C231/12

摘要： A process for producing N-(1-alkoxyethyl)carboxylic amides by reacting alcohols of 1-5 carbon atoms with N-vinylcarboxylic amides in the presence of an acidic catalyst, or by utilizing unreacted starting material, unreacted intermediate or unrecovered product for synthesis of N-(1-alkoxyethyl)carboxylic amides. A process for producing N-(1-alkoxyethyl)carboxylic amides by adding a water-soluble strong acid during reaction between a carboxylic amide and a starting material containing acetaldehyde and alcohol and/or a starting material containing an acetal, in an amount of 2.times.10.sup.-3 to 3.times.10.sup.-1 equivalents to 1 mole of the carboxylic amide in the starting material, and using a strongly acidic ion-exchange resin as the catalyst.

摘要翻译： 通过使1-5个碳原子的醇与N-乙烯基羧酸酰胺在酸性催化剂的存在下反应或通过利用未反应的起始原料，未反应的中间体或未回收的产物合成来制备N-（1-烷氧基乙基） N-（1-烷氧基乙基）羧酰胺。 通过在羧酸酰胺和含有乙醛和醇的起始原料之间的反应过程中加入水溶性强酸和/或含有缩醛的起始材料，以2x10的量加入N-（1-烷氧基乙基）羧酰胺的方法 3〜3×10 -1当量，并使用强酸性离子交换树脂作为催化剂。

公开(公告)号：US6072084A

公开(公告)日：2000-06-06

申请号：US203745

申请日：1998-12-02

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

IPC分类号： C07C231/12 ,  C07C231/24 ,  C07C233/05 ,  C08F26/02

CPC分类号： C08F26/02 ,  C07C231/12 ,  C07C231/24 ,  C07C233/05

摘要： A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinylcarboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinylcarboxylic acid amide content of the N-(1-alkoxyethyl)carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.

摘要翻译： 具有30ppm以下的N-1,3-丁二烯基羧酸酰胺含量的高度可聚合的N-乙烯基羧酸酰胺及其制造方法，以及N-乙烯基羧酸酰胺的均聚物的制造方法或其共聚物 与另一种使用其的可共聚单体。 此外，通过N-（1-烷氧基乙基）羧酸酰胺或亚乙基双二羧酸酰胺的热裂解或催化裂解制备高度可聚合的N-乙烯基羧酸酰胺，其中N-（1-烷氧基乙酰基） ）羧酸酰胺或亚乙基双羧酸酰胺为10重量％以下。

公开(公告)号：US6166253A

公开(公告)日：2000-12-26

申请号：US151307

申请日：1998-09-11

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Etsuko Mitarai

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Etsuko Mitarai

IPC分类号： C07C231/12 ,  C07C233/05

CPC分类号： C07C231/12

摘要： A process for producing N-(1-alkoxyethyl)carboxylic amides by reacting alcohols of 1-5 carbon atoms with N-vinylcarboxylic amides in the presence of an acidic catalyst, or by utilizing unreacted starting material, unreacted intermediate or unrecovered product for synthesis of N-(1-alkoxyethyl)carboxylic amides. A process for producing N-(1-alkoxyethyl)carboxylic amides by adding a water-soluble strong acid during reaction between a carboxylic amide and a starting material containing acetaldehyde and alcohol and/or a starting material containing an acetal, in an amount of 2.times.10.sup.-3 to 3.times.10.sup.-1 equivalents to 1 mole of the carboxylic amide in the starting material, and using a strongly acidic ion-exchange resin as the catalyst.

摘要翻译： 通过使1-5个碳原子的醇与N-乙烯基羧酸酰胺在酸性催化剂的存在下反应或通过利用未反应的起始原料，未反应的中间体或未回收的产物合成来制备N-（1-烷氧基乙基） N-（1-烷氧基乙基）羧酰胺。 通过在羧酸酰胺和含有乙醛和醇的起始原料之间的反应过程中加入水溶性强酸和/或含有缩醛的起始材料，以2x10的量加入N-（1-烷氧基乙基）羧酰胺的方法 3〜3×10 -1当量，并使用强酸性离子交换树脂作为催化剂。

公开(公告)号：US5455042A

公开(公告)日：1995-10-03

申请号：US250453

申请日：1994-05-27

申请人： Yasuyuki Sakai ,  Noriyuki Suzuki ,  Tetsuo Kudo ,  Kuniomi Marumo ,  Toshiyuki Aizawa ,  Kunio Imamura ,  Shuichi Sugita ,  Kazuo Kanbayashi

发明人： Yasuyuki Sakai ,  Noriyuki Suzuki ,  Tetsuo Kudo ,  Kuniomi Marumo ,  Toshiyuki Aizawa ,  Kunio Imamura ,  Shuichi Sugita ,  Kazuo Kanbayashi

IPC分类号： A61K9/06 ,  A61K9/00 ,  A61K9/70 ,  A61K47/32 ,  A61L15/58

CPC分类号： A61K9/7053 ,  A61K47/32 ,  A61K9/0014 ,  A61K9/7023 ,  A61K9/7061

摘要： The subject invention relates to an ointment comprising a homogeneous mixture of polymer or copolymer of N-vinylacetamide, as an essential component, water and/or alcohols, and a pharmacologically active component. The ointment may be coated or plastered onto the skin or mucosa of a human being or animal in order to effect a therapeutic response.

摘要翻译： 本发明涉及一种软膏剂，其包含N-乙烯基乙酰胺作为必要成分的聚合物或共聚物的均匀混合物，水和/或醇，以及药理活性成分。 软膏可以涂覆或涂抹在人或动物的皮肤或粘膜上以实现治疗反应。

公开(公告)号：US5362918A

公开(公告)日：1994-11-08

申请号：US051280

申请日：1993-04-23

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Kunitoshi Wakabayashi ,  Tetsuo Kudo ,  Hiroyuki Hasegawa

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Kunitoshi Wakabayashi ,  Tetsuo Kudo ,  Hiroyuki Hasegawa

IPC分类号： B01D3/00 ,  C07C29/82 ,  C07C29/86 ,  C07C41/56 ,  C07C41/58 ,  B01D3/34

CPC分类号： C07C41/56 ,  B01D3/009 ,  C07C29/82 ,  C07C29/86 ,  C07C41/58 ,  Y02P20/127 ,  Y02P20/582

摘要： A process for producing acetaldehyde dimethylacetal comprising reacting acetaldehyde and methanol in the presence of an acid catalyst is disclosed, in which the reaction is carried out in a part of a rectification tower while conducting rectification to withdraw the water by-produced from the bottom of the tower and to recover a distillate containing the acetaldehyde dimethylacetal produced from the top of the tower. The distillate is subjected to azeotropic distillation in the presence of n-hexane or cyclohexane to separate methanol as an azeotrope with n-hexane or cyclohexane and a small amount of the acetaldehyde dimethylacetal and to recover high purity acetaldehyde dimethylacetal as a bottom.

摘要翻译： 公开了一种在酸催化剂存在下使乙醛和甲醇反应的方法，其中反应在精馏塔的一部分进行，同时进行精馏以从底部的副产物中回收 塔，并回收含有从塔顶产生的乙醛二甲缩醛的馏出物。 将馏出物在正己烷或环己烷的存在下进行共沸蒸馏，以与正己烷或环己烷和少量乙醛二甲缩醛共沸以分离甲醇，并回收高纯度乙醛二甲缩醛作为底部。

公开(公告)号：US5254338A

公开(公告)日：1993-10-19

申请号：US652715

申请日：1991-02-08

申请人： Yasuyuki Sakai ,  Noriyuki Suzuki ,  Tetsuo Kudo ,  Kuniomi Marumo ,  Toshiyuki Aizawa ,  Kunio Imamura ,  Shuichi Sugita ,  Kazuo Kanbayashi

发明人： Yasuyuki Sakai ,  Noriyuki Suzuki ,  Tetsuo Kudo ,  Kuniomi Marumo ,  Toshiyuki Aizawa ,  Kunio Imamura ,  Shuichi Sugita ,  Kazuo Kanbayashi

IPC分类号： A61K9/06 ,  A61K9/00 ,  A61K9/70 ,  A61K47/32 ,  A61L15/58

CPC分类号： A61K9/7053 ,  A61K47/32 ,  A61K9/0014 ,  A61K9/7023 ,  A61K9/7061

摘要： A (co)polymer suitable for bases or auxiliary agents for external application (for example, hydrophilic gels, adhesives, thickeners or excipients) to be coated or plastered onto the skin or mucosa of a human being or animal, such as ointment agents (ointment, hydrogel, jelly or cream), plastering agents (molded poultice, tape agent or plaster agent), sticky bandages (sticky bandage, strap, wound strap, surgical tape, taping material, supporter), and to preparations for external application containing same.

公开(公告)号：US06153708A

公开(公告)日：2000-11-28

申请号：US271428

申请日：1999-03-18

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

IPC分类号： C07C231/12 ,  C07C231/24 ,  C07C233/05 ,  C08F26/02 ,  C08F283/04

CPC分类号： C08F26/02 ,  C07C231/12 ,  C07C231/24 ,  C07C233/05

摘要： A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinyl-carboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinyl-carboxylic acid amide content of the N-(1-alkoxyethyl)-carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.

摘要翻译： 具有30ppm以下的N-1,3-丁二烯基羧酸酰胺含量的高度可聚合的N-乙烯基羧酸酰胺及其制造方法，以及N-乙烯基羧酸酰胺的均聚物的制造方法或其共聚物 与另一种使用其的可共聚单体。 此外，通过N-（1-烷氧基乙基）羧酸酰胺或亚乙基双二羧酸酰胺的热裂解或催化裂解制备高度可聚合的N-乙烯基 - 羧酸酰胺，其中N-乙烯基 - 羧酸酰胺的N-乙烯基 - 羧酸酰胺含量， （1-烷氧基乙基） - 羧酸酰胺或亚乙基双羧酸酰胺为10重量％以下。

公开(公告)号：US6143836A

公开(公告)日：2000-11-07

申请号：US168081

申请日：1998-10-08

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

IPC分类号： C07C231/12 ,  C07C231/24 ,  C07C233/05 ,  C08F26/02 ,  C08F283/04

CPC分类号： C08F26/02 ,  C07C231/12 ,  C07C231/24 ,  C07C233/05

摘要： A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinylcarboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinylcarboxylic acid amide content of the N-(1-alkoxyethyl)carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.

公开(公告)号：US5892115A

公开(公告)日：1999-04-06

申请号：US996819

申请日：1997-12-23

申请人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

发明人： Toshiyuki Aizawa ,  Hitoshi Nakamura ,  Tetsuo Kudo ,  Kunitoshi Wakabayashi ,  Kenji Shimamura ,  Shun-ichi Nagamatsu

IPC分类号： C07C231/12 ,  C07C231/24 ,  C07C233/05 ,  C08F26/02

CPC分类号： C08F26/02 ,  C07C231/12 ,  C07C231/24 ,  C07C233/05

摘要： A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinylcarboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinylcarboxylic acid amide content of the N-(1-alkoxyethyl)carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.