公开(公告)号：US06809055B2

公开(公告)日：2004-10-26

申请号：US09981926

申请日：2001-10-17

Applicant: Rudolf Overbeek ,  Nelleke van der Puil ,  Chuen Y. Yeh ,  Lawrence L. Murrell ,  Yun-Feng Chang ,  Philip Jay Angevine ,  Johannes Hendrik Koegler

Inventor： Rudolf Overbeek ,  Nelleke van der Puil ,  Chuen Y. Yeh ,  Lawrence L. Murrell ,  Yun-Feng Chang ,  Philip Jay Angevine ,  Johannes Hendrik Koegler

IPC: B01J2906

CPC classification number: C10G47/16 ,  B01J29/06 ,  B01J29/7007 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/08 ,  B01J2229/40 ,  B01J2229/64 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/48 ,  C07C2/66 ,  C07C2529/40 ,  C10G29/205 ,  C10G45/64 ,  C07C15/073

Abstract: An improved zeolite having a high number of strong acid sites wherein said zeolite has an AAI of at least 1.0. In a preferred embodiment, such zeolite is produced by controlling conditions after production of the crystalline structure such that loss of tetrahedral aluminum is minimized to thereby provide a zeolite with the above defined AAI.

Abstract translation: 具有大量强酸性位点的改进的沸石，其中所述沸石的AAI为至少1.0。 在优选的实施方案中，通过控制晶体结构生产后的条件来制备这种沸石，使得四面体铝的损失最小化，从而提供具有上述限定的AAI的沸石。

公开(公告)号：US06740764B1

公开(公告)日：2004-05-25

申请号：US10129826

申请日：2002-05-09

Applicant: Yi Chen ,  Weiping Ding ,  Yuan Chun ,  Ma Lian ,  Ulrich Müller

Inventor： Yi Chen ,  Weiping Ding ,  Yuan Chun ,  Ma Lian ,  Ulrich Müller

IPC: B01J2906

CPC classification number: B01J37/086 ,  B01J29/89

Abstract: Oxide comprising at least the elements Si and Ti, at least noncrystalline silicon dioxide and at least one crystalline silicate phase which has at least one zeolite structure, with noncrystalline silicon dioxide being applied to at least one crystalline silicate phase having at least one zeolite structure, wherein the oxide has no silicon-carbon bonds.

Abstract translation: 氧化物至少包含元素Si和Ti，至少非结晶二氧化硅和至少一种具有至少一种沸石结构的结晶硅酸盐相，其中非结晶二氧化硅被施加至至少一种具有至少一种沸石结构的结晶硅酸盐相， 其中所述氧化物不具有硅 - 碳键。

公开(公告)号：US06716785B2

公开(公告)日：2004-04-06

申请号：US10259140

申请日：2002-09-27

Applicant: Dennis Stamires ,  Paul O'Connor

Inventor： Dennis Stamires ,  Paul O'Connor

IPC: B01J2906

CPC classification number: B01J37/0009 ,  B01J21/16 ,  B01J23/007 ,  C01B33/40

Abstract: A process for the in-situ preparation of a composite comprising a cationic clay and binder/matrix material from sources comprising an aluminum containing source, a silicon containing source and a di-valent metal containing source comprising the steps of: a. preparing a precursor mixture by mixing the aluminum containing source, the silicon containing source and the di-valent metal containing source with seeding material, b. homogenizing the precursor mixture, and c. aging the precursor mixture to obtain the composite. One or two of the aluminum containing source, silicon containing source or di-valent metal containing source is to be in excess of the amount required for stoichiometry of the three sources with respect to the formation of the cationic clay. The excess source or sources will form the binder/matrix material of the composite. The invention also includes a body comprising a composite obtained by this process having binding/matrix material present in a discontinuous phase.

Abstract translation: 一种包含阳离子粘土和粘合剂/基体材料的复合材料的方法，所述复合材料包括含铝的源，含硅源和含二价金属的源，所述方法包括以下步骤：a。 b。通过将含铝源，含硅源和含二价金属的源与接种材料混合来制备前体混合物，b。 均化前体混合物，和c。 老化前体混合物以获得复合材料。含铝的源，含硅源或含二价金属的源中的一种或两种应超过三种源的化学计量所需的量，相对于形成 阳离子粘土。 多余的源或来源将形成复合材料的粘合剂/基体材料。 本发明还包括一种主体，其包含通过该方法获得的具有不连续相中存在的结合/基质材料的复合物。

公开(公告)号：US06716783B2

公开(公告)日：2004-04-06

申请号：US10321184

申请日：2002-12-17

Applicant: Kevin C. Ott ,  Noline C. Clark ,  Mark T. Paffett

Inventor： Kevin C. Ott ,  Noline C. Clark ,  Mark T. Paffett

IPC: B01J2906

CPC classification number: B01D53/9418 ,  B01D2251/2062 ,  B01D2251/208 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/50 ,  B01J29/06 ,  B01J29/061 ,  B01J29/072 ,  B01J29/076 ,  B01J29/68 ,  B01J29/69 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/38 ,  Y02T10/24

Abstract: The present invention provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by contacting the gas stream under conditions effective to catalytically reduce the nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, the catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.

公开(公告)号：US06712953B1

公开(公告)日：2004-03-30

申请号：US09603838

申请日：2000-10-16

Applicant: Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

Inventor： Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

IPC: B01J2906

CPC classification number: C10G47/20 ,  B01J29/076

Abstract: The invention relates to a catalyst that contains at least one matrix, at least one zeolite and at least one hydro-dehydrogenating element that is located at the matrix (deposited on the catalyst or contained in the matrix), in which the zeolite contains in its porous network at least one element of group VIB and/or group VIII. Said hydro-dehydrogenating element preferably belongs to group VIB and/or to group VIII of the periodic table. The catalyst contains at least one promoter element)phosphorus, boron, silicon). The invention also relates to the use of this catalyst for the transformation of hydrocarbon fractions, in particular hydrorefining and hydrocracking

Abstract translation: 本发明涉及一种催化剂，其含有至少一种基质，至少一种沸石和位于基质（沉积在催化剂上或包含在基质中）的至少一种氢化脱氢元素，其中沸石中含有 VIB组和/或VIII组的至少一种元素的多孔网络。 所述加氢脱氢元件优选属于元素周期表VIB族和/或VIII族。 催化剂含有至少一种助催化剂元素）磷，硼，硅）。 本发明还涉及该催化剂用于烃馏分转化，特别是加氢精制和加氢裂化的用途

公开(公告)号：US06689195B1

公开(公告)日：2004-02-10

申请号：US09936196

申请日：2002-06-20

Applicant: Marc Henri Carolina Anthonis ,  Anton-Jan Bons ,  Harry William Deckman ,  Jonas Hedlund ,  Wenyih F. Lai ,  Jacobus Anna Josephus Peters

Inventor： Marc Henri Carolina Anthonis ,  Anton-Jan Bons ,  Harry William Deckman ,  Jonas Hedlund ,  Wenyih F. Lai ,  Jacobus Anna Josephus Peters

IPC: B01J2906

CPC classification number: B01D67/0051 ,  B01D69/02 ,  B01D69/105 ,  B01D71/028 ,  B01D2323/08 ,  B01D2325/20 ,  B01J20/183 ,  B01J35/065 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2229/64

Abstract: A process is described for the manufacture of crystalline molecular sieve layers with good para-xylene over meta-xylene selectivity's good para-xylene permeances and selectivities. The process requires impregnation of the support prior to hydrothermal synthesis using the seeded method and may be undertaken with pre-impregnation masking. The crystalline molecular sieve layer has a selectivity (&agr;x) for para-xylene over meta-xylene of 2 or greater and a permeance (Qx) for para-xylene of 3.27×10−8 mole(px)/m2.s.Pa(px) or greater measured at a temperature of ≧250° C. and an aromatic hydrocarbon partial pressure of ≧10×103 Pa.

Abstract translation: 描述了制备具有良好的对二甲苯的结晶分子筛层的方法，其中间二甲苯选择性良好的对二甲苯渗透性和选择性。 该方法需要在使用接种方法的水热合成之前浸渍载体，并且可以用预浸渍掩模进行。 结晶分子筛层对二甲苯的间二甲苯选择性（alphax）为2或更大，对二甲苯的渗透率（Qx）为3.27×10 -8（mol）/ m 2。 在> = 250℃的温度和≥10×10 3 Pa的芳族烃分压下测量的s.Pa（px）或更大。

公开(公告)号：US06682650B2

公开(公告)日：2004-01-27

申请号：US09873241

申请日：2001-06-05

Applicant: Kosaku Honna ,  Yasuhiro Araki ,  Yasuo Miki ,  Hiromichi Shimada

Inventor： Kosaku Honna ,  Yasuhiro Araki ,  Yasuo Miki ,  Hiromichi Shimada

IPC: B01J2906

CPC classification number: B01J29/166 ,  B01J29/088 ,  B01J29/106 ,  B01J2229/14 ,  B01J2229/186 ,  C10G2300/107

Abstract: A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf. A catalyt having a hydrogenation catalytic metal loaded on the above catalyst support exhibits

Abstract translation: 一种催化剂载体，其包括Al / Si原子比为0.01-0.1的沸石和孔径在5-30nm范围内的中孔，以及与介孔的内壁复合的超细颗粒。 超细颗粒是选自Ti，Zr和Hf的金属的氧化物的颗粒。 具有负载在上述催化剂载体上的氢化催化剂的催化剂表现出

公开(公告)号：US06656347B2

公开(公告)日：2003-12-02

申请号：US09956250

申请日：2001-09-20

Applicant: David M. Stockwell ,  Randall P. Brown ,  Stephen H. Brown

Inventor： David M. Stockwell ,  Randall P. Brown ,  Stephen H. Brown

IPC: B01J2906

CPC classification number: C10G11/05 ,  B01J21/16 ,  B01J29/084 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1095 ,  B01J37/0045 ,  B01J37/0246 ,  B01J2229/42 ,  B01J2229/64

Abstract: Zeolite microsphere FCC catalysts having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. The catalysts are formed from microspheres containing a metakaolin and kaolin calcined through its exotherm, the latter calcined kaolin being derived from a kaolin having a high pore volume. Kaolin having a high pore volume can be a pulverized ultrafine kaolin or a kaolin which has been pulverized to have an incipient slurry point less than 57% solids.

公开(公告)号：US06635594B1

公开(公告)日：2003-10-21

申请号：US09806817

申请日：2001-04-03

Applicant: Graham John Bratton ,  Karon Doreen Buck ,  Timothy de Villiers Naylor ,  Martin Grayling Major

Inventor： Graham John Bratton ,  Karon Doreen Buck ,  Timothy de Villiers Naylor ,  Martin Grayling Major

IPC: B01J2906

CPC classification number: B01D63/066 ,  B01D71/028 ,  B01J29/06 ,  B01J37/0246

Abstract: An improved porous substrate for zeolite membranes is formed by coating the substrate with a layer of zeolite particles of a narrow particle distribution size of between 20 and 0.01 microns.

Abstract translation: 用于沸石膜的改进的多孔基材是通过用窄的颗粒分布尺寸为20至0.01微米的沸石颗粒层涂覆基材而形成的。

公开(公告)号：US06632766B2

公开(公告)日：2003-10-14

申请号：US09733693

申请日：2000-12-08

Applicant: Vladislav I. Kanazirev

Inventor： Vladislav I. Kanazirev

IPC: B01J2906

CPC classification number: B01J20/3007 ,  B01J20/041 ,  B01J20/08 ,  B01J20/183 ,  B01J20/28019 ,  B01J20/28042 ,  B01J20/30 ,  B01J20/3035 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3408 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42 ,  C07C7/13 ,  C10G70/047 ,  C10L3/12 ,  Y02C10/08

Abstract: Applicant has developed an improved adsorbent useful in removing contaminants from various hydrocarbon streams. The adsorbent contains a zeolite, an alumina and a metal component. The metal component (Madd) is present in an amount at least 10 mole % the stoichiometric amount of metal (M) (expressed as the oxide) needed to balance the negative charge of the zeolite lattice. In a specific application an adsorbent comprising zeolite X, alumina and sodium is used to purify an ethylene stream in order to remove CO2, H2S, methanol, and other S— and O— containing compounds.

Abstract translation: 申请人开发了一种改进的吸附剂，用于从各种烃流中去除污染物。 吸附剂含有沸石，氧化铝和金属组分。 金属组分（Madd）以平衡沸石晶格的负电荷所需的金属（M）（表示为氧化物）的化学计量量的至少10摩尔％的量存在。 在具体应用中，使用包含沸石X，氧化铝和钠的吸附剂来净化乙烯流，以便除去CO 2，H 2 H 2， S，甲醇和其它含S-和O-的化合物