摘要:
The porous metallic material of the present invention has an overall porosity of 80 to 99%, and a skeleton in a three dimensional network structure which is entirely composed of a sintered metal powder having a porosity of 10 to 60%. The specific surface area is very high, for example, 300 to 11000 cm.sup.2 /cm.sup.3. The porous metallic material can be reinforced by a reinforcing plate. The porous metallic material is also suitable for an electrode of an alkaline secondary battery and enables achievement of increases in the life and the amount of the active material contained therein. The porous metallic material can be produced by preparing a foamable slurry containing a metal powder, forming the foamable slurry, drying the formed product, preferably after foaming, and finally burning the dry formed product.
摘要:
The porous metallic material of the present invention has an overall porosity of 80 to 99%, and a skeleton in a three dimensional network structure which is entirely composed of a sintered metal powder having a porosity of 10 to 60%. The specific surface area is very high, for example, 300 to 11000 cm.sup.2 /cm.sup.3. The porous metallic material can be reinforced by a reinforcing plate. The porous metallic material is also suitable for an electrode of an alkaline secondary battery and enables achievement of increases in the life and the amount of the active material contained therein. The porous metallic material can be produced by preparing a foamable slurry containing a metal powder, forming the foamable slurry, drying the formed product, preferably after foaming, and finally burning the dry formed product.
摘要翻译:本发明的多孔金属材料的总孔隙率为80〜99%,三维网状结构的骨架完全由孔隙率为10〜60%的烧结金属粉末构成。 比表面积非常高,例如为300〜11000cm 2 / cm 3。 多孔金属材料可以通过加强板加强。 多孔金属材料也适用于碱性二次电池的电极,能够实现其中所含的活性物质的寿命和量的增加。 多孔金属材料可以通过制备含有金属粉末的可发泡浆料,形成可发泡浆料,干燥成形产品,优选在发泡之后,最后燃烧干成型产品来制备。
摘要:
Provided is a power generation cell for a solid electrolyte fuel cell using a lanthanum gallate solid electrolyte as a solid electrolyte, particularly a structure of a fuel electrode of the power generation cell for the solid electrolyte fuel cell. The fuel electrode is of a power generation cell for a solid electrolyte fuel cell in which particles (2) of a B-doped ceria (wherein, B represents one or two or more of Sm, La, Gd, Y and Ca) are attached to the surface of the framework of porous nickel having a framework structure in which a network is formed by mutual sintering of nickel particles (1). The ceria particles (2) are distributed with the highest density and attached around the framework structure portions (3) the sectional areas of which are made small by the mutual sintering of the nickel particles (1) to be bonded to each other.
摘要:
A solid electrolyte fuel cell having a long service life, comprising a power generating cell (4) having a fuel electrode (3) laminated on one surface of a solid electrolyte (1) and an air electrode (2) laminated on the other surface, an air electrode current collector (5) laminated in contact with the air electrode (2) of the power generating cell (4) and formed of a porous silver material or a silver-coated porous metal material, a fuel electrode current collector (6) laminated in contact with the fuel electrode (3) of the power generating cell (4), an air electrode-side separator (7) having a silver-plated layer (9) formed on its surface on the side contacting the fuel electrode current collector (5), a fuel electrode-side separator (8) laminated in contact with the fuel electrode current collector, and air supply passage (11) provided by being connected with the air electrode-side separator (7) and a fuel supply passage (10) provided by being connected with the fuel electrode-side separator (8), wherein a silver vapor supply unit is provided in the air supply passage to thereby supply silver vapor-containing air to the air electrode current collector (5).
摘要:
The present invention provides a power generation cell for a solid electrolyte fuel cell using a lanthanum gallate solid electrolyte as a solid electrolyte, particularly a structure of a fuel electrode of the power generation cell for the solid electrolyte fuel cell. The fuel electrode according to the first aspect of the present invention is a fuel electrode of a power generation cell for a solid electrolyte fuel cell in which particles (2) of a B-doped ceria (herein, B represents one or two or more of Sm, La, Gd, Y and Ca) are attached to the surface of the framework of porous nickel having a framework structure in which a network is formed by mutual sintering of nickel particles (1). The ceria particles (2) are distributed with the highest density and attached around the framework structure portions (3) the sectional areas of which are made small by the mutual sintering of the nickel particles (1) to be bonded to each other.
摘要:
An object of the present invention is to provide a solid oxide fuel cell assembled with an internal reforming mechanism stable and efficient over a long period. To achieve the object, in the present invention, a fuel-electrode layer 3 and an air-electrode layer 4 are disposed on both surfaces of a solid electrolyte layer 2; a fuel-electrode-side porous metal 6 and an air-electrode-side porous metal 7 are disposed on the outer surfaces of the fuel-electrode layer 3 and the air-electrode layer 4, respectively; and a separator 8 is disposed on each of the outer surfaces of the fuel-electrode-side porous metal 6 and the air-electrode-side porous metal 7. Then, the solid oxide fuel cell is constructed by closely adhering them all. The pores 6a in the fuel-electrode-side porous metal 6 is partially or fully filled with a hydrocarbon reforming catalyst 10, and reforming reaction is driven by the reforming catalyst 10 before a fuel gas reaches the fuel-electrode layer 3.
摘要:
A solid oxide fuel cell is formed by arranging a fuel electrode layer and an air electrode layer on both surfaces of a solid electrolyte, respectively, a fuel electrode current collector and an air electrode current collector outside the fuel electrode layer and the air electrode layer, respectively, and separators outside the fuel electrode current collector and the air electrode current collector. A fuel gas and an oxidant gas are supplied from the separators to the fuel electrode layers and the oxidant electrode layers, respectively, through the fuel electrode current collectors and the air electrode current collectors, respectively. Alternatively, indents are provided on the surface of each of the separators, which surface is in contact with one of the current collectors, to increase the dwell volume and hence the retaining time of the gas in the interior of the current collectors.
摘要:
A flat plate laminated type high-temperature fuel cell, with internal manifold structure, has a laminated body constructed by alternately laminating power generation cells (5) and separators (8), and by applying a load to the laminated body in the laminating direction to compress elements of the laminated body. Each separator (8) has a connecting section (8b) for connecting a manifold section (8a) of the separator (8) and a section (8c) at which the power generation cell (5) is located, and the connecting section (8b) has flexibility to the load. Thus, it is possible to improve adhesiveness in the power generating section of the fuel cell stack and gas seal performance in the manifold section. Further, each of separators (108) has through-holes (122) extending in the laminating direction, and a fixing rod (123) is inserted into each of the through-holes (122) for restricting movements of the separators (108) in a plane direction due to thermal strain in operation. Thus, the movements of the separators due to thermal strain under high temperature atmosphere at power generation can be restricted and damage to the power generation cells can be prevented.
摘要:
A solid oxide fuel cell is formed by arranging a fuel electrode layer and an air electrode layer on both surfaces of a solid electrolyte, respectively, a fuel electrode current collector and an air electrode current collector outside the fuel electrode layer and the air electrode layer, respectively, and separators outside the fuel electrode current collector and the air electrode current collector. In a first embodiment, a fuel gas and an oxidant gas are supplied from the separators to the fuel electrode layer and the oxidant electrode layer, respectively, through the fuel electrode current collector and the air electrode current collector, respectively. Each separator is formed by laminating a plurality of thin metal plates at least including a thin metal plate in which a first gas discharge opening is arranged in a central part and second gas discharge openings are circularly arranged in a peripheral part, and a thin metal plate with an indented surface. Gases discharged from the separators can be supplied to entire areas of the electrode layers through the current collectors, so that electric power generation can be performed.
摘要:
A solid oxide fuel cell is formed by arranging a fuel electrode layer and an air electrode layer on both surfaces of a solid electrolyte, respectively, a fuel electrode current collector and an air electrode current collector outside the fuel electrode layer and the air electrode layer, respectively, and separators outside the fuel electrode current collector and the air electrode current collector. In a first embodiment, a fuel gas and an oxidant gas are supplied from the separators to the fuel electrode layer and the oxidant electrode layer, respectively, through the fuel electrode current collector and the air electrode current collector, respectively. Each separator is formed by laminating a plurality of thin metal plates at least including a thin metal plate in which a first gas discharge opening is arranged in a central part and second gas discharge openings are circularly arranged in a peripheral part, and a thin metal plate with an indented surface. Gases discharged from the separators can be supplied to entire areas of the electrode layers through the current collectors, so that electric power generation can be performed.