公开(公告)号：US20120190791A1

公开(公告)日：2012-07-26

申请号：US13430801

申请日：2012-03-27

申请人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

发明人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

IPC分类号： C08K9/04 ,  C08L79/08

CPC分类号： C08F2/44

摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

摘要翻译： 一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

公开(公告)号：US08158243B2

公开(公告)日：2012-04-17

申请号：US13044866

申请日：2011-03-10

申请人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

发明人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

IPC分类号： B32B5/00 ,  C08K3/34 ,  C08K9/04

CPC分类号： C08F2/44

摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

公开(公告)号：US08278383B2

公开(公告)日：2012-10-02

申请号：US13430801

申请日：2012-03-27

申请人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

发明人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

IPC分类号： C08K9/04 ,  C08K3/34

CPC分类号： C08F2/44

摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

摘要翻译： 一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

公开(公告)号：US20110212314A1

公开(公告)日：2011-09-01

申请号：US13044866

申请日：2011-03-10

申请人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

发明人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

IPC分类号： B32B5/00 ,  C08J3/28 ,  C08K5/50 ,  C08K5/3417

CPC分类号： C08F2/44

摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

摘要翻译： 一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

公开(公告)号：US07928154B2

公开(公告)日：2011-04-19

申请号：US11766456

申请日：2007-06-21

申请人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

发明人： Kwok Pong Chan ,  Sarah Elizabeth Genovese ,  Erik C. Hagberg ,  David Bruce Hall ,  John Lester Maxam ,  Tara J. Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  James Mitchell White

IPC分类号： C08K9/04 ,  C08K3/34

CPC分类号： C08F2/44

摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

摘要翻译： 一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

公开(公告)号：US08426533B2

公开(公告)日：2013-04-23

申请号：US12339987

申请日：2008-12-19

申请人： Roy Ray Odle ,  Vijay Gopalakrishnan ,  Narayan Ramesh ,  Albert Santo Stella ,  Lioba Maria Kloppenburg ,  David Bruce Hall

发明人： Roy Ray Odle ,  Vijay Gopalakrishnan ,  Narayan Ramesh ,  Albert Santo Stella ,  Lioba Maria Kloppenburg ,  David Bruce Hall

IPC分类号： C08G85/00 ,  C08G73/10

CPC分类号： C08G73/1007 ,  C08G73/1064 ,  C08K5/18 ,  C08L79/08

摘要： The present invention provides a process for measuring and controlling chemical reactions that produce thermoplastic polymers by utilizing a stoichiometry correction during a reaction cycle to produce thermoplastic resins with desired properties. The thermoplastic polymer is made from at least one first monomer having a first reactive end group and at least one second monomer having a second reactive end group by reaction of the first reactive end group with the second reactive end group and has a glass transition temperature of greater than 130° C.

摘要翻译： 本发明提供了一种通过在反应循环期间利用化学计量校正来制备具有所需性质的热塑性树脂来测量和控制产生热塑性聚合物的化学反应的方法。 热塑性聚合物由具有第一反应性端基的至少一种第一单体和具有第二反应性端基的至少一种第二单体通过第一反应性端基与第二反应性端基的反应制备，并且玻璃化转变温度为 大于130℃

公开(公告)号：US20100160578A1

公开(公告)日：2010-06-24

申请号：US12339987

申请日：2008-12-19

申请人： Roy Ray Odle ,  Vijay Gopalakrishnan ,  Narayan Ramesh ,  Albert Santo Stella ,  Lioba Maria Kloppenburg ,  David Bruce Hall

发明人： Roy Ray Odle ,  Vijay Gopalakrishnan ,  Narayan Ramesh ,  Albert Santo Stella ,  Lioba Maria Kloppenburg ,  David Bruce Hall

IPC分类号： C08G85/00 ,  C08G73/10

CPC分类号： C08G73/1007 ,  C08G73/1064 ,  C08K5/18 ,  C08L79/08

摘要： The present invention provides a process for measuring and controlling chemical reactions that produce thermoplastic polymers by utilizing a stoichiometry correction during a reaction cycle to produce thermoplastic resins with desired properties. The thermoplastic polymer is made from at least one first monomer having a first reactive end group and at least one second monomer having a second reactive end group by reaction of the first reactive end group with the second reactive end group and has a glass transition temperature of greater than 130° C.

摘要翻译： 本发明提供了一种通过在反应循环期间利用化学计量校正来制备具有所需性质的热塑性树脂来测量和控制产生热塑性聚合物的化学反应的方法。 热塑性聚合物由具有第一反应性端基的至少一种第一单体和具有第二反应性端基的至少一种第二单体通过第一反应性端基与第二反应性端基的反应制备，并且玻璃化转变温度为 大于130℃

公开(公告)号：US08536298B2

公开(公告)日：2013-09-17

申请号：US11137082

申请日：2005-05-25

申请人： Philip L. Angermeier ,  Robert Edgar Colborn ,  Robert R. Gallucci ,  Paul Edward Howson ,  Tara Jane Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  John Morgan Whitney

发明人： Philip L. Angermeier ,  Robert Edgar Colborn ,  Robert R. Gallucci ,  Paul Edward Howson ,  Tara Jane Mullen ,  Roy Ray Odle ,  Albert Santo Stella ,  John Morgan Whitney

IPC分类号： C08G73/10

CPC分类号： C08G69/28 ,  C08G69/04

摘要： A process for preparing polyimide resins comprises stirring a diamine and a dianhydride in a solvent to form a slurry; heating the slurry to a temperature sufficient for the diamine and dianhydride to react wherein the temperature is below the melting point of the dianhydride, below the melting point of the diamine, or below the melting points of the dianhydride and diamine; and reacting the diamine and dianhydride to form a polyimide having sufficient molecular weight to precipitate from the solvent.

摘要翻译： 制备聚酰亚胺树脂的方法包括在溶剂中搅拌二胺和二酐以形成浆料; 将浆料加热至足以使二胺和二酐反应的温度，其中温度低于二酐的熔点，低于二胺的熔点或低于二酐和二胺的熔点; 并使二胺和二酐反应形成具有足够分子量的聚酰亚胺以从溶剂中沉淀出来。

公开(公告)号：US08134016B2

公开(公告)日：2012-03-13

申请号：US12202529

申请日：2008-09-02

申请人： Albert Santo Stella ,  David Bruce Hall

发明人： Albert Santo Stella ,  David Bruce Hall

IPC分类号： C07D405/12

CPC分类号： C07D407/12

摘要： A method for purifying dianhydrides is provided. In one aspect, purified oxybisphthalic anhydrides, intermediates useful in the preparation of polyetherimides are provided. In one embodiment, a first solution containing a dianhydride compound, a solvent, and a phase transfer catalyst is contacted with a solid inorganic adsorbent material having a total pore volume of about 0.5 milliliters/gram or greater and a cumulative pore volume distribution of about 20 percent or greater of particles having a pore diameter in a range between about 3 nanometers and about 20 nanometers. The solution containing the dianhydride compound is then separated from the solid inorganic adsorbent material to provide a purified dianhydride compound which is substantially free of the phase transfer catalyst. The purification technique is especially valuable for preparing high purity oxybisphthalic anhydrides, such as 4,4′-oxybisphthalic anhydride (4,4′-ODPA), which are substantially free of residual phase transfer catalyst.

摘要翻译： 提供了一种纯化二酸酐的方法。 在一个方面，提供了纯的氧化双邻苯二甲酸酐，可用于制备聚醚酰亚胺的中间体。 在一个实施方案中，将含有二酐化合物，溶剂和相转移催化剂的第一溶液与总孔体积为约0.5毫升/克或更大并且累积孔体积分布约为20的固体无机吸附材料接触 百分比或更大的具有在约3纳米和约20纳米之间的孔径的颗粒。 然后将含有二酐化合物的溶液与固体无机吸附材料分离，得到基本上不含相转移催化剂的纯化二酐化合物。 纯化技术对于制备基本上不含残余相转移催化剂的4,4'-氧双苯二甲酸酐（4,4'-ODPA）的高纯度羟基双苯酐具有特别的价值。

公开(公告)号：US07411032B2

公开(公告)日：2008-08-12

申请号：US11603523

申请日：2006-11-21

申请人： Albert Santo Stella ,  David Bruce Hall

发明人： Albert Santo Stella ,  David Bruce Hall

IPC分类号： C08G69/26

CPC分类号： C08G73/1007 ,  C07C51/573 ,  C08G73/1014 ,  C08G73/1028 ,  C08G73/105 ,  C07C65/24

摘要： A method for making polyetherimides is provided by reacting a high purity dianhydride with an aromatic diamine under condensation polymerization conditions. The dianhydrides employed are purified by a method comprising contacting a first solution containing a dianhydride compound, a solvent, and a phase transfer catalyst, with a solid inorganic adsorbent material having a total pore volume of about 0.5 milliliters/gram or greater and a cumulative pore volume distribution of about 20 percent or greater of particles having a pore diameter in a range between about 3 nanometers and about 20 nanometers. The solution containing the dianhydride compound is then separated from the solid inorganic adsorbent material to provide a purified dianhydride compound which is substantially free of the phase transfer catalyst. The purified dianhydrides are then condensed with aromatic diamines to provide polyetherimide compositions which are substantially free of residual phase transfer catalyst.

摘要翻译： 通过在缩聚条件下使高纯度二酐与芳族二胺反应来提供制备聚醚酰亚胺的方法。 所用的二酸酐通过包括将含有二酐化合物，溶剂和相转移催化剂的第一溶液与总孔体积为约0.5毫升/克或更大的固体无机吸附材料和累积孔 约20％或更大的孔径在约3纳米至约20纳米之间的颗粒的体积分布。 然后将含有二酐化合物的溶液与固体无机吸附材料分离，得到基本上不含相转移催化剂的纯化二酐化合物。 然后将纯化的二酸酐与芳族二胺缩合，得到基本上不含残余相转移催化剂的聚醚酰亚胺组合物。