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1.发明授权
公开(公告)号：US5997714A
公开(公告)日：1999-12-07
申请号：US739943
申请日：1996-10-30
CPC分类号： C25D11/38 , C09D5/4476
摘要： The invention provides a material coated with an organic film which exhibits excellent corrosion resistance and lacquer adhesion. The invention includes an electroconductive substrate coated with an electrolytically polymerized coating film containing chromium. Particularly, a zinc-type plated steel sheet coated with an electrolytically polymerized coating film containing chromium in accordance with the invention is well suited for application in vehicle bodies. The invention further provides a method of making a material coated with an organic film which involves forming organic coating material containing chromium on an electroconductive substrate acting as an electrode by electrolytically polymerizing an organic monomer in an electrolyte solution containing chromium. The method provides a monolithic composite structure comprising chromium compounds and an organic coating film, and avoid the problems associated with passivation after chromium plating of steel. The method of the invention can also reduce processing by two-thirds in relation to conventional methods.
摘要翻译： 本发明提供涂覆有有机膜的材料，其表现出优异的耐腐蚀性和漆粘附性。 本发明包括涂覆有包含铬的电解聚合涂膜的导电基材。 特别地，根据本发明涂覆有含铬的电解聚合涂膜的锌电镀钢板非常适用于车体。 本发明还提供一种制造涂覆有机膜的材料的方法，该方法涉及通过在含铬的电解液中电解聚合有机单体，在作为电极的导电性基体上形成含有铬的有机涂层材料。 该方法提供了包含铬化合物和有机涂膜的整体复合结构，并避免了镀铬后钝化相关的问题。 本发明的方法还可以将传统方法的处理减少三分之二。
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公开(公告)号：US5834128A
公开(公告)日：1998-11-10
申请号：US702247
申请日：1996-08-28
CPC分类号： C08G61/124 , B05D7/16 , C08G61/10 , B05D2350/65 , Y10T428/12569 , Y10T428/12799
摘要： An organic film-coated plated steel sheet is disclosed which includes a base steel sheet, a zinc-base plated layer disposed thereon, and an organic film layer formed by cathodic polymerization of one or more monomers and superposed as an outermost layer on the zinc-base plated layer. The steel is excellent in corrosion resistance, weldability, electrodeposition paintability or paint adhesion and, thus, is suitable as a rust-proof steel sheet particularly for use in automobile bodies. Also disclosed is a process for producing that steel with less production equipment and reduced cost.
摘要翻译： 公开了一种有机薄膜镀覆钢板，其包括基材钢板，设置在其上的锌基镀层，以及通过一种或多种单体的阴极聚合形成的有机薄膜层，并且在锌 - 基底镀层。 钢的耐腐蚀性，焊接性，电沉积涂饰性或涂料粘合性优异，因此适用于特别用于汽车车身的防锈钢板。 还公开了一种用较少生产设备生产该钢材并降低成本的方法。
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3.发明授权
公开(公告)号：US5273643A
公开(公告)日：1993-12-28
申请号：US46764
申请日：1993-04-13
申请人： Kazuhiro Hasegawa , Hiroki Nakamaru , Kazuo Mochizuki , Tomokatsu Katagiri , Nobuyuki Morito , Shigeo Kurokawa
发明人： Kazuhiro Hasegawa , Hiroki Nakamaru , Kazuo Mochizuki , Tomokatsu Katagiri , Nobuyuki Morito , Shigeo Kurokawa
CPC分类号： C25D3/565
摘要： The present invention provides a method of producing a zinc-chromium alloy-plated steel sheet having excellent properties such as bare corrosion resistance, corrosion resistance after coating, plating adhesiveness and weldability.The method is characterized by plating the surface of the steel sheet using an acid plating bath containing zinc ion (Zn.sup.2+) and chromium ion (Cr.sup.3+) at a molar concentration ratio of about 0.1.ltoreq.Cr.sup.3+ /(Zn.sup.3+ +Cr.sup.3+).ltoreq.0.9 in a total amount of at least about 0.5 mol/1 within the dissolution range, and about 0.1 to 30 g/1 of at least one nonionic organic additive having at least a triple bond, at a bath temperature of about 25.degree. to 70.degree. C. and a pH of about 1.0 to 4.0 with a current density of about 50 to 200 A/dm.sup.2.
摘要翻译： 本发明提供一种具有耐腐蚀性，涂层耐蚀性，电镀粘合性和焊接性等优异性能的镀锌 - 铬合金镀覆钢板的方法。 该方法的特征在于，使用含有约0.1 Cr 3+ /（Zn 3+ ++ Cr 3+）摩尔浓度的锌离子（Zn 2+）和铬离子（Cr 3+）的酸性电镀电镀钢板的表面， 在溶解范围内的总量为至少约0.5mol / l的0.9，以及约0.1至30g / l的至少一种具有至少三重键的非离子有机添加剂，在浴温为约25℃至 70℃，pH为约1.0至4.0，电流密度为约50至200A / dm 2。
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4.发明授权公开(公告)号：US07160631B2
公开(公告)日：2007-01-09
申请号：US10492311
申请日：2002-10-23
CPC分类号： C23C2/26 , C23C28/00 , Y10T428/12535 , Y10T428/12583 , Y10T428/12611 , Y10T428/12799 , Y10T428/25 , Y10T428/273
摘要： The present invention provides for a zinc-based coated steel sheet having a zinc-based coating layer and a lubricant film, which is formed on the zinc-based coating layer, containing zinc phosphate particles in an amount of 50 wt. % or more, and having substantially no reaction layer formed by reaction between the zinc-based coating and the zinc phosphate particles, and a method for the manufacture thereof. The zinc-based coated steel sheet according to the present invention has an excellent anti-peeling property, excellent frictional property, even in the non-lubricated condition which occurs at areas where the press oil film is broken, and excellent anti-galling property.
摘要翻译： 本发明提供了一种锌基涂层钢板，其具有锌基涂层和润滑剂膜，其形成在锌基涂层上，其含有50重量％的磷酸锌颗粒。 ％以上，并且基本上没有通过锌基涂层和磷酸锌颗粒之间的反应形成的反应层及其制造方法。 本发明的锌系被覆钢板，即使在压榨油膜破裂的区域发生非润滑状态，也具有优异的抗磨损性，因此具有优异的抗剥离性，优异的摩擦性。
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