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1.发明申请公开(公告)号：US20150166686A1
公开(公告)日：2015-06-18
申请号：US14348912
申请日：2012-10-19
发明人： Qingchun Liu , Zhenli Wei
CPC分类号： C08C19/02 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J2231/641 , B01J2531/822 , C08L15/005
摘要： This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.
摘要翻译： 本发明涉及基于钌或锇基络合物催化剂的新型催化剂组合物以及在这种催化剂组合物存在下选择性氢化丁腈橡胶的方法。
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2.发明申请公开(公告)号：US20140249277A1
公开(公告)日：2014-09-04
申请号：US14352077
申请日：2012-10-19
发明人： Qingchun Liu , Zhenli Wei
IPC分类号： C08C19/02
CPC分类号： C08C19/02 , B01J31/2265 , B01J31/2273 , B01J31/2278 , B01J2231/645 , B01J2531/0241 , B01J2531/821 , B01J2531/825 , C08L15/005
摘要： This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.
摘要翻译： 本发明涉及基于钌或锇基络合物催化剂的新型催化剂组合物以及在这种催化剂组合物存在下选择性氢化丁腈橡胶的方法。
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公开(公告)号：US20150119530A1
公开(公告)日：2015-04-30
申请号：US14397050
申请日：2013-04-26
发明人： Qingchun Liu , Zhenli Wei , Martin Hoch
IPC分类号： C08C19/02 , C08F236/12
CPC分类号： C08C19/02 , C08F236/12 , C08L15/005
摘要： This invention relates to a novel process for selectively hydrogenating nitrile rubbers in the presence of specific Ruthenium based complex catalysts without simultaneous molecular weight degradation by a metathetic reaction.
摘要翻译： 本发明涉及一种在特定的钌基络合物催化剂存在下选择性氢化丁腈橡胶的新方法，而不会由于瞬时反应而同时分子量降解。
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4.发明申请公开(公告)号：US20150025199A1
公开(公告)日：2015-01-22
申请号：US14352071
申请日：2012-10-19
发明人： Werner Obrecht , Sarah David , Qingchun Liu , Zhenli Wei
CPC分类号： B01J31/2295 , B01J31/0204 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J2231/543 , B01J2231/641 , B01J2231/645 , B01J2531/821 , B01J2531/825 , B01J2540/22 , B01J2540/34 , B01J2540/62 , C08C19/02 , C08C2019/09
摘要： This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts of the Grubbs-Hoveyda, Grela or Zhan type and specific co-catalysts comprising at least one vinyl group, pref. ethyl vinyl ether, and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions, preferably with a preceding metathesis step using the same complex catalyst as in the hydrogenation step.
摘要翻译： 本发明涉及基于Grubbs-Hoveyda，Grela或Zhan型的钌或锇基络合物催化剂和包含至少一种乙烯基的特定助催化剂的新型催化剂组合物。 乙基乙烯基醚，以及在这种催化剂组合物的存在下选择性氢化丁腈橡胶的方法，优选使用与氢化步骤中相同的络合催化剂的前述复分解步骤。
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公开(公告)号：US09802972B2
公开(公告)日：2017-10-31
申请号：US14896412
申请日：2014-06-06
发明人： Zhenli Wei , Qingchun Liu
CPC分类号： C07F15/0046 , B01J31/2217 , B01J31/2243 , B01J31/2273 , B01J31/2278 , B01J2231/645 , B01J2531/821 , B01J2531/825 , C07C5/03 , C07C2531/22 , C08C19/02 , C08F236/12 , C08L15/005 , C07C9/15
摘要： The present invention provides novel ruthenium or osmium based complex structures with a unique combination of ligands comprising a Schiff-base type ligand, a N-heterocyclic carbene ligand and a CO ligand which can be prepared according to two different routes involving easily accessible starting materials and which represent excellent catalysts for hydrogenating unsaturated compounds, oligomers and polymers, in particular at unforeseeably low temperatures.
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6.发明申请公开(公告)号：US20150126683A1
公开(公告)日：2015-05-07
申请号：US14352073
申请日：2012-10-19
发明人： Werner Obrecht , Sarah David , Qingchun Liu , Zhenli Wei
CPC分类号： C08C19/02 , B01J31/0204 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2278 , B01J31/2286 , B01J31/2295 , B01J31/2404 , B01J2231/543 , B01J2231/641 , B01J2231/645 , B01J2531/821 , B01J2531/825 , B01J2540/20 , B01J2540/40 , C08C2019/09
摘要： This invention relates to novel catalyst compositions based on ruthenium or osmium carbene-complex catalysts, pref. of the Grubbs-I, -II or -III type or fluorenylidene analogues thereof, and terminal olefins, pref. enol ethers such as ethyl vinyl ether (EVE or VEE) as co-catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions, pref. with a preceding metathesis step using the same complex catalyst as in the hydrogenation step.
摘要翻译： 本发明涉及基于钌或锇卡宾络合物催化剂的新型催化剂组合物， 的Grubbs-I，-II或-III型或亚芴基类似物，和末端烯烃。 烯醇醚如乙基乙烯基醚（EVE或VEE）作为助催化剂，以及在这种催化剂组合物存在下选择性氢化丁腈橡胶的方法。 使用与氢化步骤相同的复合催化剂的前述复分解步骤。
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