Abstract:
A negative electrode active material for a lithium secondary battery, including silicon oxide particles, wherein the silicon oxide has a full width at half maximum peak ranging between 2 and 6 in a particle size distribution and the silicon oxide particles have an average particle size (D50) of 1 μm to 20 μm, and a negative electrode and a lithium secondary battery comprising the same. The negative electrode active material according to the disclosure has outstanding life performance and output performance.
Abstract:
A negative electrode which satisfies a need for high energy density while allowing high-speed charging of a battery. A lithium secondary battery including the negative electrode is also provided. The negative electrode includes: a first negative electrode active material having a first core including a silicon oxide-based composite and a carbon coating layer covering the first core including a silicon oxide-based composite; and a second negative electrode active material having a second core including an artificial graphite and a carbon coating layer covering the second core.
Abstract:
Disclosed is an electrode active material for a lithium secondary battery including a first material including a carbon material, a second material of a nanostructure formed on the first material, the second material including at least one selected from a metal and a metalloid capable of reversibly alloying with lithium, and a third material present on a surface of at least one of the first material and the second material to control a side reaction with an electrolyte solution, an electrode including the electrode active material, and a lithium secondary battery having the electrode.
Abstract:
An anode active material and a method for preparing the same, wherein the anode active material has a core-shell structure having formula (MOx-Liy)-C (here, M is a metal (or metalloid), x is greater than 0 and less than 1.5, and y is greater than 0 and less than 4) and including a core part containing an alloy of a metal (or metalloid) oxide-Li (MOx-Liy) and a shell part containing a carbon material coated on a surface of the core part, wherein the shell part contains lithium in an amount less than 5 atm % in the surface and the inner portion thereof. The anode active material can provide high capacity, excellent cycle characteristics, excellent volume expansion control capability, and high initial efficiency.
Abstract:
The anode active material of the present invention comprises silicon-based particles obtained from at least one of silicon, a silicon oxide and a silicon alloy, and the silicon-based particles have a faceted shape, thereby providing high capacity and good life characteristics without causing any deterioration which has been generated in the use of conventional silicon-based particles, and eventually providing a lithium secondary battery having such characteristics.
Abstract:
The present invention relates to a method for preparing an anode active material, comprising (S1) forming a shell being a coating layer comprising a carbon material on the surface of a core comprising silicon oxide particles, to obtain a silicon oxide-carbon composite having a core-shell structure; (S2) mixing the silicon oxide-carbon composite with an oxygen-containing lithium salt, followed by heat treatment to produce a silicon oxide-lithium alloy, thereby obtaining a (SiOx-Liy)—C (0
Abstract:
A negative electrode active material for a lithium secondary battery which includes: silicon particles; and a coating layer surrounding respective silicon particles, wherein the silicon particles have a full width at half maximum (FWHM) of peak ranging from 2 to 10 in the particle diameter distribution having an average particle diameter (D50) of 1 μm to 30 μm, and the coating layer includes at least one selected from the group consisting of carbon and a polymer. A negative electrode and lithium secondary battery including the negative electrode active material are also disclosed.
Abstract:
The present disclosure relates to a negative electrode material that may be used as a negative electrode active material. The negative electrode material includes a silicon oxide material containing a metal (M)-silicate and a carbonaceous material. According to an embodiment of the present disclosure, the negative electrode material may include the silicon oxide material containing a metal (M)-silicate and the carbonaceous material mixed with each other at a predetermined ratio. The negative electrode active material according to the present disclosure comprises a composite of a carbonaceous material having a broad particle size distribution with a metal-silicate, and thus provides improved electrical conductivity and life characteristics.
Abstract:
Alloy particles for negative electrode active material are proposed, which can impart anti-oxidation property to Si-containing alloy particles, and suppress oxidation of the negative electrode active material due to electrolyte at a considerably high level. A negative electrode material of secondary battery is achieved by a negative electrode material of secondary battery which is capable of intercalating and de-intercalating lithium and which consists of alloy particles including a silicon phase, a metal phase and bismuth, in which a crystallite size of the silicon phase is 10 nm or smaller, and the metal phase includes at least one kind of metal alloying with silicon but not with lithium, and the negative electrode material includes primary particles formed at least by the silicon and the metals.
Abstract:
A negative electrode active material for a lithium secondary battery including complex particles including silicon oxide particles doped with a metal of lithium, magnesium, calcium or aluminum, a linear conductive material disposed between the doped silicon oxide particles, and a carbon-based binder that hinds the doped silicon oxide particles and the conductive material together. The carbon-based binder is a result of sintering a carbon-based precursor. A method of preparing the negative electrode active material, a negative electrode and a lithium secondary battery are also provided. The negative electrode active material according to the present disclosure is superior at least in initial efficiency and life characteristics.