-
公开(公告)号:US12100837B2
公开(公告)日:2024-09-24
申请号:US17428779
申请日:2020-10-23
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Jun Won Lee
CPC classification number: H01M4/525 , H01M4/0497 , H01M4/505 , H01M10/0525 , C01G53/006 , C01G53/50 , C01P2002/60 , C01P2004/04 , C01P2004/50 , C01P2004/54 , H01M2004/028 , Y02E60/10
Abstract: A method of preparing a positive electrode active material precursor includes: providing a transition metal-containing solution including nickel, cobalt, and manganese; and introducing the transition metal-containing solution into a reactor, adding a basic aqueous solution and an ammonium cation-containing complex-forming agent, and performing a co-precipitation reaction to prepare a transition metal hydroxide in the form of a secondary particle formed by agglomerating primary particles. The co-precipitation reaction is performed under conditions satisfying Expression 1 described in the specification, and a positive electrode active material precursor whose crystalline grain has a controlled aspect ratio. A positive electrode active material prepared using the positive electrode active material precursor, a positive electrode for a lithium secondary battery, which includes the positive electrode active material, and a lithium secondary battery are also provided.
-
公开(公告)号:US20240109789A1
公开(公告)日:2024-04-04
申请号:US18266839
申请日:2022-02-03
Applicant: LG Chem, Ltd.
Inventor: Ji Hun Jung , Hyun Ah Park , Eung Ju Lee , Min Hee Son
IPC: C01G53/00 , H01M10/052
CPC classification number: C01G53/50 , H01M10/052 , C01P2004/03 , C01P2004/45 , C01P2006/40 , C01P2006/90
Abstract: A positive electrode active material, a method of preparing the same, and a positive electrode and lithium secondary battery including the same are disclosed herein. In some embodiments, a positive electrode active material includes a lithium transition metal oxide which contains 60 mol % or more of nickel based on a total number of moles of transition metals excluding lithium in the lithium transition metal oxide, wherein the oxide is in a form of a secondary particle which is an aggregate of primary particles, wherein the lithium transition metal oxide satisfies Equation 1:
1
≤
x
y
≤
20
Wherein x is a minimum area of a rectangle including all pores having an area greater than 0.002 μm2 among closed pores distributed in the secondary particle, and y is a total sum of areas of the pores having an area greater than 0.002 μm2 among the closed pores distributed in the secondary particle.-
公开(公告)号:US12132203B2
公开(公告)日:2024-10-29
申请号:US17432606
申请日:2020-02-28
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Duck Gyun Mok
CPC classification number: H01M4/525 , C01G53/006 , H01M4/505 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2006/40 , H01M2004/021 , H01M2004/028
Abstract: A positive electrode active material precursor, a method of preparing the same, a positive electrode for a secondary battery and a lithium secondary battery which include the same are disclosed herein. In some embodiments, a method of preparing a positive electrode active material precursor includes adding a transition metal aqueous solution, an ammonium ion-containing solution, and a basic aqueous solution to an initial reaction solution, and performing a co-precipitation reaction to prepare a positive electrode active material precursor having an average particle diameter (D50) of 3 μm to 5 μm, wherein the transition metal aqueous solution including a nickel raw material, a cobalt raw material, and a manganese raw material, and wherein the initial reaction solution includes a metal additive, wherein the metal additive includes at least one element selected from the group consisting of Group 5 elements and Group 6 elements.
-
公开(公告)号:US20230081939A1
公开(公告)日:2023-03-16
申请号:US17793490
申请日:2021-01-29
Applicant: LG Chem, Ltd.
Inventor: Jin Hoo Jeong , Myung Gi Jeong , Jin Wook Ju , Ji Hun Jung , Eung Ju Lee
IPC: C01G53/00 , H01M10/052
Abstract: A positive electrode active material precursor has a hydroxide represented by Formula 1, wherein the positive electrode active material precursor is a secondary particle, in which a plurality of primary particles are aggregated, and includes crystallines in which major axes of the primary particles are arranged in a direction from a center of the secondary particle toward a surface thereof and a (001) plane of the primary particle is arranged parallel to the major axis of the primary particle. A method of preparing the positive electrode active material precursor, and a positive electrode active material prepared by using the positive electrode active material precursor are also provided.
-
公开(公告)号:US20220006084A1
公开(公告)日:2022-01-06
申请号:US17428779
申请日:2020-10-23
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Jun Won Lee
IPC: H01M4/525 , H01M10/0525 , H01M4/505 , H01M4/04
Abstract: A method of preparing a positive electrode active material precursor includes: providing a transition metal-containing solution including nickel, cobalt, and manganese; and introducing the transition metal-containing solution into a reactor, adding a basic aqueous solution and an ammonium cation-containing complex-forming agent, and performing a co-precipitation reaction to prepare a transition metal hydroxide in the form of a secondary particle formed by agglomerating primary particles. The co-precipitation reaction is performed under conditions satisfying Expression 1 described in the specification, and a positive electrode active material precursor whose crystalline grain has a controlled aspect ratio. A positive electrode active material prepared using the positive electrode active material precursor, a positive electrode for a lithium secondary battery, which includes the positive electrode active material, and a lithium secondary battery are also provided.
-
公开(公告)号:US20230402598A1
公开(公告)日:2023-12-14
申请号:US18267652
申请日:2022-02-03
Applicant: LG Chem, Ltd.
Inventor: Ji Hun Jung , Hyuck Lee , Won Sig Jung , Duck Gyun Mok
IPC: H01M4/525 , H01M4/505 , H01M4/131 , H01M10/052 , C01G53/00
CPC classification number: H01M4/525 , H01M4/505 , H01M4/131 , H01M10/052 , C01G53/50 , H01M2004/021
Abstract: A positive electrode active material, a method of preparing the same, a positive electrode and a lithium secondary battery including the same are disclosed herein. In some embodiments, a positive electrode active material including a lithium transition metal oxide which contains 60 mol % or more of nickel based on a total number of moles of transition metals excluding lithium in the lithium transition metal oxide, is in a form of a secondary particle which is an aggregate of primary particles, wherein the lithium transition metal oxide satisfies Equation 1:
2
0-
公开(公告)号:US20220190326A1
公开(公告)日:2022-06-16
申请号:US17603078
申请日:2020-05-12
Applicant: LG Chem, Ltd.
Inventor: Jun Ho Eom , Chae Jin Lim , Ji Hun Jung , Dong Joon Ahn , Duck Gyun Mok
IPC: H01M4/36 , H01M4/505 , H01M4/525 , H01M4/62 , H01M4/04 , H01M10/0525 , C01G53/00 , C08K3/22 , C08K3/14
Abstract: A positive electrode active material for a secondary battery and a method of making the same are disclosed herein. In some embodiments, a positive electrode active material includes lithium composite transition metal oxide particles including 70 mol % or more of nickel (Ni) among total metals excluding lithium, and a coating portion formed on surfaces of the lithium composite transition metal oxide particles, wherein the coating portion includes a compound including fluorine and at least one selected from the group consisting of aluminum (Al), titanium (Ti), magnesium (Mg), zirconium (Zr), tungsten (W), and strontium (Sr), wherein the positive electrode active material has a Brunauer-Emmett-Teller (BET) specific surface area is in a range of 0.1 m2/g to 0.9 m2/g, and an amount of a lithium by-product on a surface of the positive electrode active material is 0.65 wt % or less based on a total weight of the positive electrode active material.
-
公开(公告)号:US20220123298A1
公开(公告)日:2022-04-21
申请号:US17432606
申请日:2020-02-28
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Duck Gyun Mok
Abstract: A positive electrode active material precursor, a method of preparing the same, a positive electrode for a secondary battery and a lithium secondary battery which include the same are disclosed herein. In some embodiments, a method of preparing a positive electrode active material precursor includes adding a transition metal aqueous solution, an ammonium ion-containing solution, and a basic aqueous solution to an initial reaction solution, and performing a co-precipitation reaction to prepare a positive electrode active material precursor having an average particle diameter (D50) of 3 μm to 5 μm, wherein the transition metal aqueous solution including a nickel raw material, a cobalt raw material, and a manganese raw material, and wherein the initial reaction solution includes a metal additive, wherein the metal additive includes at least one element selected from the group consisting of Group 5 elements and Group 6 elements.
-
-
-
-
-
-
-