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公开(公告)号:US20220123298A1
公开(公告)日:2022-04-21
申请号:US17432606
申请日:2020-02-28
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Duck Gyun Mok
Abstract: A positive electrode active material precursor, a method of preparing the same, a positive electrode for a secondary battery and a lithium secondary battery which include the same are disclosed herein. In some embodiments, a method of preparing a positive electrode active material precursor includes adding a transition metal aqueous solution, an ammonium ion-containing solution, and a basic aqueous solution to an initial reaction solution, and performing a co-precipitation reaction to prepare a positive electrode active material precursor having an average particle diameter (D50) of 3 μm to 5 μm, wherein the transition metal aqueous solution including a nickel raw material, a cobalt raw material, and a manganese raw material, and wherein the initial reaction solution includes a metal additive, wherein the metal additive includes at least one element selected from the group consisting of Group 5 elements and Group 6 elements.
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公开(公告)号:US20220407063A1
公开(公告)日:2022-12-22
申请号:US17779244
申请日:2021-03-22
Applicant: LG Chem, Ltd.
Inventor: Hyun Uk Kim , Eung Ju Lee , Woo Hyun Kim , Sang Soon Choi , Jun Gil Kim , Gyeong Il Yoo
Abstract: A positive electrode active material precursor, a method of preparing the same, and a positive electrode active material, a positive electrode, and a lithium secondary battery prepared from the same. In some embodiments, a positive electrode active material precursor includes nickel, cobalt, and manganese, wherein the positive electrode active material precursor satisfies: Equation 1 (2.5≤C(100)/C(001)≤5.0) and Equation 2 (1.0≤C(101)/C(001)≤3.0), where C(001) is a crystalline size in a (001) plane, C(100) is a crystalline size in a (100) plane, and C(101) is a crystalline size in a (101) plane. The positive electrode active material precursor has particle growth of a (001) plane that is suppressed.
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公开(公告)号:US20240396034A1
公开(公告)日:2024-11-28
申请号:US18695112
申请日:2023-05-22
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Hyeon Hui Baek , Jong Seok Jeong , Jong Pil Kim , Won Sig Jung , Tae Young Rhee , Hwan Young Choi
Abstract: A positive electrode active material includes a lithium transition metal oxide which is in the form of a single particle and divided into a surface part and a core; and a coating part which is formed on the outer surface of the surface part and contains cobalt, wherein the surface part has a layered (R-3m) structure, and nickel included in the surface part has an average oxidation number of +2.36 to +3.00. A method for producing the positive electrode active material is also provided.
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公开(公告)号:US12132203B2
公开(公告)日:2024-10-29
申请号:US17432606
申请日:2020-02-28
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Duck Gyun Mok
CPC classification number: H01M4/525 , C01G53/006 , H01M4/505 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2006/40 , H01M2004/021 , H01M2004/028
Abstract: A positive electrode active material precursor, a method of preparing the same, a positive electrode for a secondary battery and a lithium secondary battery which include the same are disclosed herein. In some embodiments, a method of preparing a positive electrode active material precursor includes adding a transition metal aqueous solution, an ammonium ion-containing solution, and a basic aqueous solution to an initial reaction solution, and performing a co-precipitation reaction to prepare a positive electrode active material precursor having an average particle diameter (D50) of 3 μm to 5 μm, wherein the transition metal aqueous solution including a nickel raw material, a cobalt raw material, and a manganese raw material, and wherein the initial reaction solution includes a metal additive, wherein the metal additive includes at least one element selected from the group consisting of Group 5 elements and Group 6 elements.
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公开(公告)号:US20230081939A1
公开(公告)日:2023-03-16
申请号:US17793490
申请日:2021-01-29
Applicant: LG Chem, Ltd.
Inventor: Jin Hoo Jeong , Myung Gi Jeong , Jin Wook Ju , Ji Hun Jung , Eung Ju Lee
IPC: C01G53/00 , H01M10/052
Abstract: A positive electrode active material precursor has a hydroxide represented by Formula 1, wherein the positive electrode active material precursor is a secondary particle, in which a plurality of primary particles are aggregated, and includes crystallines in which major axes of the primary particles are arranged in a direction from a center of the secondary particle toward a surface thereof and a (001) plane of the primary particle is arranged parallel to the major axis of the primary particle. A method of preparing the positive electrode active material precursor, and a positive electrode active material prepared by using the positive electrode active material precursor are also provided.
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公开(公告)号:US20220006084A1
公开(公告)日:2022-01-06
申请号:US17428779
申请日:2020-10-23
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Jun Won Lee
IPC: H01M4/525 , H01M10/0525 , H01M4/505 , H01M4/04
Abstract: A method of preparing a positive electrode active material precursor includes: providing a transition metal-containing solution including nickel, cobalt, and manganese; and introducing the transition metal-containing solution into a reactor, adding a basic aqueous solution and an ammonium cation-containing complex-forming agent, and performing a co-precipitation reaction to prepare a transition metal hydroxide in the form of a secondary particle formed by agglomerating primary particles. The co-precipitation reaction is performed under conditions satisfying Expression 1 described in the specification, and a positive electrode active material precursor whose crystalline grain has a controlled aspect ratio. A positive electrode active material prepared using the positive electrode active material precursor, a positive electrode for a lithium secondary battery, which includes the positive electrode active material, and a lithium secondary battery are also provided.
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公开(公告)号:US20250046806A1
公开(公告)日:2025-02-06
申请号:US18718123
申请日:2023-05-22
Applicant: LG Chem, Ltd.
Inventor: Won Sig Jung , Jong Pil Kim , Eung Ju Lee , Tae Young Rhee , Hwan Young Choi
Abstract: A positive electrode active material in a form of a single particle is configured so that after a positive electrode, which includes a positive electrode active material layer containing 80 wt % or more of the positive electrode active material based on a total weight of the positive electrode active material layer, is rolled, a density of the positive electrode active material layer after the rolling is 2.7 g/cm3 or more. When the positive electrode active material layer is analyzed by XRD (X-ray diffraction), a ratio of an area of a (003) peak to an area of all peaks identified in a 2θ range of 10° to 90° satisfies 30% or more. Also provided is a positive electrode including the same. The positive electrode active material is capable of achieving a battery with improved initial resistance characteristics and life characteristics.
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公开(公告)号:US12100837B2
公开(公告)日:2024-09-24
申请号:US17428779
申请日:2020-10-23
Applicant: LG Chem, Ltd.
Inventor: Eung Ju Lee , Ji Hun Jung , Jun Won Lee
CPC classification number: H01M4/525 , H01M4/0497 , H01M4/505 , H01M10/0525 , C01G53/006 , C01G53/50 , C01P2002/60 , C01P2004/04 , C01P2004/50 , C01P2004/54 , H01M2004/028 , Y02E60/10
Abstract: A method of preparing a positive electrode active material precursor includes: providing a transition metal-containing solution including nickel, cobalt, and manganese; and introducing the transition metal-containing solution into a reactor, adding a basic aqueous solution and an ammonium cation-containing complex-forming agent, and performing a co-precipitation reaction to prepare a transition metal hydroxide in the form of a secondary particle formed by agglomerating primary particles. The co-precipitation reaction is performed under conditions satisfying Expression 1 described in the specification, and a positive electrode active material precursor whose crystalline grain has a controlled aspect ratio. A positive electrode active material prepared using the positive electrode active material precursor, a positive electrode for a lithium secondary battery, which includes the positive electrode active material, and a lithium secondary battery are also provided.
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公开(公告)号:US20240109789A1
公开(公告)日:2024-04-04
申请号:US18266839
申请日:2022-02-03
Applicant: LG Chem, Ltd.
Inventor: Ji Hun Jung , Hyun Ah Park , Eung Ju Lee , Min Hee Son
IPC: C01G53/00 , H01M10/052
CPC classification number: C01G53/50 , H01M10/052 , C01P2004/03 , C01P2004/45 , C01P2006/40 , C01P2006/90
Abstract: A positive electrode active material, a method of preparing the same, and a positive electrode and lithium secondary battery including the same are disclosed herein. In some embodiments, a positive electrode active material includes a lithium transition metal oxide which contains 60 mol % or more of nickel based on a total number of moles of transition metals excluding lithium in the lithium transition metal oxide, wherein the oxide is in a form of a secondary particle which is an aggregate of primary particles, wherein the lithium transition metal oxide satisfies Equation 1:
1
≤
x
y
≤
20
Wherein x is a minimum area of a rectangle including all pores having an area greater than 0.002 μm2 among closed pores distributed in the secondary particle, and y is a total sum of areas of the pores having an area greater than 0.002 μm2 among the closed pores distributed in the secondary particle.
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