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    Copolyamide
    1.
    发明授权
    Copolyamide 失效
    共聚酰胺

    公开(公告)号：US4051087A

    公开(公告)日：1977-09-27

    申请号：US687973

    申请日：1976-05-20

    申请人： Lacey E. Scoggins ,  Robert W. Campbell

    发明人： Lacey E. Scoggins ,  Robert W. Campbell

    IPC分类号： C08G69/26

    CPC分类号： C08G69/265 ,  Y10T428/31739

    摘要： Normally solid, moldable polyamides having diamine-derived structural units of the formula ##STR1## wherein each A is individually selected from the group consisting of 5-methylnonamethylene, 2,4-dimethyloctamethylene, 2,4,6-trimethylheptamethylene, and 4-isopropylheptamethylene; first diacid-derived structural units of the formula ##STR2## and second diacid-derived structural units of the formula ##STR3## wherein X is a divalent aliphatic hydrocarbon radical containing from 14 to 46 carbon atoms. Minor amounts of other polyamide-forming materials can be included in the copolyamide to provide up to 30 percent of the nitrogen atoms and up to 30 percent of the carbonyl groups. When used as adhesives, these copolyamides possess very good initial T-peel strength.

    摘要翻译： 通常为具有式“IMAGE”的具有二胺衍生的结构单元的固体可成型聚酰胺，其中每个A各自选自5-甲基亚麻基，2,4-二甲基八亚甲基，2,4,6-三甲基亚庚基和4-异丙基亚庚基 ; 具有式“IMAGE”的第一二酸衍生的结构单元和式IMAMA的第二二酸衍生的结构单元，其中X是含有14至46个碳原子的二价脂族烃基。 可以在共聚酰胺中包含少量的其它聚酰胺形成材料，以提供高达30％的氮原子和至多30％的羰基。 当用作粘合剂时，这些共聚酰胺具有非常好的初始T剥离强度。

    Producing fiber grade polyamide from terephthalic acid and 5-methyl-1,9-nonanediamine
    2.
    发明授权
    Producing fiber grade polyamide from terephthalic acid and 5-methyl-1,9-nonanediamine 失效
    由对苯二甲酸和5-甲基-1,9-壬二胺生产纤维级聚酰胺

    公开(公告)号：US4172194A

    公开(公告)日：1979-10-23

    申请号：US851328

    申请日：1977-11-14

    申请人： Lacey E. Scoggins ,  Robert W. Campbell

    发明人： Lacey E. Scoggins ,  Robert W. Campbell

    IPC分类号： C08G69/28

    CPC分类号： C08G69/28

    摘要： Terephthalic acid and a diamine, always including 5-methyl-1,9-nonanediamine, and a lower fatty acid, e.g., acetic acid, are admixed with water, the water is evaporated, the concentrated mixture is heated (100.degree.-200.degree. C., 1/2-2 hrs.); then heated further (125.degree.-295.degree. C., 1/2-3 hrs., autogenous pressure up to 150-600 psig) with venting as needed; decompressed to atmospheric pressure (1/4-2 hrs., 245.degree.-295.degree. C.); and heated (270.degree.-295.degree. C., 1/2-2 hrs.) to produce a polyamide having good acid and basic dye receptivity, inherent viscosity, melt spinning and drawing characteristics. An isomeric mixture of diamines containing 5-methyl-1,9-nonanediamine, and 2,4-dimethyl-1,8-octanediamine, 2,4,6-trimethyl-1,7-heptanediamine and/or 4-isopropyl-1,7-heptanediamine can be the starting 5-methyl-1,9-nonanediamine-furnishing material. The diamine-furnishing material contains at least one principal diamine component having the formula H.sub.2 NRNH.sub.2, where R is selected from the group consisting of 5-methylnonamethylene, 2,4-dimethyloctamethylene, 2,4,6-trimethylheptamethylene, and 4-isopropylheptamethylene, the R in the formula of at least about 50 percent of the principal diamine component molecules initially present in the reaction being 5-methylnonamethylene. Other structural units, up to about 20 mole percent, can be present in the product which preferably will be at least 90 mole percent and up to about 98 mole percent and even up to about 100 mole percent derived from the foregoing recited terephthalic acid and diamines. Such other structural units are supplied by, e.g., other diamines, other dicarboxylic acids, amino acids and lactams.

    摘要翻译： 将对苯二甲酸和二胺（总是包括5-甲基-1,9-壬二胺）和低级脂肪酸（例如乙酸）与水混合，蒸发水，将浓缩的混合物加热（100-200℃） C.，1 / 2-2小时）; 然后根据需要进一步加热（125°-295℃，1 / 2-3小时，自生压力至150-600psig） 减压至大气压（1 / 4-2小时，245℃-295℃）; 加热（270°-295℃，1 / 2-2小时），得到具有良好的酸和碱性染料接受性，特性粘度，熔融纺丝和拉伸特性的聚酰胺。 含有5-甲基-1,9-壬二胺和2,4-二甲基-1,8-辛二胺，2,4,6-三甲基-1,7-庚二胺和/或4-异丙基-1的二胺的异构体混合物 ，7-庚二胺可以是起始的5-甲基-1,9-壬二胺装饰材料。 二胺家具材料含有至少一种具有式H2NRNH2的主要二胺组分，其中R选自5-甲基亚麻醇，2,4-二甲基八亚甲基，2,4,6-三甲基亚庚基和4-异丙基亚庚基， 式中最初存在于反应中的至少约50％的主要二胺组分分子中的R为5-甲基亚麻醇。 最高约20摩尔％的其它结构单元可以存在于产物中，其优选为前述对苯二甲酸和二胺衍生的至少90摩尔％和高达约98摩尔％，甚至高达约100摩尔％ 。 这样的其它结构单元由例如其它二胺，其它二羧酸，氨基酸和内酰胺提供。

    Poly(arylene sulfide)composites and methods of production
    4.
    发明授权
    Poly(arylene sulfide)composites and methods of production 失效
    聚（亚芳基硫醚）复合材料及其生产方法

    公开(公告)号：US5286561A

    公开(公告)日：1994-02-15

    申请号：US4604

    申请日：1993-01-14

    申请人： Timothy W. Johnson ,  Lacey E. Scoggins

    发明人： Timothy W. Johnson ,  Lacey E. Scoggins

    IPC分类号： C08G75/04 ,  C08G75/02 ,  C08G75/06 ,  C08J3/20 ,  C08L81/02 ,  D02G3/00

    CPC分类号： C08J3/20 ,  C08G75/0277 ,  C08J2381/02 ,  Y10T428/2933 ,  Y10T442/2025 ,  Y10T442/2549 ,  Y10T442/2631

    摘要： The present invention provides: (a) a method for producing a poly(arylene sulfide)(PAS) resin composition: (b) a PAS resin composition produced by the inventive resin composition production method; (c) a method which utilizes the inventive PAS resin composition in the production of a continuous fiber-reinforced composite; and (d) a PAS composite produced by the inventive composite production method. The PAS resin composition produced by the inventive resin composition production method comprises a crystallizable arylene sulfide polymer and a nucleating agent. The nucleating agent is admixed with the crystallizable arylene sulfide polymer by adding said nucleating agent to the polymerization reaction system. The inventive PAS resin composition solidifies to a fine-grained crystalline morphology and is well suited for use in the production of continuous fiber-reinforced composites, molded articles, and other products.

    摘要翻译： 本发明提供：（a）聚（亚芳基硫醚）（PAS）树脂组合物的制造方法：（b）通过本发明的树脂组合物制造方法制造的PAS树脂组合物; （c）利用本发明的PAS树脂组合物生产连续纤维增强复合材料的方法; 和（d）通过本发明的复合生产方法制备的PAS复合材料。 通过本发明的树脂组合物制备方法制备的PAS树脂组合物包含可结晶的亚芳基硫醚聚合物和成核剂。 通过将所述成核剂加入到聚合反应体系中，将成核剂与可结晶的亚芳基硫醚聚合物混合。 本发明的PAS树脂组合物固化成细晶粒结晶形态，并且非常适合用于生产连续纤维增强复合材料，模塑制品和其它产品。

    Arylene sulfide polymerization; arylene sulfide polymer treated with aromatic compound having more than 2 halogen substituents; processed product thereof
    6.
    发明授权
    Arylene sulfide polymerization; arylene sulfide polymer treated with aromatic compound having more than 2 halogen substituents; processed product thereof 失效
    亚芳基硫化物聚合; 用具有多于2个卤素取代基的芳族化合物处理的亚芳基硫醚聚合物; 其加工产品

    公开(公告)号：US4656231A

    公开(公告)日：1987-04-07

    申请号：US490607

    申请日：1983-05-02

    申请人： Dale O. Tieszen ,  Lacey E. Scoggins

    发明人： Dale O. Tieszen ,  Lacey E. Scoggins

    IPC分类号： C08G75/02 ,  C08G75/14

    CPC分类号： C08G75/0231 ,  C08G75/025

    摘要： A process for the production and use of branched polymers of arylene sulfide in which (A) a reaction mixture of (1) at least one p-dihalo-benzene, (2) at least one alkali metal sulfide, (3) at least one organic amide, (4) water in an amount of about 1.0 mole to about 2.4 moles per mole of alkali metal sulfide, and (5) at least one alkali metal carboxylate is contacted under polymerization conditions for a time sufficient to form arylene sulfide polymer and the arylene sulfide polymer formed in said reaction mixture is contacted under polymerization conditions with a polyhaloaromatic compound having more than two halogen substituents per molecule for a time having a range of up to about 75 minutes before entering upon termination of the polymerization process, (B) the reaction mixture is contacted with carbon dioxide, (C) volatiles are removed from the reaction mixture, (D) arylene sulfide polymer is recovered from the reaction mixture, (E) the recovered polymer is washed, and (F) the polymer is further processed, as by molding, extruding into film or sheet, or used as a coating. An embodiment of the process in which the alkali metal sulfide is produced in situ by the reaction of an excess of alkali metal hydroxide with alkali metal hydrosulfide. An embodiment in which carbon dioxide is contacted with arylene sulfide polymer formed in the reaction mixture to stabilize the polymer. A molded object, a film, a sheet, or a coating composition that is the product of the reaction and work-up process above.

    摘要翻译： 一种制备和使用亚芳基硫醚支化聚合物的方法，其中（A）（1）至少一种对二卤代苯，（2）至少一种碱金属硫化物，（3）至少一种 有机酰胺，（4）每摩尔碱金属硫化物约1.0摩尔至约2.4摩尔量的水，和（5）至少一种碱金属羧酸盐在聚合条件下接触足以形成亚芳基硫醚聚合物的时间， 在聚合反应混合物中形成的亚芳基硫醚聚合物在聚合过程终止前进入聚合过程之前，在每分子具有多于两个卤素取代基的多卤代芳族化合物接触达一至约75分钟范围内的时间，（B） 反应混合物与二氧化碳接触，（C）从反应混合物中除去挥发物，（D）从反应混合物中回收亚芳基硫化物聚合物，（E）洗涤回收的聚合物，（F） 进一步加工奥氏体，通过成型，挤出成膜或片，或用作涂层。 通过过量碱金属氢氧化物与碱金属氢硫化物的反应原位产生碱金属硫化物的方法的一个实施方案。 二氧化碳与反应混合物中形成的亚芳基硫醚聚合物接触以稳定聚合物的实施方案。 作为上述反应和后处理工序的产物的成型体，膜，片，或涂料组合物。