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    Production processes of arylene thioether oligomer and copolymer
    6.
    发明授权
    Production processes of arylene thioether oligomer and copolymer 失效
    亚芳基硫醚低聚物和共聚物的生产工艺

    公开(公告)号：US5262517A

    公开(公告)日：1993-11-16

    申请号：US858735

    申请日：1992-03-27

    申请人： Hiroyuki Sato ,  Mitsuru Hoshino ,  Yukichika Kawakami

    发明人： Hiroyuki Sato ,  Mitsuru Hoshino ,  Yukichika Kawakami

    IPC分类号： C08G63/688 ,  C08G75/02 ,  C08G75/06 ,  C08G75/14

    CPC分类号： C08G75/0286 ,  C08G63/688

    摘要： Disclosed herein are a process for the preparation of a carboxylated arylene thioether oligomer, in which an alkali metal sulfide is caused to act on a poly(arylene thioether) so as to depolymerize the poly(arylene thioether), thereby preparing an alkali thiolate-containing oligomer, and a carboxylating agent is then caused to act on the alkali thiolate-containing oligomer, thereby forming the carboxylated arylene thioether oligomer, and a process for the production of an arylene thioether copolymer, wherein the carboxylated arylene thioether oligomer alone, which has been obtained in accordance with this preparation process, or a mixture of the carboxylated oligomer in an amount of at least 50 wt. % and another carboxylic compound in an amount less than 50 wt. % is reacted with an alkylenediol or an alkylenediol and a polyester or an alkylene diol and a lactone.

    Biaxially oriented paraphenylene sulfide block copolymer film and process for producing the same
    7.
    发明授权
    Biaxially oriented paraphenylene sulfide block copolymer film and process for producing the same 失效
    双轴取向对苯撑硫醚嵌段共聚物膜及其制备方法

    公开(公告)号：US4777228A

    公开(公告)日：1988-10-11

    申请号：US944509

    申请日：1986-12-22

    申请人： Toshiya Mizuno ,  Takao Ichii ,  Yo Iizuka

    发明人： Toshiya Mizuno ,  Takao Ichii ,  Yo Iizuka

    IPC分类号： B29C55/12 ,  C08G75/02 ,  C08J5/18 ,  C08L81/02 ,  H01B3/30 ,  H05K1/03 ,  B29C47/00 ,  B29C55/14 ,  C08G75/14

    CPC分类号： C08J5/18 ,  B29C55/12 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0245 ,  C08G75/0254 ,  C08G75/0286 ,  C08L81/02 ,  H01B3/301 ,  H05K1/0333 ,  B29K2081/00 ,  C08J2381/02 ,  Y10T428/31533

    摘要： Disclosed herein is a biaxially oriented paraphenylene sulfide block copolymer film showing a heat shrinkage of 0-2.0% at 100.degree.-220.degree. C., comprising a paraphenylene sulfide block copolymer essentially composed of recurring units (A): ##STR1## and recurring units (B): ##STR2## the molar fraction of recurring units (A) being 0.50-0.98, and having a melt viscosity (.eta.*) of 1,000-15,000 poises as measured at 310.degree. C. and shear rate of 200 sec.sup.-1, a glass transition temperature (Tg) of 20.degree.-80.degree. C., a crystalline melting point (Tm) of 250.degree.-285.degree. C. and a crystallization index (Ci) of 15-45 (measured with the non-stretched heat-treated polymer film), and a process for producing the biaxially oriented paraphenylene sulfide block copolymer film.

    摘要翻译： 本文公开了一种双轴取向的对苯撑硫化物嵌段共聚物膜，其在100-220℃下的热收缩率为0-2.0％，其包含基本上由重复单元（A）构成的对苯硫醚嵌段共聚物：重复单元 （B）：重复单元（A）的摩尔分数为0.50-0.98，在310℃下测得的熔融粘度（η值）为1,000-15,000泊，剪切速率为200秒-1 ，玻璃化转变温度（Tg）为20〜-80℃，结晶熔点（Tm）为250〜-285℃，结晶指数（Ci）为15〜45℃（用未拉伸 热处理聚合物膜）和制造双轴取向对苯撑硫嵌段共聚物膜的方法。

    Process for the modification of aromatic polymers via Friedel-Crafts reactions to produce novel polymers and the use thereof
    8.
    发明授权
    Process for the modification of aromatic polymers via Friedel-Crafts reactions to produce novel polymers and the use thereof 失效
    通过Friedel-Crafts反应改性芳族聚合物以制备新型聚合物的方法及其用途

    公开(公告)号：US4684376A

    公开(公告)日：1987-08-04

    申请号：US824128

    申请日：1986-01-30

    申请人： Elena S. Percec ,  George S. Li

    发明人： Elena S. Percec ,  George S. Li

    IPC分类号： B01D71/50 ,  B01D71/52 ,  B01D71/66 ,  C08G65/48 ,  C08G75/02 ,  B01D53/22 ,  C08L71/04

    CPC分类号： C08G75/0286 ,  B01D71/50 ,  B01D71/52 ,  B01D71/66 ,  C08G65/485 ,  Y10S525/905

    摘要： A process for the addition of pendant groups to polyarylenes comprises the steps of charging a reaction vessel with a solution of a polyarylene and a Friedel-Crafts catalyst; said polyarylene having the formula ##STR1## adding to the reaction vessel a pendant forming group G, wherein G is selected from the group consisting of sulfonyl halides, sulfonamide halides, alkylhalides, acylhalides and phosphorus acid halides; heating the contents of the reaction vessel to form a substituted polyarylene having the formula ##STR2## and thereafter recovering the substituted polyarylene. The substituted polyarylenes are novel and have utility as a semipermeable membrane and a process for the separation of gases therewith is also provided.

    摘要翻译： 将侧基添加到聚亚芳基的方法包括以下步骤：用聚亚芳基和Friedel-Crafts催化剂的溶液装入反应容器; 所述具有式“IMAGE”的聚亚芳基向反应容器中加入侧基形成基团G，其中G选自磺酰卤，磺酰胺卤化物，烷基卤，酰卤和磷酰卤; 加热反应容器的内容物以形成具有式“IMAGE”的取代聚亚芳基，然后回收取代的聚亚芳基。 取代的聚亚芳基是新颖的并且可用作半透膜，并且还提供了用于分离气体的方法。

    Preparation of poly(arylene sulfide)s from poly(arylene sulfide disulfide)
    10.
    发明授权
    Preparation of poly(arylene sulfide)s from poly(arylene sulfide disulfide) 失效
    由聚（亚芳基硫醚二硫化物）制备聚（亚芳基硫醚）

    公开(公告)号：US5256742A

    公开(公告)日：1993-10-26

    申请号：US957854

    申请日：1992-10-08

    申请人： William E. Sattich ,  Owen H. Decker ,  Dwayne R. Senn ,  Darryl R. Fahey

    发明人： William E. Sattich ,  Owen H. Decker ,  Dwayne R. Senn ,  Darryl R. Fahey

    IPC分类号： C08G75/02 ,  C08G75/16

    CPC分类号： C08G75/0286 ,  C08G75/0272

    摘要： A process for preparing a poly(arylene sulfide) and copolymer thereof from a poly(arylene sulfide disulfide) is provided which comprises contacting the poly(arylene sulfide disulfide) with a polyhalo-substituted cyclic compound having unsaturation between adjacent ring carbon atoms and having halogen atoms attached to the ring carbon atoms in a polar organic compound and a basic compound at an elevated temperature. Alternatively, the poly(arylene sulfide disulfide) can be substantially dissolved in the polar organic solvent at elevated temperature to form fragments which can be contacted with the polyhalo-substituted cyclic compound in a polar organic compound and a basic compound at an elevated temperature. The fragments also can be isolated, recovered and then contacted with the polyhalo-substituted cyclic compound in a polar organic compound and a basic compound at an elevated temperature.

    摘要翻译： 提供了一种由聚（亚芳基硫醚二硫化物）制备聚（亚芳基硫醚）及其共聚物的方法，其包括使聚（亚芳基硫醚二硫化物）与相邻环碳原子之间具有不饱和键并具有卤素的多卤取代环状化合物 在极性有机化合物中与环碳原子连接的原子和升高的温度下的碱性化合物。 或者，聚（亚芳基硫醚二硫化物）可以在升高的温度下基本上溶解在极性有机溶剂中，形成可在高温下与极性有机化合物和碱性化合物中的多卤取代的环状化合物接触的片段。 片段也可以分离，回收，然后在高温下与极性有机化合物和碱性化合物中的多卤取代的环状化合物接触。