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公开(公告)号：US08048956B2
公开(公告)日：2011-11-01
申请号：US12328797
申请日：2008-12-05
CPC分类号： C08F130/04
摘要： The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.
摘要翻译： 本发明涉及使包含至少一种式I结构基团的聚芴与式II的铱（III）化合物反应的方法。本发明还涉及作为反应产物的聚芴和聚芴的用途 在光电器件中。
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公开(公告)号：US20090156783A1
公开(公告)日：2009-06-18
申请号：US11957579
申请日：2007-12-17
申请人： Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
发明人： Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
IPC分类号： C08G73/00
CPC分类号： C08G61/12 , C08G2261/142 , C08G2261/1526 , C08G2261/3142 , C08G2261/3162 , H01L51/0039 , H01L51/5012 , Y10S428/917
摘要： Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
摘要翻译： 包括至少一种衍生自式I化合物或包含至少一个式II侧基的结构单元的聚合物可用于其中R 1，R 3，R 4和R 6独立地为氢，烷基，烷氧基，氧杂烷基，烷芳基， 芳基，芳基烷基，杂芳基，取代的烷基; 取代的烷氧基，取代的氧杂烷基，取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基，取代的亚烷基，氧杂亚烷基，CO或CO 2; R2a是亚烷基; R5各自独立地为氢，烷基，烷基芳基，芳基，芳基烷基，烷氧基，羧基，取代的烷基; 取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的烷氧基，X是卤素，三氟甲磺酸酯，-B（OR1a）2，或位于2,5-或2,7-位; 苯基吡啶，苯并噻吩并吡啶，二苯并喹嗪，芴基吡啶，酮吡咯，2-（1-萘基）苯并恶唑）），2-苯基苯并恶唑，2-苯基苯并噻唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基 - 2-苯基吡啶，噻吩基吡啶，苯基亚胺，乙烯基吡啶，吡啶基萘，吡啶基吡咯，吡啶基咪唑，苯基吲哚，其衍生物或其组合。
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公开(公告)号：US08053536B2
公开(公告)日：2011-11-08
申请号：US12328805
申请日：2008-12-05
CPC分类号： C08G61/02 , C08G2261/1412 , C08G2261/1424 , C08G2261/143 , C08G2261/148 , C08G2261/1526 , C08G2261/5242 , C08G2261/95 , C09K11/06 , C09K2211/185 , H01L51/0039 , H01L51/0085 , H05B33/14
摘要： The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II wherein R1 and R2 are independently alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R5is H or CHO; R3 and R4 are independently hydrogen, alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R11 and R12 taken together form a substituted or unsubstituted monocyclic or bicyclic heteroaromatic ring; R13 is independently at each occurrence halo, nitro, hydroxy, amino, alkyl, aryl, arylalkyl, alkoxy, substituted alkoxy, substituted alkyl, substituted aryl, or substituted arylalkyl; Ar is aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a combination thereof; X is selected from a direct bond, alky, substituted alkyl, and combinations thereof; Y is CHO or NH2; Z is CHO or NH2 where Z does not equal Y; and p is 0, 1 or 2. The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.
摘要翻译： 本发明涉及包括使包含至少一个式I结构基团的聚芴与式II的铱（III）化合物反应的方法，其中R 1和R 2独立地为烷基，取代的烷基，芳基，取代的芳基或其组合; R5is H或CHO; R3和R4独立地是氢，烷基，取代的烷基，芳基，取代的芳基或其组合; R11和R12一起形成取代或未取代的单环或双环杂芳环; R13各自独立地为卤素，硝基，羟基，氨基，烷基，芳基，芳基烷基，烷氧基，取代的烷氧基，取代的烷基，取代的芳基或取代的芳基烷基; Ar是芳基，杂芳基，取代的芳基，取代的杂芳基或其组合; X选自直接键，烷基，取代的烷基及其组合; Y为CHO或NH2; Z是CHO或NH2，其中Z不等于Y; 并且p为0,1或2.本发明还涉及作为反应产物的聚芴以及聚芴在光电器件中的应用。
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公开(公告)号：US20100144992A1
公开(公告)日：2010-06-10
申请号：US12328797
申请日：2008-12-05
IPC分类号： C08F130/04
CPC分类号： C08F130/04
摘要： The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.
摘要翻译： 本发明涉及使包含至少一种式I结构基团的聚芴与式II的铱（III）化合物反应的方法。本发明还涉及作为反应产物的聚芴和聚芴的用途 在光电器件中。
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公开(公告)号：US07973126B2
公开(公告)日：2011-07-05
申请号：US11957579
申请日：2007-12-17
申请人： Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
发明人： Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
CPC分类号： C08G61/12 , C08G2261/142 , C08G2261/1526 , C08G2261/3142 , C08G2261/3162 , H01L51/0039 , H01L51/5012 , Y10S428/917
摘要： Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
摘要翻译： 包括至少一种衍生自式I化合物或包含至少一个式II侧基的结构单元的聚合物可用于其中R 1，R 3，R 4和R 6独立地为氢，烷基，烷氧基，氧杂烷基，烷芳基， 芳基，芳基烷基，杂芳基，取代的烷基; 取代的烷氧基，取代的氧杂烷基，取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基，取代的亚烷基，氧杂亚烷基，CO或CO 2; R2a是亚烷基; R5各自独立地为氢，烷基，烷基芳基，芳基，芳基烷基，烷氧基，羧基，取代的烷基; 取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的烷氧基，X是卤素，三氟甲磺酸酯，-B（OR1a）2，或位于2,5-或2,7-位; 苯基吡啶，苯并噻吩并吡啶，二苯并喹嗪，芴基吡啶，酮吡咯，2-（1-萘基）苯并恶唑）），2-苯基苯并恶唑，2-苯基苯并噻唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基 - 2-苯基吡啶，噻吩基吡啶，苯基亚胺，乙烯基吡啶，吡啶基萘，吡啶基吡咯，吡啶基咪唑，苯基吲哚，其衍生物或其组合。
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公开(公告)号：US07830081B2
公开(公告)日：2010-11-09
申请号：US11748195
申请日：2007-05-14
IPC分类号： C08G77/398 , H01J1/62
摘要： Optoelectronic devices include polysiloxanes derived from hydrosilation of an organometallic compound of formula L2MZ,wherein L and Z are independently bidentate ligands; at least one of L and Z comprises alkenyl, alkenylaryl, alkenyloxy, alkenyloxyaryl, alkynyl, alkynylaryl, alkynyloxy, alkynyloxyaryl, substituted alkenyl, substituted alkenylaryl, substituted alkenyloxy, substituted alkenyloxyaryl, substituted alkynyl, substituted alkynylaryl, substituted alkynyloxy, substituted alkynyloxyaryl, acrylate, methacrylate, or a combination thereof; and M is Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Ga, Ge, In, Sn, Sb, Tl, Pd, Bi, Po, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu.
摘要翻译： 光电器件包括衍生自式L2MZ的有机金属化合物的氢化硅石的聚硅氧烷，其中L和Z独立地是二齿配体; L和Z中的至少一个包括烯基，烯基芳基，烯氧基，烯基氧基芳基，炔基，炔基芳基，炔氧基，炔氧基芳基，取代的烯基，取代的烯基芳基，取代的烯氧基，取代的烯基氧基芳基，取代的炔基，取代的炔基芳基，取代的炔氧基，取代的炔氧基芳基，丙烯酸酯， 甲基丙烯酸酯或其组合; 并且M是Zr，Nb，Mo，Tc，Ru，Rh，Pd，Ag，Cd，Hf，Ta，W，Re，Os，Ir，Pt，Au，Hg，Ga，Ge，In，Sn，Sb， ，Pd，Bi，Po，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb或Lu。
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公开(公告)号：US20100144976A1
公开(公告)日：2010-06-10
申请号：US12328805
申请日：2008-12-05
IPC分类号： C08F212/32 , C08F4/72
CPC分类号： C08G61/02 , C08G2261/1412 , C08G2261/1424 , C08G2261/143 , C08G2261/148 , C08G2261/1526 , C08G2261/5242 , C08G2261/95 , C09K11/06 , C09K2211/185 , H01L51/0039 , H01L51/0085 , H05B33/14
摘要： The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II wherein R1 and R2 are independently alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R5is H or CHO; R3 and R4 are independently hydrogen, alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R11 and R12 taken together form a substituted or unsubstituted monocyclic or bicyclic heteroaromatic ring; R13 is independently at each occurrence halo, nitro, hydroxy, amino, alkyl, aryl, arylalkyl, alkoxy, substituted alkoxy, substituted alkyl, substituted aryl, or substituted arylalkyl; Ar is aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a combination thereof; X is selected from a direct bond, alky, substituted alkyl, and combinations thereof; Y is CHO or NH2; Z is CHO or NH2 where Z does not equal Y; and p is 0, 1 or 2. The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.
摘要翻译： 本发明涉及包括使包含至少一个式I结构基团的聚芴与式II的铱（III）化合物反应的方法，其中R 1和R 2独立地为烷基，取代的烷基，芳基，取代的芳基或其组合; R5is H或CHO; R3和R4独立地是氢，烷基，取代的烷基，芳基，取代的芳基或其组合; R11和R12一起形成取代或未取代的单环或双环杂芳环; R13各自独立地为卤素，硝基，羟基，氨基，烷基，芳基，芳基烷基，烷氧基，取代的烷氧基，取代的烷基，取代的芳基或取代的芳基烷基; Ar是芳基，杂芳基，取代的芳基，取代的杂芳基或其组合; X选自直接键，烷基，取代的烷基及其组合; Y为CHO或NH2; Z是CHO或NH2，其中Z不等于Y; 并且p为0,1或2.本发明还涉及作为反应产物的聚芴以及聚芴在光电器件中的应用。
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公开(公告)号：US07718087B2
公开(公告)日：2010-05-18
申请号：US11504552
申请日：2006-08-14
CPC分类号： C09K11/06 , C08L65/00 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型聚合有机铱化合物的组合物。 本发明的聚合有机铱组合物称为（2）型有机铱组合物，其构成为使得新型有机铱化合物的至少一种配位体的数均分子量为2000克/摩尔或更高（如 通过凝胶渗透色谱法测定）。 类型（2）有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面，本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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公开(公告)号：US20080026496A1
公开(公告)日：2008-01-31
申请号：US11637582
申请日：2006-12-12
申请人： Joseph John Shiang , Kevin Henry Janora , Gautam Parthasarathy , James Anthony Cella , Kelly Scott Chichak
发明人： Joseph John Shiang , Kevin Henry Janora , Gautam Parthasarathy , James Anthony Cella , Kelly Scott Chichak
CPC分类号： H01L51/0043 , H01L51/0003 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0085 , H01L51/56 , Y10T428/31511
摘要： The present invention provides a method for the preparation of organic light-emitting devices comprising a bilayer structure made by forming a first film layer comprising an electroactive material and an INP precursor material, and exposing the first film layer to a radiation source under an inert atmosphere to generate an interpenetrating network polymer composition comprising the electroactive material. At least one additional layer is disposed on the reacted first film layer to complete the bilayer structure. The bilayer structure is comprised within an organic light-emitting device comprising standard features such as electrodes and optionally one or more additional layers serving as a bipolar emission layer, a hole injection layer, an electron injection layer, an electron transport layer, a hole transport layer, exciton-hole transporting layer, exciton-electron transporting layer, a hole transporting emission layer, or an electron transporting emission layer.
摘要翻译： 本发明提供一种制备有机发光器件的方法，其包括通过形成包含电活性材料和INP前体材料的第一膜层制备的双层结构，并在惰性气氛下将第一膜层暴露于辐射源 以产生包含电活性材料的互穿网络聚合物组合物。 在反应的第一膜层上设置至少一个附加层以完成双层结构。 双层结构包括在包括标准特征的有机发光器件中，例如电极和可选地用作双极型发射层的一个或多个附加层，空穴注入层，电子注入层，电子传输层，空穴传输 层，激子 - 空穴传输层，激子 - 电子传输层，空穴传输发射层或电子传输发射层。
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公开(公告)号：US07695640B2
公开(公告)日：2010-04-13
申请号：US11506001
申请日：2006-08-17
CPC分类号： H05B33/14 , C08L65/00 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5016 , H01L51/5048 , H01L51/5088 , Y02E10/549 , Y10S428/917
摘要： The present invention provides novel polymer compositions comprising a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the polymeric component may be an electroactive polymer. The novel polymer compositions of the invention are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel polymer compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含聚合物组分和包含至少一种环金属配体和至少一种酮吡咯配体的新型有机铱化合物的新型聚合物组合物。 在聚合物组合物中使用的有机铱化合物被称为类型（1）有机铱组合物，并且构成为使得新的有机铱化合物的配体的数均分子量为每摩尔或更大2000克（如通过 凝胶渗透色谱）。 类型（1）有机铱组合物在本文中被称为包含“有机铱络合物”。 在一个方面，聚合物组分可以是电活性聚合物。 本发明的新型聚合物组合物可用于诸如OLED器件和光伏器件的光电子器件。 在一个方面，本发明提供了可用于制备具有增强的颜色特性和光输出效率的OLED器件的新型聚合物组合物。
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