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    Low emissivity (low-E) thin coating stacks with intermediate antidiffusion layers
    1.
    发明授权
    Low emissivity (low-E) thin coating stacks with intermediate antidiffusion layers 有权
    具有中等反扩散层的低发射率（低E）薄涂层

    公开(公告)号：US07858193B2

    公开(公告)日：2010-12-28

    申请号：US12064391

    申请日：2006-08-10

    申请人： Lars Ihlo ,  Uwe Schmidt ,  Ralf Comtesse ,  Heinz Schicht

    发明人： Lars Ihlo ,  Uwe Schmidt ,  Ralf Comtesse ,  Heinz Schicht

    IPC分类号： B32B17/06

    CPC分类号： C03C17/36 ,  C03C17/3618 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C2217/73 ,  C03C2217/948 ,  Y10T428/265

    摘要： In a heat-resistant low-emissivity (low-E) multilayer system that includes a silver layer as functional layer, for transparent substrates, in particular for window panes, which has, between the surface of the substrate and the silver layer, a high-refringence layer, in particular made of TiO2, Nb2O5 or TiNbOx, and, immediately below the silver layer, a layer essentially consisting of ZnO, a mixed oxide layer with a thickness of at least 0.5 nm, made of NiCrOx or InSnOx (ITO) that serves as antiscattering layer is placed between the high-refringence layer and the ZnO layer.

    摘要翻译： 在包括银层作为功能层的耐热低发射率（low-E）多层系统中，对于透明基板，特别是用于窗玻璃，其在基板的表面和银层之间具有高的 特别是由TiO 2，Nb 2 O 5或TiNbO x制成，并且在银层的正下方，由NiCrOx或InSnOx（ITO）制成的基本上由ZnO组成的厚度为至少0.5nm的混合氧化物层的层， 用作防灰层的高折射层和ZnO层之间。

    LOW EMISSIVITY (LOW-E) THIN COATING STACKS WITH INTERMEDIATE ANTIDIFFUSION LAYERS
    2.
    发明申请
    LOW EMISSIVITY (LOW-E) THIN COATING STACKS WITH INTERMEDIATE ANTIDIFFUSION LAYERS 有权
    低电感（LOW-E）薄涂层与中间抗反射层

    公开(公告)号：US20090186213A1

    公开(公告)日：2009-07-23

    申请号：US12064391

    申请日：2006-08-10

    申请人： Lars Ihlo ,  Uwe Schmidt ,  Ralf Comtesse ,  Schicht Heinz

    发明人： Lars Ihlo ,  Uwe Schmidt ,  Ralf Comtesse ,  Schicht Heinz

    IPC分类号： B32B17/06

    CPC分类号： C03C17/36 ,  C03C17/3618 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C2217/73 ,  C03C2217/948 ,  Y10T428/265

    摘要： In a heat-resistant low-emissivity (low-E) multilayer system that includes a silver layer as functional layer, for transparent substrates, in particular for window panes, which has, between the surface of the substrate and the silver layer, a high-refringence layer, in particular made of TiO2, Nb2O5 or TiNbOx, and, immediately below the silver layer, a layer essentially consisting of ZnO, a mixed oxide layer with a thickness of at least 0.5 nm, made of NiCrOx or InSnOx (ITO) that serves as antiscattering layer is placed between the high-refringence layer and the ZnO layer.

    摘要翻译： 在包括银层作为功能层的耐热低发射率（low-E）多层系统中，对于透明基板，特别是用于窗玻璃，其在基板的表面和银层之间具有高的 特别是由TiO 2，Nb 2 O 5或TiNbO x制成，并且在银层的正下方，由NiCrOx或InSnOx（ITO）制成的基本上由ZnO组成的厚度为至少0.5nm的混合氧化物层的层， 用作防灰层的高折射层和ZnO层之间。

    Prestressable low-E layer systems for window panes
    4.
    发明授权
    Prestressable low-E layer systems for window panes 失效
    用于窗玻璃的预应力低E层系统

    公开(公告)号：US07211328B2

    公开(公告)日：2007-05-01

    申请号：US10466523

    申请日：2002-01-23

    申请人： Heinz Schicht ,  Herbert Schindler ,  Lars Ihlo ,  Uwe Schmidt

    发明人： Heinz Schicht ,  Herbert Schindler ,  Lars Ihlo ,  Uwe Schmidt

    IPC分类号： B32B17/00

    CPC分类号： C03C17/3626 ,  C03C17/36 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/3657

    摘要： A multilayer film, capable of withstanding high thermal stresses, with silver as functional layer, a sacrificial metal layer placed on top of the silver layer and antireflection dielectric layers, has a metal nitride layer between the silver layer and the sacrificial metal layer. This metal nitride layer is composed in particular of Si3N4 and/or AlN and constitutes an effective diffusion barrier. The optical and energy properties of the silver layer consequently remain, for the most part, preserved, even after undergoing high thermal stresses (for example of the bending or toughening type when curving and/or prestressing a window pane provided with the multilayer film).

    摘要翻译： 能够耐受高热应力的多层膜，银作为功能层，置于银层和抗反射介电层顶部的牺牲金属层在银层和牺牲金属层之间具有金属氮化物层。 该金属氮化物层特别是由Si 3 N 4 N 4和/或AlN构成，构成有效的扩散阻挡层。 因此，即使在经受高热应力（例如弯曲和/或预应力提供多层膜的窗玻璃）时，银层的光学和能量特性也大部分被保留。

    Prestressable layer system for partition glass
    6.
    发明申请
    Prestressable layer system for partition glass 失效
    分隔玻璃预应力层系统

    公开(公告)号：US20060099427A1

    公开(公告)日：2006-05-11

    申请号：US10522619

    申请日：2003-08-01

    申请人： Heinz Schicht ,  Lars Ihlo ,  Uwe Schmidt ,  Herbert Schindler

    发明人： Heinz Schicht ,  Lars Ihlo ,  Uwe Schmidt ,  Herbert Schindler

    IPC分类号： B32B17/06

    CPC分类号： C03C17/3618 ,  C03C17/36 ,  C03C17/3626 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C2217/78

    摘要： A low-emissivity multilayer system, capable of being bent and prestressed, for glazing panes, with silver as functional layer, comprises a sacrificial metal layer of Ti or an alloy of Ti and Zn and/or Al placed above the silver layer, antireflection dielectric layers and an oxide, nitride or oxynitride covering layer. The sacrificial metal layer contains chemically bonded hydrogen. An optionally Al- and/or In-doped ZnO layer is adjacent to the sacrificial metal layer. The covering layer consists of a titanium compound. Multilayer systems of this type can be manufactured relatively inexpensively and have a high hardness and a high chemical resistance. Their color parameters are very reproducible, even in the case of a heat treatment at high temperature.

    摘要翻译： 具有银作为功能层的能够弯曲和预应力的低辐射多层系统包括Ti的牺牲金属层或者设置在银层上方的Ti和Zn和/或Al的合金，抗反射电介质 层和氧化物，氮化物或氧氮化物覆盖层。 牺牲金属层包含化学键合的氢。 任选的Al和/或In掺杂的ZnO层与牺牲金属层相邻。 覆盖层由钛化合物组成。 这种多层系统可以相对廉价地制造并且具有高硬度和高耐化学性。 它们的颜色参数是非常可重现的，即使在高温下进行热处理的情况下也是如此。

    Highly heat-resistant low-emissivity multilayer system for transparent substrates
    9.
    发明授权
    Highly heat-resistant low-emissivity multilayer system for transparent substrates 失效
    用于透明基板的高耐热低发射多层系统

    公开(公告)号：US08043707B2

    公开(公告)日：2011-10-25

    申请号：US12295090

    申请日：2007-03-28

    申请人： Heinz Schicht ,  Uwe Schmidt ,  Pierre-Alain Gillet

    发明人： Heinz Schicht ,  Uwe Schmidt ,  Pierre-Alain Gillet

    IPC分类号： B32B17/06

    CPC分类号： C03C17/36 ,  C03C17/3626 ,  C03C17/3652 ,  C03C17/366 ,  C03C2217/73 ,  C03C2218/154 ,  C23C14/06 ,  C23C14/086 ,  Y10T428/265 ,  Y10T428/31601

    摘要： A low-emissivity multilayer system highly resistant to heat treatment for transparent substrates, in particular for window panes comprises, starting from the substrate, at least a lower antireflection coating consisting of several partial layers and including a layer essentially consisting of ZnO which is adjacent with a silver-based functional layer, an essentially metallic blocking layer located on top of the silver-based layer, an upper antireflection coating consisting of several partial layers and a cover coating optionally consisting of several partial layers. The upper antireflection coating has: a partial layer of ZnO or a mixed oxide ZnMeOx that contains ZnO or a succession of layers of mixed oxides of the ZnO:Al/ZnMeOx type; a partial layer of Si3N4 or SixOyNz; and between these two partial layers, a separating layer with a thickness of 0.5 to 5 nm, consisting of a metal oxide or a mixed oxide with a cubic crystal lattice, which prevents direct contact between these two partial layers. Coated window panes that are highly resistant to technical handling operations comprising an inserted separating layer that makes it possible to further improve the mechanical and chemical properties of the multilayer system.

    摘要翻译： 对于透明基板，特别是用于窗玻璃的耐热处理的低发射率多层系统包括从基板开始的至少一个由几个部分层组成的下部抗反射涂层，并且包括基本上由ZnO组成的层 银基功能层，位于银基层顶部的基本上金属的阻挡层，由几个部分层组成的上部抗反射涂层和可选地由几个部分层组成的覆盖涂层。 上部抗反射涂层具有：ZnO的一部分层或含有ZnO的混合氧化物ZnMeO x或ZnO：Al / ZnMeOx类型的一系列混合氧化物层; Si3N4或SixOyNz的部分层; 并且在这两个部分层之间，由金属氧化物或具有立方晶格的混合氧化物组成的厚度为0.5至5nm的分离层，其防止这两个部分层之间的直接接触。 涂覆的窗玻璃对技术处理操作具有高度的抵抗性，包括插入的分离层，其使得可以进一步提高多层体系的机械和化学性质。

    Glass substrate provided with a thin-film stack having reflective properties in the infrared and/or in the region of solar radiation
    10.
    发明授权
    Glass substrate provided with a thin-film stack having reflective properties in the infrared and/or in the region of solar radiation 失效
    玻璃基板设置有在红外线和/或太阳辐射区域具有反射特性的薄膜叠层

    公开(公告)号：US6159621A

    公开(公告)日：2000-12-12

    申请号：US126931

    申请日：1998-07-31

    申请人： Heinz Schicht ,  Uwe Schmidt ,  Wilfried Kaiser ,  Bodo Hryniw

    发明人： Heinz Schicht ,  Uwe Schmidt ,  Wilfried Kaiser ,  Bodo Hryniw

    IPC分类号： C03C17/36 ,  B32B15/04

    CPC分类号： C03C17/3618 ,  C03C17/36 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C17/3681 ,  C03C2217/73 ,  Y10T428/12535 ,  Y10T428/12549 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/265

    摘要： The invention concerns a transparent substrate provided with a thin-film stack comprising at least one metallic film with reflective properties in the infrared, under which is disposed a first antireflection coating consisting essentially of one or more metal oxides, and an upper protective metallic film characterized in that the protective metallic film consists of an alloy of Ti, Zr or Hf with Al, Pt or Pd or an AlSi alloy.According to the invention, the second upper antireflection coating includes at least two metal oxide films, one of which is ZnO based and contains 0.1 to 10% by weight of at least one of the elements B, Si, Ga, Sm, Al, Co, Mg, Mn, Fe, Ni and/or Cr and the other is SnO.sub.2 or Bi.sub.2 O.sub.3 based, and a final, hard oxide based film.

    摘要翻译： 本发明涉及一种透明基板，其具有薄膜叠层，该薄膜叠层包括至少一种在红外线中具有反射性质的金属膜，在该基板上设置有基本上由一种或多种金属氧化物组成的第一抗反射涂层，以及上部保护性金属膜，其特征在于 因为保护金属膜由Ti，Zr或Hf与Al，Pt或Pd或AlSi合金组成。 根据本发明，第二上部抗反射涂层包括至少两个金属氧化物膜，其中一个是ZnO基的，并且含有0.1至10重量％的元素B，Si，Ga，Sm，Al，Co中的至少一种 ，Mg，Mn，Fe，Ni和/或Cr，另一种是SnO 2或Bi 2 O 3，以及最终的基于硬氧化物的膜。