摘要:
A multilayer system for the surface-coating of transparent substrates, particularly a low emission (Low-E) multilayer system for glass glazing, has at least one layer of mixed oxides produced by reactive sputtering from a metal target alloy. The layer of mixed oxides is made up of ZnO and TiO2 at at least one of the oxides Al2O3, Ga2O3 and Sb2O3. It can act as an upper and/or lower antireflection layer, as a partial layer of an antireflection layer and/or as a top coat. Such a multilayer system is characterized by a high hardness and by very good resistance to a maritime environmental.
摘要翻译:用于透明基板的表面涂覆的多层系统,特别是用于玻璃玻璃的低发射(Low-E)多层系统)具有至少一层通过来自金属靶合金的反应溅射产生的混合氧化物层。 混合氧化物层由氧化物Al 2 O 3 N,Ga 3 O 3中的至少一种由ZnO和TiO 2构成, 2 O 3和Sb 2 O 3 3。 它可以作为上部和/或下部抗反射层,作为抗反射层的部分层和/或顶涂层。 这种多层系统的特征在于高硬度和非常好的抵抗海上环境。
摘要:
A multilayer film, capable of withstanding high thermal stresses, with silver as functional layer, a sacrificial metal layer placed on top of the silver layer and antireflection dielectric layers, has a metal nitride layer between the silver layer and the sacrificial metal layer. This metal nitride layer is composed in particular of Si3N4 and/or AlN and constitutes an effective diffusion barrier. The optical and energy properties of the silver layer consequently remain, for the most part, preserved, even after undergoing high thermal stresses (for example of the bending or toughening type when curving and/or prestressing a window pane provided with the multilayer film).
摘要翻译:能够耐受高热应力的多层膜,银作为功能层,置于银层和抗反射介电层顶部的牺牲金属层在银层和牺牲金属层之间具有金属氮化物层。 该金属氮化物层特别是由Si 3 N 4 N 4和/或AlN构成,构成有效的扩散阻挡层。 因此,即使在经受高热应力(例如弯曲和/或预应力提供多层膜的窗玻璃)时,银层的光学和能量特性也大部分被保留。
摘要:
A low-emissivity multilayer system, capable of being bent and prestressed, for glazing panes, with silver as functional layer, comprises a sacrificial metal layer of Ti or an alloy of Ti and Zn and/or Al placed above the silver layer, antireflection dielectric layers and an oxide, nitride or oxynitride covering layer. The sacrificial metal layer contains chemically bonded hydrogen. An optionally Al- and/or In-doped ZnO layer is adjacent to the sacrificial metal layer. The covering layer consists of a titanium compound. Multilayer systems of this type can be manufactured relatively inexpensively and have a high hardness and a high chemical resistance. Their color parameters are very reproducible, even in the case of a heat treatment at high temperature.
摘要:
A low-emissivity multilayer system, capable of being bent and prestressed, for glazing panes, with silver as functional layer, comprises a sacrificial metal layer of Ti or an alloy of Ti and Zn and/or Al placed above the silver layer, antireflection dielectric layers and an oxide, nitride or oxynitride covering layer. The sacrificial metal layer contains chemically bonded hydrogen. An optionally Al- and/or In-doped ZnO layer is adjacent to the sacrificial metal layer. The covering layer consists of a titanium compound. Multilayer systems of this type can be manufactured relatively inexpensively and have a high hardness and a high chemical resistance. Their color parameters are very reproducible, even in the case of a heat treatment at high temperature.
摘要:
In a heat-resistant low-emissivity (low-E) multilayer system that includes a silver layer as functional layer, for transparent substrates, in particular for window panes, which has, between the surface of the substrate and the silver layer, a high-refringence layer, in particular made of TiO2, Nb2O5 or TiNbOx, and, immediately below the silver layer, a layer essentially consisting of ZnO, a mixed oxide layer with a thickness of at least 0.5 nm, made of NiCrOx or InSnOx (ITO) that serves as antiscattering layer is placed between the high-refringence layer and the ZnO layer.
摘要翻译:在包括银层作为功能层的耐热低发射率(low-E)多层系统中,对于透明基板,特别是用于窗玻璃,其在基板的表面和银层之间具有高的 特别是由TiO 2,Nb 2 O 5或TiNbO x制成,并且在银层的正下方,由NiCrOx或InSnOx(ITO)制成的基本上由ZnO组成的厚度为至少0.5nm的混合氧化物层的层, 用作防灰层的高折射层和ZnO层之间。
摘要:
A glass pane is provided with a multilayer system having metallic reflection and a high thermal resistance. The multilayer system comprises a dielectric base layer, a metal layer having a high reflection, made of chromium or a metal alloy containing at least 45 wt % chromium, and a nitride top layer. The dielectric base layer is composed of at least one oxide partial layer made of SnO2, ZnO and/or TiO2, close to the surface of the glass, and a nitride partial layer, close to the metal layer.
摘要:
A layer stack for the surface coating of transparent substrates, in particular panes of glass, has at least one metal oxide composite layer produced by reactive cathodic sputtering and contains Zn oxide and Sn oxide. Relative to the total amount of metal, this metal oxide composite layer contains from 0.5 to 6.5% by weight of one or more of the elements Al, Ga, In, B, Y, La, Ge, Si, P, As, Sb, Bi, Ce, Ti, Zr, Nb and Ta. In a layer stack which has a silver layer as a functional layer, the metal oxide composite layer may be used as an upper and/or lower antireflection layer, as a diffusion barrier layer, as a sublayer of an antireflection layer and/or as an upper cover layer.
摘要:
A layer stack for the surface coating of transparent substrates, in particular panes of glass, has at least one metal oxide composite layer produced by reactive cathodic sputtering and contains Zn oxide and Sn oxide. Relative to the total amount of metal, this metal oxide composite layer contains from 0.5 to 6.5% by weight of one or more of the elements Al, Ga, In, B, Y, La, Ge, Si, P, As, Sb, Bi, Ce, Ti, Zr, Nb and Ta. In a layer stack which has a silver layer as a functional layer, the metal oxide composite layer may be used as an upper and/or lower antireflection layer, as a diffusion barrier layer, as a sublayer of an antireflection layer and/or as an upper cover layer.
摘要:
The invention is a transparent substrate provided with a multilayer stack having thermal properties, especially solar-control or low-emissivity properties. The stack comprises at least one silver-based functional layer surrounded by at least two coatings made of dielectric material, with the presence of thin metal layers between the functional layer and at least one of the coatings made of dielectric material. A preferred stack is D1/ZnO/Ag/AlM/D2/ZnM′O, with AlM representing an aluminum alloy, ZnM′O a mixed oxide of zinc and at least one other metal, with D1 and D2 being a layer or a superposition of layers comprising at least one layer made of a metal oxide, silicon nitride, metal nitride or made of a mixed silicon/metal nitride.
摘要:
The invention relates to a transparent substrate, in particular glass substrate, provided with a thin-film stack including at least one metal film with properties in the infrared, in particular a low-emissivity one, arranged between two coatings which each include at least one anti-reflection film based on dielectric material, and at least one protective film based on a sacrificial metal or a partially or fully oxidized sacrificial metal or a sacrificial metal alloy placed between the said metal film and one of the said coatings. According to the invention, the film placed directly below and/or above the said metal film contains at least one of the noble metals Pd, Au, Ir, Pt and Rh. The low-level addition of one or more of these metals to the others, namely the film placed below and/or above the metal film, leads to an increase in the chemical stability and the hardness of the thin-film stack.