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    Plant protecting agents and methods for their use
    1.
    发明授权
    Plant protecting agents and methods for their use 失效
    植物保护剂及其使用方法

    公开(公告)号：US4160035A

    公开(公告)日：1979-07-03

    申请号：US848351

    申请日：1977-11-03

    申请人： Laszlo Levai ,  Gyula Mikite ,  Attila Kis-Tamas

    发明人： Laszlo Levai ,  Gyula Mikite ,  Attila Kis-Tamas

    IPC分类号： C07C205/42 ,  A01N9/24

    CPC分类号： C07C205/42

    摘要： A plant protecting composition with pesticidal effects contains an effective amount of at least one compound of the formula ##STR1## wherein R is a C.sub.1-20 alkyl group or a phenyl or phenyl-C.sub.1-3 alkylene group having optionally one or more C.sub.1-3 alkyl or halogen substituents on the phenyl ring, and a diluent in an amount necessary to make up the final weight of the composition. To kill plant pests, the composition is applied to growing plants either prior to or after emergence.

    摘要翻译： 具有杀虫作用的植物保护组合物含有有效量的至少一种式（I）的化合物，其中R是C 1-20烷基或具有任选一个或多个的苯基或苯基-C 1-3亚烷基 苯基环上的C 1-3烷基或卤素取代基，以及构成组合物最终重量所需量的稀释剂。 为了杀死植物害虫，组合物在出苗之前或之后施用于生长的植物。

    Nitroalkanol derivatives and plant protecting agents containing the same
    2.
    发明授权
    Nitroalkanol derivatives and plant protecting agents containing the same 失效
    硝基链烷醇衍生物和含有它们的植物保护剂

    公开(公告)号：US4469703A

    公开(公告)日：1984-09-04

    申请号：US350570

    申请日：1982-02-22

    申请人： Attila Kis-Tamas ,  Gyula Mikite ,  Erzsebet Csutak nee Jakucs ,  Laszlo Kocsis

    发明人： Attila Kis-Tamas ,  Gyula Mikite ,  Erzsebet Csutak nee Jakucs ,  Laszlo Kocsis

    IPC分类号： C07D317/52 ,  A01N37/02 ,  A01N37/10 ,  A01N37/12 ,  A01N43/06 ,  A01N43/08 ,  A01N43/30 ,  C07C67/00 ,  C07C201/00 ,  C07C205/40 ,  C07C205/42 ,  C07C205/45 ,  C07D307/42 ,  C07D307/45 ,  C07D307/70 ,  C07D317/32 ,  C07D317/54 ,  A01N37/06 ,  A01N43/16 ,  C07C67/02

    CPC分类号： C07C205/42 ,  C07C205/40

    摘要： The invention relates to nitroalkanol derivatives of the general formula (I), ##STR1## wherein R.sub.1 is a C.sub.2-12 alkenyl or alkadienyl group, a C.sub.4-12 alkoxyalkyl or alkoxyalkenyl group having one or more C.sub.1-3 alkyl substituents, a C.sub.3-6 cycloalkyl or cycloalkenyl group, a furyl group, a nitrofuryl group, or a phenyl group having optionally one or more identical or different substituents selected from the group consisting of hydroxy, C.sub.1-4 alkoxy, halogen, nitro, C.sub.1-4 alkylenedioxy and C.sub.1-4 alkenoyloxy groups,R.sub.2 and R.sub.4 each represent hydrogen or they form together a valence bond,R.sub.3 is a C.sub.1-12 alkanoyloxy group, a benzoyloxy group having optionally one or more halogen substituents or hydrogen atom, andR.sub.5 is a C.sub.1-12 alkyl group or a phenyl group having optionally one or more halogen substituents,with the proviso that if R.sub.2 and R.sub.4 each stand for hydrogen, R.sub.1 is other than unsubstituted phenyl and R.sub.3 may represent only a C.sub.1-4 alkanoyloxy group or a benzoyloxy group having optionally one or more halogen substituents, and with the further proviso that if R.sub.2 and R.sub.4 form together a valence bond and R.sub.5 is methyl, R.sub.1 is other than unsubstituted phenyl.The nitroalkenol derivatives defined above as well as the known 1-phenyl-2-nitro-3-acetoxy-propane-1 possess valuable pesticidal effects, primarily fungicidal activities, and can be applied to advantage in the agriculture as plant protecting agents.

    摘要翻译： 本发明涉及通式（I）的硝基链烷醇衍生物，其中R1是C2-12链烯基或链二烯基，具有一个或多个C 1-3烷基取代基的C 4-12烷氧基烷基或烷氧基烯基， C 3-6环烷基或环烯基，呋喃基，硝基呋喃基或具有任选一个或多个相同或不同取代基的苯基，所述取代基选自羟基，C 1-4烷氧基，卤素，硝基，C 1-4 亚烷基二氧基和C 1-4烯酰氧基，R 2和R 4各自表示氢或它们一起形成价键，R 3是C 1-12烷酰氧基，具有任选一个或多个卤素取代基或氢原子的苯甲酰氧基，R 5是C 1 -12烷基或具有任选一个或多个卤素取代基的苯基，条件是如果R 2和R 4各自代表氢，则R 1不是未取代的苯基，并且R 3可以仅表示C 1-4烷酰氧基或苯甲酰氧基 任选地一个或 更多的卤素取代基，进一步的条件是如果R 2和R 4一起形成一个价键，R 5是甲基，则R 1不是未取代的苯基。 上述硝基烯醇衍生物以及已知的1-苯基-2-硝基-3-乙酰氧基 - 丙烷-1具有有价值的杀虫作用，主要是杀真菌活性，可作为植物保护剂在农业中有利地应用。

    Terpene derivatives and insecticidal compositions containing terpenes
    3.
    发明授权
    Terpene derivatives and insecticidal compositions containing terpenes 失效
    含有萜烯的萜烯衍生物和杀虫组合物

    公开(公告)号：US4344959A

    公开(公告)日：1982-08-17

    申请号：US251043

    申请日：1981-04-06

    申请人： Lajos Novak ,  Csaba Szantay ,  Janos Rohaly ,  Attila Kis-Tamas ,  Laszlo Varjas ,  Janos Csutak

    发明人： Lajos Novak ,  Csaba Szantay ,  Janos Rohaly ,  Attila Kis-Tamas ,  Laszlo Varjas ,  Janos Csutak

    IPC分类号： C07C69/003 ,  A01N37/42 ,  A01N43/08 ,  A01N49/00 ,  C07D307/33 ,  C07D307/58 ,  A61K31/365 ,  A61K31/23 ,  C07D307/20

    CPC分类号： C07D307/33 ,  A01N49/00 ,  C07D307/58

    摘要： The invention relates to new compounds of the general formula (I), ##STR1## wherein R.sup.1 is hydrogen or a lower alkoxy group andZ.sup.1 is hydrogen, orR.sup.1 and Z.sup.1 form together a double bond,Z.sup.2 is hydrogen andB is hydroxy, orZ.sup.2 and B form together a double bond,Z.sup.3 and Z.sup.4 each stand for hydrogen or they form together an ethylene group, orZ.sup.4 and D form together a double bond,C is oxygen atom or a lower alkoxy group,D is a valence bond if C stands for oxygen, or otherwise D forms a double bond together with Z.sup.4 or Z.sup.5,Z.sup.5 forms a double bond together with D or represents hydrogen, andR.sup.2 is a group of the general formula --COOR.sup.3, wherein R.sup.3 is lower alkyl, orZ.sup.5 and R.sup.2 form together a 1-oxo-2-oxa-tetramethylene group, with the proviso that if Z.sup.3 and Z.sup.4 form together an ethylene group, R.sup.2 may stand only for a --COOR.sup.3 group,insecticidal compositions containing them, as well as to a process for their preparation.

    摘要翻译： 本发明涉及通式（I）的新化合物，其中R1是氢或低级烷氧基，Z1是氢，或R1和Z1一起形成双键，Z2是氢，B是 羟基或Z 2和B一起形成双键，Z 3和Z 4各自代表氢或它们一起形成亚乙基，或Z 4和D一起形成双键，C是氧原子或低级烷氧基，D是 如果C代表氧，则键合键，否则D与Z4或Z5一起形成双键，Z5与D一起形成双键或代表氢，R2是通式-COOR3的基团，其中R3是低级烷基 ，或Z5和R2一起形成1-氧代-2-氧杂 - 四亚甲基，条件是如果Z 3和Z 4一起形成亚乙基，则R2可以仅为-COOR 3基团，还含有它们的杀虫组合物 关于他们的准备过程。

    Process for the preparation of imidazolones
    4.
    发明授权
    Process for the preparation of imidazolones 有权
    咪唑啉酮的制备方法

    公开(公告)号：US6162923A

    公开(公告)日：2000-12-19

    申请号：US463433

    申请日：2000-04-26

    申请人： Csaba Huszar ,  Attila Kis-Tamas ,  Attila Nemeth ,  Antal Gajary ,  Lajosne Pali

    发明人： Csaba Huszar ,  Attila Kis-Tamas ,  Attila Nemeth ,  Antal Gajary ,  Lajosne Pali

    IPC分类号： C07D235/02

    CPC分类号： C07D235/02

    摘要： The present invention relates to a process for the preparation of a compound of general formula (I), ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group of 1-6 carbon atoms, and their salts, wherein the compound of formula (II): ##STR2## is reacted with a compound of formula (III): ##STR3## wherein R represents an alkyl group of 1-4 carbon atoms and R.sup.1 is the same as defined above, by heating their neutral pH mixtures at the boiling temperature of the mixture, and the resulting compound of general formula (IV): ##STR4## wherein R and R.sup.1 are the same as defined above, is cyclized into the compound of general formula (I) by further elevating the temperature of the neutral mixture, and if desired, the compounds of general formula (I) are transformed into their salts, or the compounds of general formula (I) are liberated from their salts.

    摘要翻译： PCT No.PCT / HU98 / 00065 Sec。 371日期：2000年04月26日 102（e）日期2000年4月26日PCT提交1998年7月22日PCT公布。 出版物WO99 /​​ 05118 日期1999年2月4日本发明涉及制备通式（I）化合物的方法，其中R1表示氢原子或1-6个碳原子的烷基，及其盐，其中化合物 式（II）：与式（III）化合物反应：其中R表示1-4个碳原子的烷基且R1与上述定义相同，通过在混合物的沸点温度下加热其中性pH混合物 ，并且通过进一步提高中性混合物的温度将所得到的通式（IV）化合物（其中R和R 1与上述定义相同）环化成通式（I）的化合物，如果需要，化合物 通式（I）的化合物转化为它们的盐，或者通式（I）的化合物从其盐中释放出来。

    Plant growth regulating compounds and compositions and a process for the preparation thereof
    5.
    发明授权
    Plant growth regulating compounds and compositions and a process for the preparation thereof 失效
    植物生长调节化合物和组合物及其制备方法

    公开(公告)号：US4740228A

    公开(公告)日：1988-04-26

    申请号：US569594

    申请日：1984-01-10

    申请人： Attila Kis-Tamas ,  Ferenc Jurak ,  Zoltan Vig ,  Pal Fekete ,  Judit Kulcsar

    发明人： Attila Kis-Tamas ,  Ferenc Jurak ,  Zoltan Vig ,  Pal Fekete ,  Judit Kulcsar

    IPC分类号： A01N37/18 ,  A01N37/34 ,  A01N43/46 ,  A01P21/00 ,  A47B13/04 ,  C07C67/00 ,  C07C253/00 ,  C07C255/32 ,  C07C255/35 ,  C07C255/41 ,  C07C255/56 ,  C07C255/58 ,  C07D295/10 ,  C07D295/16 ,  C07D295/18 ,  A01N37/22 ,  A01N37/20

    CPC分类号： C07C255/00 ,  A01N37/34

    摘要： The invention relates to new plant growth regulating compositions, which contain as active agent 0.001 to 95% by weight of one or more compound(s) of the general formula (I), ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen atom, a C.sub.1-5 alkyl group, a C.sub.5-7 cycloalkyl group, an aryl group, a halogen-substituted aryl group, an aralkyl group, a C.sub.2-5 alkenyl group or a C.sub.2-5 alkynyl group, orR.sup.1 and R.sup.2 form, together with the adjacent nitrogen atom, a morpholino, pyrrolidino, piperidino or perhydroazepinyl group, andR.sup.3 stands for hydrogen or a C.sub.1-5 alkyl group,together with an inert, solid, liquid and/or gaseous carrier or diluent, and optionally one or more additives, such as surfactants or other substances of plant biological activity.The compounds of the general formula (I) in which R.sup.1 is hydrogen and R.sup.2 stands for hydrogen, C.sub.1-3 alkyl, aralkyl or C.sub.3-5 alkenyl group, furthermore in which R.sup.1 and R.sup.3 are hydrogen and R.sup.2 is an aryl group have already been described in the literature, whereas the remaining derivatives of the general formula (I) are new. These compounds can be prepared by reacting a compound of the general formula (II) ##STR2## with an amine of the general formula (III), ##STR3## or by alkylating a compound of the general formula (IV). ##STR4## In the above formulae X stands for halogen, hydroxy or C.sub.1-4 alkoxy, whereas R.sup.1, R.sup.2 and R.sup.3 have the meanings as defined above.

    摘要翻译： 本发明涉及新的植物生长调节组合物，其含有0.001至95重量％的一种或多种通式（I）化合物，其中R 1和R 2各自表示氢的活性剂 原子，C1-5烷基，C5-7环烷​​基，芳基，卤素取代的芳基，芳烷基，C2-5烯基或C2-5炔基，或R1和R2形式 与相邻的氮原子一起形成吗啉代，吡咯烷子基，哌啶子基或全氢氮杂基，R3代表氢或C1-5烷基，与惰性，固体，液体和/或气态载体或稀释剂一起使用， 或更多的添加剂，例如表面活性剂或植物生物活性的其它物质。 其中R1是氢并且R2代表氢，C1-3烷基，芳烷基或C3-5烯基的通式（Ⅰ）化合物，此外R1和R3是氢，R2是芳基， 文献中描述的，而通式（I）的剩余衍生物是新的。 这些化合物可以通过使通式（II）的化合物（II）与通式（III）的胺，（IMAGE）（III）反应或通过烷基化通式（IV）的化合物 ）。 （IV）在上式中，X表示卤素，羟基或C 1-4烷氧基，而R 1，R 2和R 3具有如上定义的含义。

    Bicyclo(2.2.1)heptane oximes used for plant growth regulating
    6.
    发明授权
    Bicyclo(2.2.1)heptane oximes used for plant growth regulating 失效
    用于植物生长调节的双环（2.2.1）庚烷肟

    公开(公告)号：US4425158A

    公开(公告)日：1984-01-10

    申请号：US322675

    申请日：1981-11-18

    申请人： Zoltan Budai ,  Attila Kis-Tamas ,  Tibor Mezei ,  Aranka Lay nee Konya ,  Zoltan Vigh ,  Agnes Sokorai nee Janki

    发明人： Zoltan Budai ,  Attila Kis-Tamas ,  Tibor Mezei ,  Aranka Lay nee Konya ,  Zoltan Vigh ,  Agnes Sokorai nee Janki

    IPC分类号： A01N33/24 ,  A01N33/04 ,  A01N35/10 ,  A01P21/00 ,  C07C251/44 ,  C07C251/50

    CPC分类号： A01N35/10

    摘要： The invention relates to new bicyclo(2.2.1)heptane derivatives of the general formula I ##STR1## wherein R represents a C.sub.1-12 alkyl group optionally substituted by a lower alkoxy group, a C.sub.2-4 alkenyl group or a phenyl-(lower alkyl) group optionally substituted on the phenyl ring by one or more lower alkoxy groups or halogen atoms.The invention relates further to plant growth regulating compositions comprising as active agent 0.001 to 95% by weight of a racemic and/or optically active compound of the general formula I, wherein R has the above defined meanings, along with a conventional organic or inorganic, solid and/or liquid carrier and/or filler and/or diluent and/or surfactant.The invention encompasses also the preparation of the compounds of the general formula I which comprises reacting a racemic or optically active compound of the general formula II ##STR2## wherein Y is an oxygen or sulfur atom or an oxim group, with a compund of the general formula IIIR - XwhereinR is as defined above, andX represents a leaving group, preferably a halogen atom, a sulfonyloxy or an aminooxy group, with the proviso that when using a compound of the general formula II, in which Y is an oxim group, X is other than aminooxy group,in the presence of a basic condensing agent, and optionally resolving the racemic compound of the general formula I obtained into its optically active antipodes.

    摘要翻译： 本发明涉及通式I的新的双环（2.2.1）庚烷衍生物，其中R表示任选被低级烷氧基，C 2-4链烯基或苯基 - （ 低级烷基）基团，其任选在苯环上被一个或多个低级烷氧基或卤素原子取代。 本发明进一步涉及植物生长调节组合物，其包含作为活性剂0.001至95重量％的通式I的外消旋和/或旋光活性化合物，其中R具有上述定义的含义，以及常规的有机或无机， 固体和/或液体载体和/或填料和/或稀释剂和/或表面活性剂。 本发明还包括通式I的化合物的制备，其包括使通式II的外消旋或旋光活性化合物其中Y是氧或硫原子或肟基，与下列化合物反应： 通式III R-X其中R如上定义，X​​表示离去基团，优选卤素原子，磺酰氧基或氨基氧基，条件是当使用通式II的化合物时，其中Y为 肟基，X不是氨基氧基，在碱性缩合剂的存在下，并且任选地将所得通式I的外消旋化合物拆分成其光学活性对映体。

    Plant growth regulating and insecticidal compositions
    8.
    发明授权
    Plant growth regulating and insecticidal compositions 失效
    植物生长调节和杀虫组合物

    公开(公告)号：US4244888A

    公开(公告)日：1981-01-13

    申请号：US65156

    申请日：1979-08-09

    申请人： Zoltan Budai ,  Ferenc Jurak ,  Attila Kis-Tamas ,  Aranka Lay nee Konya ,  Tibor Mezei ,  Zoltan Vig ,  Terez Zubovits nee Kristof

    发明人： Zoltan Budai ,  Ferenc Jurak ,  Attila Kis-Tamas ,  Aranka Lay nee Konya ,  Tibor Mezei ,  Zoltan Vig ,  Terez Zubovits nee Kristof

    IPC分类号： A01N33/24 ,  A01N35/10 ,  C07C249/04 ,  C07C251/44 ,  C07C131/02

    CPC分类号： A01N35/10

    摘要： Racemic or optically active 2-(propargyloxyimino)-1,7,7-trimethyl-bicyclo[2,2,1]heptane of the formula (I) ##STR1## or a mixture of these isomers is prepared by reacting a racemic or optically active 1,7,7-trimethyl-bicyclo[2,2,1]heptane derivative of the general formula (II), ##STR2## wherein Y stands for oxygen atom, sulfur atom or oxime group, with a propyne derivative of the general formula (III),R--CH.sub.2 --C.tbd.CH (III) whereinR stands for halogen atom or aminooxy group, with the proviso that if Y represents oxime group, R may stand only for halogen, and if R represents aminooxy group, Y may stand only for oxygen or sulfur atom.The resulting product is new and possesses strong plant growth promoting and insecticidal effects.

    摘要翻译： 式（I）的外消旋或光学活性的2-（炔丙氧基亚氨基）-1,7,7-三甲基 - 双环[2,2,1]庚烷或其混合物可以通过使 外消旋或光学活性的通式（II）的17,7-三甲基 - 双环[2,2,1]庚烷衍生物，其中Y代表氧原子，硫原子或肟基，其中 通式（III）的丙炔衍生物，其中R代表卤素原子或氨基氧基的R-CH 2 -C 3 CHCH（III），条件是如果Y表示肟基，则R可以仅为卤素，如果 R表示氨基氧基，Y可以仅为氧或硫原子。 产生的产品是新的，具有很强的植物生长促进和杀虫作用。

    Bicyclo(2.2.1)heptane oximes
    10.
    发明授权
    Bicyclo(2.2.1)heptane oximes 失效
    双环（2.2.1）庚烷肟

    公开(公告)号：US4511737A

    公开(公告)日：1985-04-16

    申请号：US551941

    申请日：1983-11-15

    申请人： Zoltan Budai ,  Attila Kis-Tamas ,  Tibor Mezei ,  Aranka Lay ,  Zoltan Vigh ,  Agnes Sokorai

    发明人： Zoltan Budai ,  Attila Kis-Tamas ,  Tibor Mezei ,  Aranka Lay ,  Zoltan Vigh ,  Agnes Sokorai

    IPC分类号： A01N33/24 ,  A01N33/04 ,  A01N35/10 ,  A01P21/00 ,  C07C251/44 ,  C07C251/50 ,  C07C131/02

    CPC分类号： A01N35/10

    摘要： The invention relates to new bicyclo(2.2.1)heptane derivatives of the general formula I ##STR1## wherein R represents a C.sub.1-12 alkyl group optionally substituted by a lower alkoxy group, a C.sub.2-4 alkenyl group or a phenyl-(lower alkyl) group optionally substituted on (I), phenyl ring by one or more lower alkoxy groups or halogen atoms.The invention relates further to plant growth regulating compositions comprising as active agent 0.001 to 95% by weight of a racemic and/or optically active compound of the general formula I, wherein R has the above defined meanings, along with a conventional organic or inorganic, solid and/or liquid carrier and/or filler and/or diluent and/or surfactant.The invention encompasses also the preparation of the compounds of the general formula (I) which comprises reacting a racemic or optically active compound of the general formula (II) ##STR2## wherein Y is an oxygen or sulfur atom or an oxim group, with a compound of the general formula (III)R--XwhereinR is as defined above, andX represents a leaving group, preferably a halogen atom, a sulfonyloxy or an aminooxy group, with the proviso that when using a compound of the general formula (II), in which Y is an oxim group, X is other than aminooxy group,in the presence of a basic condensing agent, and optionally resolving the racemic compound of the general formula (I) obtained into its optically active antipodes.

    摘要翻译： 本发明涉及通式I（I）的新型双环（2.2.1）庚烷衍生物，其中R表示任选被低级烷氧基取代的C 1-12烷基，C 2-4链烯基或苯基 - （低级烷基）基团，其任选地在（I）上取代，苯基环由一个或多个低级烷氧基或卤素原子取代。 本发明进一步涉及植物生长调节组合物，其包含作为活性剂0.001至95重量％的通式I的外消旋和/或旋光活性化合物，其中R具有上述定义的含义，以及常规的有机或无机， 固体和/或液体载体和/或填料和/或稀释剂和/或表面活性剂。 本发明还包括通式（I）的化合物的制备，其包括使通式（II）的外消旋或光学活性化合物其中Y是氧或硫原子或肟基的（II） 与通式（III）RX的化合物，其中R如上定义，X​​表示离去基团，优选卤素原子，磺酰氧基或氨基氧基，条件是当使用通式 （II），其中Y是肟基，X不是氨基氧基，在碱性缩合剂的存在下，并且任选地将通式（I）的外消旋化合物拆分成其光学活性对映体。