摘要:
Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1−x O2, wherein 0.05≦x≦0.10, a+b+c=1, 0.6≦b/a≦1.1, c/(a+b)
摘要翻译:提供了用于锂离子电化学电池的正极,当比较循环52之后的容量与循环2之间的容量在2.5V与4.7V之间的循环时相比,在50次充放电循环之后具有大于约95%的容量保持 / Li +。在所提供的正电极中有用的组合物可以具有式Li 1 + x(NiaMnbCoc)1-x O 2,其中0.05&nlE; x&nlE; 0.10,a + b + c = 1,0.6& /a≦̸1.1,c /(a + b)<0.25,a,b和c都大于零。 制造这些正电极的过程包括将组合物在850℃烧制至925℃
摘要:
Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1−x O2, wherein 0.05≦x≦0.10, a+b+c=1, 0.6≦b/a≦1.1, c/(a+b)
摘要翻译:提供了用于锂离子电化学电池的正极,当比较循环52之后的容量与循环2之间的容量在2.5V与4.7V之间的循环时相比,在50次充放电循环之后具有大于约95%的容量保持 / Li +。在所提供的正电极中有用的组合物可以具有式Li 1 + x(NiaMnbCoc)1-x O 2,其中0.05&nlE; x&nlE; 0.10,a + b + c = 1,0.6& /a≦̸1.1,c /(a + b)<0.25,a,b和c都大于零。 制造这些正电极的过程包括将组合物在850℃烧制至925℃
摘要:
A lithium-ion electrochemical cell is provided that has high total energy, high energy density and good performance upon repeated charge-discharge cycles. The cell includes a composite positive electrode that comprises a metal oxide electrode material, a composite negative electrode that comprises a alloy anode active material having a first cycle irreversible capacity of 10 percent or higher and an electrolyte. The first cycle irreversible capacity of the composite positive electrode is within 40 percent of the first cycle irreversible capacity of the composite negative electrode.
摘要:
Single-phase lithium-transition metal oxide compounds containing cobalt, manganese and nickel can be prepared by wet milling cobalt-, manganese-, nickel- and lithium-containing oxides or oxide precursors to form a finely-divided slurry containing well-distributed cobalt, manganese, nickel and lithium, and heating the slurry to provide a lithium-transition metal oxide compound containing cobalt, manganese and nickel and having a substantially single-phase O3 crystal structure. Wet milling provides significantly shorter milling times than dry milling and appears to promote formation of single-phase lithium-transition metal oxide compounds. The time savings in the wet milling step more than offsets the time that may be required to dry the slurry during the heating step.
摘要:
Single-phase lithium-transition metal oxide compounds containing cobalt, manganese and nickel can be prepared by wet milling cobalt-, manganese-, nickel- and lithium-containing oxides or oxide precursors to form a finely-divided slurry containing well-distributed cobalt, manganese, nickel and lithium, and heating the slurry to provide a lithium-transition metal oxide compound containing cobalt, manganese and nickel and having a substantially single-phase O3 crystal structure. Wet milling provides significantly shorter milling times than dry milling and appears to promote formation of single-phase lithium-transition metal oxide compounds. The time savings in the wet milling step more than offsets the time that may be required to dry the slurry during the heating step.