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公开(公告)号：US20060128999A1
公开(公告)日：2006-06-15
申请号：US11350881
申请日：2006-02-10
IPC分类号： C07C45/50
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
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2.发明授权Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法公开(公告)号：US07223374B2
公开(公告)日：2007-05-29
申请号：US11350881
申请日：2006-02-10
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
摘要翻译： 通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或 锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。 在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。
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3.发明授权Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法公开(公告)号：US07060860B2
公开(公告)日：2006-06-13
申请号：US10411389
申请日：2003-04-11
IPC分类号： C07C45/50
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
摘要翻译： 通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或 锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。 在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。
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公开(公告)号：US06908878B2
公开(公告)日：2005-06-21
申请号：US10189328
申请日：2002-07-05
CPC分类号： B01J37/082 , B01J23/28 , B01J23/30 , B01J23/36 , C07C6/04 , Y02P20/52 , C07C11/06 , C07C11/04 , C07C11/08
摘要： An improved catalyst composition for the metathesis of olefins comprises at least one porous mineral carrier based on alumina, at least one compound of rhenium, molybdenum, or tungsten, and further includes silicon in an oxide form.
摘要翻译： 用于烯烃复分解的改进的催化剂组合物包含至少一种基于氧化铝的多孔矿物载体，至少一种铼，钼或钨的化合物，并且还包括氧化物形式的硅。
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