摘要:
The invention concerns a method for preparing anisotropic silica aggregates comprising the following steps: a) contacting at least one polymer with non-aggregated silica particles and/or highly dispersed in an aqueous medium, with a ratio R, polymer weight to silica particle surface, ranging between 0.03 and 2 mg/m; 2; and whereof the electrostatic value of the silica particle surface is not less than the value of the charge of the silica particle surface measured in an aqueous phase without added salts at a pH not less than 7; b) consolidating the aggregates obtained at step a) either by heat treatment, or by precipitation of a mineral compound. The invention also concerns a silica aggregate comprising a chaining of elementary particles whereof the number of particles ranges between 5 and 15, whereof 80% of elementary particles are in contact with not more than 2 particles and whereof the greatest distance measurable between 2 points of the aggregate is not more than 5 times the average size of one elementary particle.
摘要翻译:本发明涉及一种制备各向异性二氧化硅聚集体的方法,包括以下步骤:a)使至少一种聚合物与非聚集的二氧化硅颗粒接触和/或高度分散在水性介质中,R与聚合物重量与二氧化硅颗粒表面的比率, 范围在0.03至2mg / m; 2; 并且二氧化硅颗粒表面的静电值不小于在不低于7的pH下在没有添加盐的情况下在水相中测量的二氧化硅颗粒表面的电荷的值; b)通过热处理或通过沉淀矿物化合物来固化在步骤a)获得的聚集体。 本发明还涉及一种二氧化硅聚集体,其包含基本粒子的连接,其中粒子数目在5至15之间,其中80%的基本粒子与不超过2个粒子接触,并且其中2个点之间的最大距离可以测量 聚集体不超过一个基本粒子的平均尺寸的5倍。
摘要:
Precipitated silicas including clusters of large primary silica particles having at the surface thereof small primary silica particles, have a specific surface area CTAB (SCTAB) ranging from 60 to 400 m2/g; a cluster average size d50, as measured by XDC grading after ultrasound deagglomeration, such that d50 (nm)>(6214/SCTAB (m2/g)+23; a pore volume distribution such that V(d5-d50)/V(d5-d100)>0.906−(0.0013×SCATB (m2/g)); and a pore size distribution such that Mode (nm)>(4166/SCTAB (m2/g))−9.2; such silicas are useful reinforcing fillers for polymers.
摘要:
Precipitated silicas including clusters of large primary silica particles having at the surface thereof small primary silica particles, have a specific surface area CTAB (SCTAB) ranging from 60 to 400 m2/g; a cluster average size d50, as measured by XDC grading after ultrasound deagglomeration, such that d50 (nm)>(6214/SCTAB (m2/g)+23; a pore volume distribution such that V(d5-d50)/V(d5-d100)>0.906−(0.0013×SCATB (m2/g)); and a pore size distribution such that Mode (nm)>(4166/SCTAB (m2/g))−9.2; such silicas are useful reinforcing fillers for polymers.
摘要:
The invention concerns a method for preparing anisotropic silica aggregates comprising the following steps: a) contacting at least one polymer with non-aggregated silica particles and/or highly dispersed in an aqueous medium, with a ratio R, polymer weight to silica particle surface, ranging between 0.03 and 2 mg/m; 2; and whereof the electrostatic value of the silica particle surface is not less than the value of the charge of the silica particle surface measured in an aqueous phase without added salts at a pH not less than 7; b) consolidating the aggregates obtained at step a) either by heat treatment, or by precipitation of a mineral compound. The invention also concerns a silica aggregate comprising a chaining of elementary particles whereof the number of particles ranges between 5 and 15, whereof 80% of elementary particles are in contact with not more than 2 particles and whereof the greatest distance measurable between 2 points of the aggregate is not more than 5 times the average size of one elementary particle.
摘要翻译:本发明涉及一种制备各向异性二氧化硅聚集体的方法,包括以下步骤:a)使至少一种聚合物与非聚集的二氧化硅颗粒接触和/或高度分散在水性介质中,R与聚合物重量与二氧化硅颗粒表面的比率, 范围在0.03至2mg / m; 2; 并且二氧化硅颗粒表面的静电值不小于在不低于7的pH下在没有添加盐的情况下在水相中测量的二氧化硅颗粒表面的电荷的值; b)通过热处理或通过沉淀矿物化合物来固化在步骤a)获得的聚集体。 本发明还涉及一种二氧化硅聚集体,其包含基本粒子的连接,其中粒子数目在5至15之间,其中80%的基本粒子与不超过2个粒子接触,并且其中2个点之间的最大距离可以测量 聚集体不超过一个基本粒子的平均尺寸的5倍。
摘要:
A solar energy reflector (1) comprises a mirror (5) with no copper layer laminated to a supporting sheet (7) by means of a bonding material (6). The edges of the mirror (5) are provided, at least on a portion forming the major part of their height and closest to the metallic sheet, with an edge protection (8) made of a material comprising silicone, polyurethane and/or acrylic and the material forming the edge protection (8) is different from the bonding material (6).
摘要:
Mirrors according to the present invention comprise a glass substrate (1) having a front surface (10) and a rear surface (11), said rear surface (11) carrying, in order, a silver coating layer (2) and at least one base paint layer (3); they are characterised in that the glass substrate (1), the silver coating layer (2) and the at least one base paint layer (3) have each an edge portion having a rear facing surface (51, 52, 53) arranged at an acute angle (α1, α2, α3) to the front surface of the mirror and in that they comprise an additional paint layer (4) covering substantially the whole surface of the at least one base paint layer (3) and the rear facing surfaces (51, 52, 53) of the glass substrate (1), silver coating layer (2) and at least one base paint layer (3).
摘要:
Mirrors with no copper layer according to the present invention comprise a glass substrate, a silver coating layer provided at a surface of the glass substrate and at least two paint layers covering the silver coating layer, the outermost paint layer comprising a polyurethane resin based paint. They are characterised in that the paint layers are free of alkyd resin and in that the first paint layer closest to the silver coating layer has a thickness of at least 10 μm.
摘要:
Mirror consisting of a glass substrate having a front surface and a rear surface, the rear surface carrying, in order, a silver coating layer and at least one base paint layer. The glass substrate, the silver coating layer, and the at least one base paint layer each have an edge portion having a rear facing surface arranged at an acute angle to the front surface of the mirror. An additional paint layer covers the entire surface of the base paint layer and the rear facing surfaces of the glass substrate and the silver coating layer.
摘要:
Solar energy reflectors (1) according to the present invention comprise a mirror (5) laminated to a support (6) by means of a bonding material (9) comprising a foam tape.
摘要:
A solar energy reflector (1) comprises a mirror (5) with no copper layer laminated to a supporting sheet (7) by means of a bonding material (6). The edges of the mirror (5) are provided, at least on a portion forming the major part of their height and closest to the metallic sheet, with an edge protection (8) made of a material comprising silicone, polyurethane and/or acrylic and the material forming the edge protection (8) is different from the bonding material (6).